51 results about "Organic sulfide compound" patented technology

Disclosed in the present invention are a high-temperature ultrahigh-strength high-elongation copper foil for a lithium-ion battery, and a production process therefor. The production process comprises the following steps: step S1, preparing an electrolyte by dissolving raw copper in a sulfuric acid solution to form a dissolved solution, filtering same to remove impurities and then mixing same with a composite additive to obtain the electrolyte, wherein the composite additive comprises an organic sulfide, gelatin, polyethylene glycol, a nitrogen-containing compound, a polyether compound and Cl-; step S2, preparing a primary copper foil by introducing the electrolyte into an electrolytic cell of a crude foil machine via a pipeline and carrying out electroplating to obtain the primary copper foil; and step S3, subjecting the primary copper foil to a surface passivation treatment, drying and winding to obtain an ultrahigh-strength copper foil for a lithium-ion battery. A high-performance additive is introduced to control the grain refinement and uniform distribution of the copper foil, thereby improving the strength and ductility thereof; the thermal stability and strength of the improved copper foil in a high-temperature environment are maintained, thereby ensuring long-term stable operation of the improved copper foil after high-temperature cyclic charging and discharging of a silicon negative-electrode battery.

The invention relates to the technical field of organic sulfide preparation, in particular to a method for synthesizing and refining dimethyl sulfide (DMS) and dimethyl sulfoxide (DMSO) embedded into a methanol plant, which mainly utilizes high-purity oxygen of an air separation unit of the methanol plant, a high-concentration hydrogen sulfide product of low-temperature methanol washing and part of top gas-phase refined methanol of a pressurizing tower of a methanol rectification device. The production cost of the product is reduced, the added value of the product is improved, and the hydrogen sulfide product of a methanol plant is effectively utilized.

The invention discloses sewage energy-saving treatment equipment for oil-based needle coke production, and belongs to the technical field of oil-based needle coke production. The device comprises a box body, a plurality of fixing pipes are symmetrically and fixedly connected to the side wall of the box body in a penetrating mode, a plurality of box covers are clamped to the upper side of the box body, a plurality of ultraviolet irradiation lamps are fixedly connected in the box body, two baffles are symmetrically and fixedly connected in the box body, and an air flotation machine is fixedly connected to the bottom in the box body. A slag scraping assembly is installed in the box body and comprises a slag scraping plate. In the sewage treatment process, under the action of the ultraviolet irradiation lamp and the catalyst, organic sulfide in sewage can be converted into inorganic sulfide, then under the action of the slag scraping plate, impurities floating on the water surface can be scraped between the baffle and the box body, the simple impurity removal effect is achieved, the structure is simple, and the operation is convenient. The practical effect is good.

The invention relates to a ZnAl-LDH-based material as well as a preparation method and application thereof in sludge treatment. The ZnAl-LDH-based material is prepared from a divalent metal salt solution and a trivalent metal salt solution through a coprecipitation method, divalent metal comprises Zn and Cu, and trivalent metal is Al; the molar weight ratio of the divalent metal to the trivalent metal is (1-3): 1, and the ratio of the molar weight of Cu to the total molar weight of the divalent metal is (0-0.5): 1. The ZnAl-LDH-based material is used for promoting the organic sulfide in the sludge to be converted into sulfoxide sulfur and sulfone sulfur. Compared with the prior art, a series of ZnAl-LDH-based materials with proper specific surface areas and pore volume structures are prepared, and low-valence organic sulfides in municipal sludge can be promoted to be directionally converted into sulfoxide sulfur and sulfone sulfur; the method has a wide application prospect in the field of improving the high-added-value utilization of organic sulfide-containing wastes such as municipal sludge.

The invention relates to the technical field of copper foil preparation, in particular to a high-elongation ultrathin lithium battery copper foil and a preparation method and application thereof.The preparation method comprises the following steps that S1, a copper raw material, sulfuric acid and deionized water are dissolved to obtain a copper sulfate solution, the copper sulfate solution is subjected to multi-stage filtration and then mixed with an additive, and an electrolyte is obtained; s2, the electrolyte is subjected to heat exchange through a heat exchanger and then guided into an electrolytic bath, the temperature and the current density of the electrolyte are adjusted, and electrolytic foil generation is conducted; and S3, carrying out passivation and heat treatment on the copper foil obtained by electrolyzing the raw foil, and then trimming and rolling to obtain the ultrathin lithium battery copper foil, wherein the additive in the step S1 is a mixture of organic sulfide and an oxygen-containing polymer. The lithium battery copper foil prepared by the invention has good tensile strength and high elongation.

The invention discloses a system and a method for treating odor in a pretreatment stage of a municipal sewage plant. The method comprises the following steps: collecting gas; performing pretreatment; biological desulfurization: the pretreated odor enters a biological desulfurization tower from the bottom, hydrogen sulfide in the odor is oxidized into elemental sulfur or sulfate by acidophilic sulfur-oxidizing bacteria in the process of penetrating through an acidic biological filler layer, and meanwhile, part of ammonia and amine substances are removed through chemical absorption; alkali washing treatment: the gas subjected to biological desulfurization treatment enters an alkali washing tower from the bottom, and in the process of passing through an alkaline filler layer, residual hydrogen sulfide, ammonia gas, organic sulfide and the like are subjected to neutralization reaction with a sodium hydroxide solution so as to be removed; and up-to-standard discharge is realized. According to the invention, high-concentration hydrogen sulfide is efficiently and stably removed, and the impact of the high-concentration hydrogen sulfide on a subsequent treatment unit is avoided; various malodorous substances such as ammonia gas can be synchronously and efficiently removed; the impact load resistance of the system is improved, and the stability of the treatment effect is ensured; the medicament consumption and energy consumption are reduced, and the operation cost is reduced.

The invention provides a low-temperature absorption and adsorption coupling recovery treatment process for VOCs (volatile organic compounds) oil gas in a tank field, and relates to the technical field of VOCs treatment, which comprises the following steps: (1) low-temperature absorption: the VOCs oil gas in the tank field enters an absorption tower and is contacted with an intermediate material absorbent of a factory production device at-5-15 DEG C, and 80-90% of non-methane total hydrocarbon and organic sulfide are removed; (2) adsorption and removal: the absorbed oil gas enters an adsorption unit with three tanks connected in parallel, residual hydrocarbons are deeply removed through an adsorbent, and the hydrocarbon concentration of outlet tail gas is smaller than or equal to 60 mg / m; through the synergistic effect of low-temperature absorption and adsorption, various organic components in the VOCs oil gas in the tank field can be deeply captured, non-methane hydrocarbon can be efficiently removed, refractory components such as organic sulfide can be treated in a targeted manner, available resources in the oil gas are ensured to be fully recycled, and loss of valuable components is avoided.

The present application relates to the technical field of metal organic framework materials, in particular to a modified copper-based metal organic framework material, a preparation method and application thereof, and a sulfide removal method. The modified copper-based metal organic framework material comprises a metal organic framework formed by copper and an organic ligand, and silver doped on the metal organic framework; and the crystal surface of the modified copper-based metal organic framework material has long and narrow honeycomb-shaped pores. + and Ag + The modified copper-based metal organic framework material has suitable pore structures and rich adsorption sites for removing various organic sulfides, and the modified copper-based metal organic framework material has Cu + and Ag + which can adsorb sulfides through π bond action, and has a large adsorption capacity and high adsorption selectivity for sulfides (such as mercaptans, sulfides, thiophenes, etc.) as a desulfurization adsorbent.

This application provides a desulfurization adsorbent comprising an oxide active component and a support, wherein the mass ratio of the oxide active component to the support is 1:(5~1000). The oxide active component is selected from one or more oxides of alkali metals, alkaline earth metals, and Group III subgroup metals. The support is selected from one or more molecular sieves of type A, type X, type Y, activated carbon, and porous metal fluorides. The desulfurization adsorbent described in this application exhibits good adsorption effect, large adsorption capacity, and long breakthrough time for various organic sulfides.

The present invention pertains to a conductive adhesive film (10) for joining a semiconductor device and a member, the conductive adhesive film (10) comprising: a stress relaxation layer (1) that is composed of a soft high-thermal-conductivity metal having a Young's modulus of 110 GPa or less at 25°C, a thermal conductivity of 100 W / m•K or more at 25°C, and a volume resistivity of 100 μΩ•cm or less; a first adhesive layer (2) that is provided on the side of the stress relaxation layer (1) to which the semiconductor device is joined, the first adhesive layer containing copper (Cu), tin (Sn), a bismaleimide resin, and an organic phosphine and / or an organic sulfide; and a second adhesive layer (3) that is provided on the side opposite the side of the stress relaxation layer (1) to which the semiconductor device is joined, the second adhesive layer containing copper (Cu), tin (Sn), a bismaleimide resin, and an organic phosphine and / or an organic sulfide.

The application provides a sulfate-reducing bacteria culture medium and application thereof, and components of the culture medium include: a carbon source, a nitrogen source, a phosphorus source, calcium chloride, magnesium chloride, an inorganic sulfur source, an organic sulfur compound with reducibility, inorganic trace elements, agar and water; wherein the mass content of the organic sulfur compound with reducibility is 5-30 mg / L, the mass content of the inorganic trace elements is 152-365 mg / L; the organic sulfur compound with reducibility includes lipoic acid and / or thiamine hydrochloride; and the inorganic trace elements include a combination of zinc elements, manganese elements, molybdenum elements and boron elements. The application introduces inorganic trace elements required by biological cell metabolism and rich sulfur electron acceptor species, promotes the growth and metabolism process of sulfate-reducing bacteria, and enables SRB cells to form visible colonies at a faster speed.

The present invention pertains to a conductive adhesive film (10) for joining a semiconductor device and a member, said conductive adhesive film (10) comprising: a stress relief layer (1) configured from a perforated metal foil in which a through-hole is provided on the main surface of a metal foil formed of at least one metal selected from the group consisting of copper (Cu), a copper (Cu) alloy, aluminum (Al), and an aluminum (Al) alloy; a first adhesive layer (2) containing copper (Cu), tin (Sn), a bismaleimide resin, and an organic phosphine and / or an organic sulfide, sadi first adhesive layer (2) being provided on the side of the stress relief layer (1) to which the semiconductor device is joined; and a second adhesive layer (3) containing copper (Cu), tin (Sn), a bismaleimide resin, and an organic phosphine and / or an organic sulfide, said second adhesive layer (3) being provided on the side of the stress relief layer (1) facing the side to which the semiconductor device is joined.

The present application relates to a kind of multi-stage pore composite mineral cat litter and its preparation method and recovery method, relate to cat litter technical field, to solve at least one of the problems such as insufficient adsorption amount of existing cat litter, poor catalytic decomposition ability to organic sulfide, environmental pollution, high cost, poor recycling ability etc..The present application realizes the targeted capture and efficient decomposition of multiple odor molecules in pet excrement by constructing gradient pore structure and biological-mineral composite deodorization system, and is suitable for feces management in scenes such as family pet care, stray animal rescue station and zoo.The specific cat litter core of the present application includes hierarchical porous diatomite, and modified sodium-based bentonite, to realize gradient adsorption and enrichment of odor molecules, and to promote the synergistic degradation of NH3, H2S and VOCs using a non-metallic catalytic-biological enzyme combined system.

The invention relates to a hierarchical porous composite mineral cat litter as well as a preparation method and a recovery method thereof, relates to the technical field of cat litters, and aims to solve at least one of the problems of insufficient adsorption capacity, poor catalytic decomposition capability on organic sulfides, environmental pollution, high cost, poor cyclic utilization capability and the like of the existing cat litter. By constructing a gradient hole structure and a biological-mineral composite deodorization system, targeted capture and efficient decomposition of multi-element peculiar smell molecules in pet excrement are achieved, and the pet excrement treatment device is suitable for excrement management in scenes such as family pet nursing, stray animal rescue stations and zoos. Specifically, the inner core of the cat litter comprises graded porous diatomite and synergistic modified sodium bentonite, gradient adsorption and enrichment of odor molecules are realized, and synergistic degradation of NH3, H2S and VOCs is promoted by adopting a non-metal catalysis-biological enzyme combined system.

The present invention belongs to the field of energy and chemical industry, and specifically discloses a method for selective oxidative desulfurization in petroleum and its products. In this method, in a polar phase composed of water and acetonitrile, organic sulfides in a non-polar phase oil solution are selectively removed by direct oxidation of peroxy organic acid and activation of the peroxy organic acid by a catalyst to produce active substances. In the polar phase, peroxypropionic acid is used as an oxidant, and low-valent transition metals are used as catalysts to activate the peroxypropionic acid to produce active substances to achieve oxidative removal of organic sulfur in the non-polar phase. This process is suitable for the direct removal of organic sulfur in petroleum and the selective removal of organic sulfur in petroleum products, and can be expanded to the selective desulfurization of various liquid phase systems, such as the desulfurization of waste tire pyrolysis liquid. This process is suitable for reactions under normal temperature and pressure, and the process flow is simple and can be flexibly adjusted according to actual needs.

The application discloses a vanadium ion flow battery with a praseodymium sulfide composite graphite felt electrode and belongs to the technical field of flow battery electrodes. The electrode comprises a graphite felt base body and a surface-loaded praseodymium sulfide composite layer, the composite layer is composed of praseodymium sulfide nanoparticles and carbon nanomaterials, and the particle size of the nanoparticles is 5-50 nm. Preparation is carried out by mixing a praseodymium source and a sulfur source to prepare a precursor, mixing the precursor with a carbon nanomaterial dispersion liquid, performing graphite felt thermal oxidation pretreatment, hydrothermal reaction, washing and drying, and inert atmosphere heat treatment. In the application, inorganic rare earth praseodymium sulfide is used to replace organic sulfide and nitrogen-doped carbon material, Pr 3+ / Pr 4+ is used to realize efficient catalysis, the electrode is resistant to strong acid, stable in a wide temperature range, firmly combined at an interface, and long in cycle life. The electrode can be used in all-vanadium, zinc-bromine, iron-chromium and other flow batteries, is also applicable to the fields of hydrogen production by electrolysis, supercapacitors and electrocatalysis, and is mild in process and easy to scale up.

The invention relates to a method for efficiently and synergistically purifying multiple metals in wet-process phosphoric acid, which comprises the following steps: (1) adding an inorganic sulfide accounting for 0.05-0.40% of the mass of wet-process phosphoric acid slurry into the wet-process phosphoric acid slurry, and reacting for 30-60 minutes at the temperature of 80-85 DEG C and the stirring speed of 100-200 r / min; (2) pumping the reacted slurry into a filter, adding an organic sulfide accounting for 0.05-0.20% of the mass of the wet-process phosphoric acid slurry at the front end of a pump, and reacting for 10-90 seconds under the conditions that the temperature is 70-80 DEG C and the rotating speed of the pump is 900-1500 r / min; and (3) filtering to obtain dilute phosphoric acid, and aging, concentrating and aging the dilute phosphoric acid to obtain the finished product concentrated phosphoric acid. The sulfide and dithiophosphate synergistic process is adopted, the reaction time with organic sulfide is shortened to the second level, the defect that in the prior art, the efficiency of a single cadmium removal agent is low is overcome, multi-metal ions such as arsenic, cadmium and copper are synchronously removed, the removal rate reaches up to 98% or above, and the cadmium removal treatment cost of per ton of phosphoric acid is greatly reduced.

The present invention relates to a conductive adhesive film (10) for joining a semiconductor device and a member, the conductive adhesive film comprising: a stress relaxation layer (1) composed of a soft, highly thermally conductive metal having a 0.2%-proof stress at 25°C of 200 N / mm2 or less, a thermal conductivity at 25°C of 50 W / m·K or more, and a volume resistivity of 100 μΩ·cm or less; a first adhesive layer (2) that includes copper (Cu), tin (Sn), a bismaleimide resin, and an organic phosphine and / or an organic sulfide, and that is provided on the side, of the stress relaxation layer (1), to which the semiconductor device is joined; and a second adhesive layer (3) that includes copper (Cu), tin (Sn), a bismaleimide resin, and an organic phosphine and / or an organic sulfide, and that is provided on the side, of the stress relaxation layer (1), opposite to the side to which the semiconductor device is joined.

Disclosed in the present invention are a metal-doped alumina supported basic catalyst, and a preparation method therefor and a use thereof. The catalyst comprises a support and a basic component supported on the support. The support comprises Al2O3, AgxOy and RemOn. By regulating one or more of the following parameters or conditions: the content and / or valence state of AgxOy and RemOn in the support, and the synergistic effect thereof with Al2O3 in the support, the supported basic component, and an optional modified component, the performance of the catalyst is significantly improved, so that the catalyst has better desulfurization efficiency and operation period, and can achieve adsorption removal and refining of different organic and inorganic sulfides under low temperature conditions. Moreover, the catalyst can be regenerated repeatedly, and the preparation method therefor is simple and easy to implement, and is suitable for industrial production.

Disclosed is a process for treating a residual stream from bisphenol production, wherein the residual stream includes unreacted phenols, bisphenol isomers, triphenols, organic sulfides, and water. The process comprises contacting at least a portion of the residual stream or reaction products thereof with an acidic catalyst under conditions sufficient to allow acid-catalyzed hydrolysis of organic sulfides within the residual stream to the corresponding mercaptans and produce an effluent stream; and then distilling at least a portion of the effluent stream to recover a distillate product comprising phenols and mercaptans and produce a bottoms product comprising bisphenol isomers and triphenols and having a lower organic sulfide content than the residual stream.

This invention discloses a porous carbon, a method for preparing porous carbon, an anode sheet, and a lithium-ion battery. The porous carbon and its preparation method for this silicon-carbon anode material utilize inexpensive and widely available high-sulfur pitch as raw material. Crosslinking is achieved by adding ion-exchange resin-type crosslinking agents and organic sulfides, followed by two-step heat treatment, thus realizing the efficient preparation of porous carbon materials. The key to this method lies in: adding a small amount of ion-exchange resin-type crosslinking agent to promote the formation of a stable hard carbon framework structure in the high-sulfur pitch after heat treatment; simultaneously, the precise control of the introduction, type, and amount of organic sulfides effectively regulates the specific surface area, micropore ratio, and pore size distribution of the obtained porous carbon, ultimately producing a porous carbon material with high specific surface area, high micropore ratio, high pore volume, and excellent conductivity. When this porous carbon material is used as a substrate for silicon-carbon anode materials, it can significantly improve the overall performance of the battery, and the preparation process is simple.

The present invention provides a composition for controlling melon Fusarium wilt (MFW), comprising an organic sulfide combined with glucose in certain ratio. The composition of present invention may be applied to melon plants by foliar spray to effectively protect the melon plant from phytopathogenic Fusarium oxysporum f.sp. melonis (FOM) infection, and thus reduce the disease severity and prevent the onset of wilting symptoms in the melon plant.

The invention relates to a method for synthesizing benzoate derivatives from dimethyl sulfoxide, belongs to the technical field of application of organic sulfides, and solves the technical problems that existing aryl formate synthesis generally needs strong acid or strong alkali, synthetic products and synthetic conditions are limited and the like. The solution is as follows: the method for synthesizing benzoate derivatives from dimethyl sulfoxide comprises the following steps: 1) preparing benzyl methyl sulfide: putting dimethyl sulfoxide and benzyl bromide or benzyl bromide derivatives into a reaction container, and fully reacting at a first temperature to prepare benzyl methyl sulfide; and 2) preparation of the benzoate derivative: putting a photosensitizer, an inorganic base, an organic solvent, the benzyl methyl sulfide prepared in the step 1) and an organic bromide into a reaction container, and fully reacting under the irradiation of a visible light range at a second temperature and a target atmosphere condition to prepare the benzoate derivative. Compared with the prior art, the method has the advantages of high efficiency, greenness, economy, mild conditions, high social and economic benefits and the like.

The application discloses a high-etching-rate selective etching liquid and a preparation method and application thereof, and comprises the following components in parts by mass: 5-10 parts of organic acid, 60-80 parts of inorganic acid, 8-15 parts of oxidizing agent, 1-2 parts of nitrate, 1-2 parts of additive, and 5-15 parts of pure water; the nitrate comprises at least one of sodium nitrate, potassium nitrate, calcium nitrate and ammonium nitrate; and the additive is an organic sulfide substance. The etching liquid is clear and colorless, has high etching rate and high selectivity, is simple to prepare, has good etching uniformity, and can be applied in the field of etching semiconductor display panel manufacturing, and mainly solves the problem of serious shrinkage of upper metal (Al and Mo layers) after etching of a Mo / Al / Ti substrate.

The present application relates to the technical field of adsorbing material, in particular to a desulfurization adsorbent and a preparation method. The TiO2 / clay desulfurization adsorbent obtained by conventional calcination method or single alcohol impregnation method is prone to surface particle accumulation and adsorbent channel blockage, which leads to the decline of the adsorption performance of the desulfurization adsorbent to organic sulfides. In view of the above problems, the present application provides a desulfurization adsorbent, in the process of preparing the desulfurization adsorbent, the clay carrier and the active component are dispersed and dissolved in anhydrous ethanol under a nitrogen atmosphere, and then the two are blended under a nitrogen atmosphere, and after blending, atomization drying is carried out at high temperature. The operation mode, the adsorption effect of the obtained desulfurization adsorbent is good, and the desulfurization adsorbent has good adsorption to various organic sulfides in various organic solvents.

The present application belongs to the technical field of energy storage, and provides a lithium supplementing agent. The lithium supplementing agent comprises a sulfide composite material, the sulfide composite material comprising: a first sulfide, and a second sulfide doped in the first sulfide. The first sulfide comprises lithium sulfide, and the second sulfide is selected from at least one of a metal sulfide other than lithium sulfide, and an organic sulfide. The present application can solve the problems in the existing technology that positive electrode lithium supplementation is prone to gas generation, has a poor lithium replenishment effect, and is not conducive to effectively improving the overall performance of a battery.

The invention discloses an ETBE desulfurizer based on an organic amine-ester composite solvent, and relates to the technical field of separation and purification, the ETBE desulfurizer comprises the following raw materials by weight: 5-20 parts of an organic amine compound, 75-92 parts of an ester solvent, 0.5-8 parts of a scorch retarder, and 1-5 parts of a synergist. The desulfurizing agent disclosed by the invention is composed of an organic amine sulfide complexing agent, an ester solvent, a phosphite scorch retarder and a nano synergist, and organic sulfides such as mercaptan, thioether and the like in ETBE are efficiently complexed through a synergistic effect; middle-high pressure extractive distillation is adopted in the desulfurization process, the boiling point difference of sulfides is remarkably reduced by optimizing the operation pressure and temperature, and the separation efficiency is improved.

This invention belongs to the field of organic synthesis and relates to a method for preparing organosulfur ether compounds using photocatalysis. A disulfide compound 1 and tetrahydrofuran undergo a coupling reaction under the action of a base and a catalyst, and under ultraviolet light irradiation, to obtain organosulfur ether compound 3. This invention provides a novel method for preparing organosulfur compounds. Under light irradiation, a photocatalyst extracts hydrogen atoms from tetrahydrofuran to obtain alkyl radicals, which are then converted into carbocations through redox reactions. Simultaneously, the disulfide ether generates sulfur radicals under light irradiation, which produce sulfide anions under alkaline conditions. The sulfide anions and carbocations then undergo a coupling reaction to obtain sulfide compounds. The method provided by this invention is rationally designed, with mild reaction conditions, is environmentally friendly, and has low cost, achieving a yield of up to 91%. It provides a new method for the synthesis of organosulfur ether compounds and has promising industrial applications.

The invention discloses a method for rapidly preparing aza-aryl thioether compounds through mechanical piezoelectric catalysis C-S coupling reaction. According to the technical scheme, a chlorinated aza-aryl compound and a disulfide compound are used as raw materials, and a C-S coupling reaction is carried out under the conditions of normal temperature, normal pressure and air in a Ni catalysis and trace liquid auxiliary mechanical grinding mode to prepare a series of aza-aryl sulfide coupling products in a green and safe mode. According to the invention, a mechanical force method is adopted to rapidly and simply carry out C-S coupling reaction to prepare an organic sulfide intermediate or carry out thioetherification modification on molecules, the operation and treatment method is simple, the reaction mode is green and safe and is environment-friendly, BaTiO3 / Zn / Ni concerted catalysis is adopted, the reaction condition is mild, and the reaction can be completed in 100 minutes.

The application discloses a kind of based on FeS (112) / β-FeOOH composite material and preparation method and application, preparation method includes steps: iron salt is dissolved with organic sulfide in alcohol solvent, hydrothermal reaction is carried out under inert atmosphere protection, after reaction is finished, by centrifugation, washing is obtained with 112 crystal face as leading hexagonal FeS nanosheet precursor;FeS nanosheet precursor is dispersed in alkaline solution, by adjusting the content of alkaline solution, the pH value of final product is adjusted to 9~12, constant temperature stirring centrifugation, obtain FeS (112) / β-FeOOH heterojunction composite material.The application exposes FeS (112) high activity crystal face by alkali etching, realizes and β-FeOOH lattice matching bonding, forms triple synergy: interface Fe-O-Fe covalent bond inhibits oxidation, and the material oxidation rate is reduced by 80%; β-FeOOH is oriented nucleation in (112) face, and Cr (VI) reduction efficiency is increased by 2.3 times;Heterojunction accelerates electron transfer, constructs efficient reduction channel, and heavy metal removal rate reaches 2.3 times of physical mixing material, and simultaneously inhibits FeS self-oxidation, provides efficient path for heavy metal pollution treatment.