The invention discloses a high biomass content epoxy resin composition. The high biomass content epoxy resin composition comprises, by mass, 100 parts of epoxidized plant oil, 1 to 100 parts of unsaturated bio-based dicarboxylic acid, 1 to 10 parts of a curing accelerator 1, and 1 to 10 parts of a radical initiator; wherein the curing accelerator 1 is tetrabutylammonium bromide, triphenylphosphine, 2-methylimidazole, 2,4,6-tris(dimethylaminomethyl)phenol, or boron trifluoride, and the radical initiator is a peroxy curing agent or an azo curing agent. The invention also discloses a curing method and applications of the high biomass content epoxy resin composition. The high biomass content epoxy resin composition is capable of improving material mechanical properties greatly; the main raw materials come from biomass renewable resources, are both green and nontoxic, and possesses certain positive functions in alleviating oil crisis and reducing carbon dioxide release; damage on human body is reduced, environmental pollution is reduced, and it is beneficial for industrialized application and especially application in the field of paint.