The invention discloses an experimental method for raising gas desorption property, characterized by based on the experimental study of gas absorption, desorption and permeability by existing non-mechanical method, using an experimental device which comprises a gas bottle, a pressure-tolerant gas pipe, a valve, a gas storage tank, a drying agent, a pressure sensor, a desorption pot, a positive electrode, a constant temperature water tank, a guide wire, a high-voltage variable-frequency power source, a vacuum pump, a data collection card, a computer, a rubber pipe, a measuring tube, and an Erlenmeyer flask, putting an experimental coal sample in the desorption pot, using the high-voltage variable-frequency electric field to change the physicochemical properties of the coal and allow the moisture in the coal and different charged ions dissolved in the water molecules to directionally move, thus free and adsorbed gas is increased, and the desorption property is raised. According to the invention, compared with the gas desorption property obtained by using a natural coal sample, when the high-voltage variable-frequency power source output voltage is 2kV and the frequency is 40Hz, the desorption is averagely raised by 11.42%.