626 results about "Clinker (cement)" patented technology

The invention relates to the technical field of cement materials, in particular to a red-mud-containing steel slag composite cementing material and a preparation method thereof.The method comprises the steps that red mud, slag, steel slag, desulfurized gypsum and sulphoaluminate cement clinker are subjected to dry mixing to obtain an initial mixture; determining whether the excitation capability of the potential hydration activity reaches the standard or not based on the alkaline matching index, and adjusting the weight part of the sulphoaluminate cement clinker; adding a composite exciting agent to obtain activated slurry; determining whether the dispersion effect of the flocculation structure of the initial mixture is qualified or not based on the dispersion index of the flocculation structure, and adjusting the ball milling rotating speed; adding a polymer emulsion to obtain an initial composite cementing material; determining whether the synergistic enhancement effect of the polymer emulsion and the activated slurry is qualified or not based on the synergistic enhancement index, and adjusting the dripping rate of the polymer emulsion; the steel slag composite cementing material containing the red mud is obtained. The preparation stability of the red mud-containing steel slag composite cementing material is improved.

The invention discloses a light telegraph pole cement material and a preparation method thereof, and relates to the technical field of cement concrete. The method comprises the following steps: firstly, carrying out acid pickling, silane coupling agent grafting and nanoparticle vacuum impregnation treatment on shale ceramsite to obtain modified light ceramsite; the preparation method comprises the following steps: ultrasonically dispersing graphene oxide, compounding with Portland cement clinker and modified fly ash, and reacting with epoxy resin emulsion, a curing agent and a silane coupling agent to prepare organic-inorganic composite modified cement; the bamboo skeleton is subjected to silane coupling agent pretreatment to obtain a modified skeleton; then, mixing composite cement, an additive and water into slurry, adding the modified ceramsite and aggregate, and performing high-speed stirring and ultrasonic dispersion to form homogeneous concrete slurry; and finally, putting the modified bamboo skeleton into a mold, injecting the slurry, and performing centrifugal forming, steam curing and natural curing to obtain the cement material. The prepared lightweight telegraph pole cement material has excellent mechanical strength.

The application discloses a method for preparing auxiliary cementitious material and concrete products by carbonizing steel slag with industrial kiln tail gas, and steps are as follows: original steel slag is crushed, iron is removed, and screening is performed, so that a steel slag coarse-fine aggregate mixture and steel slag fine powder are obtained; the steel slag coarse-fine aggregate mixture is carbonized to obtain carbonized coarse aggregate and carbonized fine aggregate; the steel slag fine powder is ground to obtain steel slag micro-powder, the steel slag micro-powder is made into a cake to obtain a steel slag cake; the steel slag cake is subjected to carbonization treatment, and then is dried and ground to obtain a steel slag-based auxiliary cementitious material; the steel slag-based auxiliary cementitious material, silicate cement clinker powder and gypsum powder are mixed to obtain a new low-carbon cementitious material; the carbonized coarse aggregate, the carbonized fine aggregate, the new low-carbon cementitious material and sand are mixed and pressure-formed, and are subjected to carbonization treatment, so that a steel slag multi-stage carbonized product is obtained. The application effectively improves the carbonization rate and carbonization strength through the multi-stage carbonization technology, and avoids the occurrence of uneven carbonization caused by the fact that CO2 carbonization cannot reach the inside of particles.

The invention discloses a desulfurizing agent for a cement kiln as well as a production method and application of the desulfurizing agent. The desulfurizing agent is prepared from the following raw material components in percentage by weight: 88-96 wt% of limestone; 2-6 wt% of an iron raw material; 1-6 wt% of gypsum; and 0-4 wt% of a silicon-aluminum material. The desulfurizer is produced by utilizing a kiln line of a cement enterprise, is dried and ground with raw materials according to a mass ratio of 1: 100 to 3: 100, and then is put into a cement kiln system for cement clinker production, so that the emission concentration of sulfur oxides in kiln tail flue gas produced by sulphoaluminate cement clinker can be reduced from more than 2000mg / Nm < 3 > to less than 35mg / Nm < 3 >; and for other types of cement clinker, the content of the cement clinker can be reduced from 1000 mg / Nm < 3 > or above to 35 mg / Nm < 3 > or below, the desulfurization effect is stable, and the environment-friendly emission requirement can be continuously met.

This invention discloses a high-early-strength, low-shrinkage composite silicate cement and its preparation method, comprising: low-shrinkage silicate cement clinker, early-strength component, and gypsum component; the low-shrinkage silicate cement clinker is prepared from calcareous raw materials, siliceous-aluminous raw materials, ferrous raw materials, a first activator, and a mineralizer; its mineral composition includes: C3S 30-50 parts, C2S 20-40 parts, C3A 0.5-5 parts, and C4AF 10-25 parts; its particle size distribution characteristics are D10≥5μm, D90≤45μm, uniformity index of 1.2-1.6, and characteristic particle size of 25-30μm; the early-strength component is prepared from F-type fly ash or C-type fly ash, limestone, magnesium oxide, and a second activator; its mineral composition includes: C 20 A 13 M3S 350-65 parts, C2S 35-50 parts. The cement prepared by this invention not only has high early strength, but also has a small drying shrinkage rate.

The invention discloses a metal mine space carbon sequestration system and method based on upward filling of a segmented stope. A closed filling chamber is arranged in a staged blasting stope between a lower-stage filling body and an upper-stage unblasted ore body; an upper-stage drift roadway is arranged between the top of the closed filling chamber and the upper-stage unexploded ore body; a horizontal filling pipeline and a CO2 horizontal filling pipeline which are used for conveying the filling slurry and the CO2 gas to the closed filling chamber are arranged in the upper-stage access roadway, and the CO2 gas is mineralized to realize carbon sequestration through the filling slurry and the CO2 gas in the closed filling chamber. According to the method, the closed filling chamber is arranged in the goaf of the metal mine to seal and store the CO2 gas, the CO2 is utilized to be subjected to carbonization reaction with clinker minerals and hydration products in the filling cementing material, so that the dual purposes of'filling reinforcement 'and'filling carbon sequestration' are achieved, and environmental pollution cannot be generated in the whole CO2 gas sealing and storing process.

The invention discloses non-dispersible cement for underwater repair of concrete. The non-dispersible cement is prepared from the following raw materials in parts by weight: 30-50 parts of Portland cement clinker powder; 20-40 parts of functional grouting material dry powder; 15 to 30 parts of anti-dispersion reinforcing powder; 2-5 parts of a composite admixture; after the non-dispersible cement is mixed with water, the ratio of the underwater compressive strength of the formed underwater pouring slurry to the onshore standard curing compressive strength is not less than 0.7; therefore, the anti-dispersing agent is compounded with the carrier in advance to prepare stable powder, and the problems that the anti-dispersing agent is prone to caking on site and uneven in dispersion are solved. The single-component dry powder material can be used only by adding water and stirring, the construction is simple and convenient, and the dependence on the process and the cost is reduced while the excellent underwater anti-dispersion property and the early strength property are ensured.

The invention relates to the technical field of building engineering materials, in particular to an inorganic grouting material with adjustable curing time and a use method thereof. The inorganic grouting material provided by the invention comprises a main material and an adjusting material, the main material comprises the following components in parts by mass: 50-70 parts of sulphoaluminate cement clinker, 10-20 parts of quartz powder, 10-20 parts of gypsum, 3-5 parts of nano volcanic ash, 0.5-1 part of a water reducing agent and 0.1-1.5 parts of a retarder; the adjusting material comprises a composite coagulant and hydroxypropyl methyl cellulose. Through innovation of a material formula and innovation of a construction process, the problem that the grouting effect is poor due to the fact that a traditional grouting material cannot change the solidification time according to variable underground grouting scenes and requirements is solved; accurate grouting can be achieved under the conditions of different grouting depths, different crushing degrees, different diffusion radiuses, different mixing water temperatures, different coal and rock mass temperatures, different water inflow and the like.

The invention discloses a sprayable ECC for early-strength tunnel repair and a preparation method thereof. The sprayable ECC comprises the following components in parts by mass: 300-380 parts of Portland cement clinker, 25-40 parts of silica fume, 30-50 parts of superfine slag, 100-150 parts of quartz sand, 5-15 parts of a polycarboxylic acid water reducer, 5-10 parts of a nano CSH crystal nucleus suspension, 5-15 parts of mixed fibers, 0.4-1.2 parts of a polyether defoamer and 10-16 parts of an accelerator. And 72-92 parts of tap water. The jettable ECC has the technical requirements of ultrahigh early strength, ultrahigh ductility and jettable performance.

The present application belongs to the technical field of underground filling of metal mines, and particularly relates to an iron tailings powder-based cementitious material for mine full tailings cemented filling, a preparation method and application thereof. The geopolymer-based anti-cracking mortar is made of iron tailings ultrafine powder, ore powder, sulphoaluminate clinker, Portland cement clinker, desulfurization gypsum and methyl cellulose ether. The iron tailings powder-based cementitious material can completely replace ordinary Portland cement in full tailings filling and achieve better cementing effect than cement, thereby greatly reducing the consumption of cement and other cementitious materials, lowering the filling cost, reducing carbon emissions and increasing the utilization rate of tailings. The rheological properties, mechanical properties and durability of the full tailings cemented filling material made of the iron tailings powder-based cementitious material can meet the requirements of mine filling, and the material can achieve the effect of expansion and roof contact without adding external additives, thereby solving the shrinkage problem of cement-based filling materials.

The invention belongs to the technical field of cement production line transformation, and discloses a method for transforming a cement clinker production line into a coal gangue suspension calcination production line, the cement clinker production line comprises five stages of double-series preheaters and a decomposing furnace, the five stages of double-series preheaters are divided into A-row preheaters and B-row preheaters, a preheater in the column A is transformed into a preheating device of the coal gangue powder suspension calcination production line, a preheater in the column B is transformed into a gas-solid separation cyclone and a cooling device of the coal gangue powder suspension calcination production line, and a pipeline furnace is arranged between an air outlet of a decomposing furnace and an air inlet of the gas-solid separation cyclone. A decomposing furnace and a pipeline furnace are jointly transformed into a coal gangue suspension calcining furnace. According to the method, an obsolete cement clinker production line is transformed into a coal gangue suspension calcining production line with the working procedures of coal gangue grinding, conveying, metering, preheating, calcining, cooling and the like.

The present application aims at the problems of excessive consumption of traditional cement limestone resources, excessive energy consumption and high carbon emission, and provides a carbonated hardened low-calcium cement and a preparation and hardening method thereof, which is a hardening method for curing low-calcium cement by CO2 carbonation. The mass percentage composition of cement raw material components is: limestone: 60-70%, sandstone or clay or silica ash: 15-25%, phosphogypsum, fluorogypsum or desulfurization gypsum: 5-25%, component A: 0.5-2%. Component A is composed of the following raw material components in mass percentage: fluorite 0-50%, barium slag: 0-50%, lithium slag 0-50%, wood ash 0-50%, industrial sodium carbonate 0-30%. The composition design of carbonated hardened cement clinker minerals is C2S: 10-90%, C5S2$: 10-90%, C$: 0-5%, C4A3$: 0-10%, etc. In the present application, the limestone required for the cement clinker is lower than that of ordinary Portland cement clinker, the calcination temperature is reduced by 200-350 DEG C than that of ordinary Portland cement clinker, and the energy consumption and carbon emission are significantly lower than those of Portland cement; the low-calcium cement is hardened by CO2 carbonation curing, which can make the cement obtain excellent mechanical properties within 2 hours.

The invention provides a method for extracting vanadium by negative pressure roasting of dolomite and acid leaching of vanadium slag, and belongs to the technical field of resource recovery, the method comprises the following steps: crushing the vanadium slag, the dolomite and the vanadium slag to a certain particle size, mixing according to a certain proportion, and pelletizing; carrying out negative pressure roasting on the pellets by adopting a closed furnace to obtain roasted clinker and carbon dioxide; leaching and trapping the carbon dioxide through a calcium-containing aqueous solution to prepare light calcium carbonate; the roasted clinker is leached through sulfuric acid, and a vanadium-containing solution and leaching residues are obtained after leaching; extracting the vanadium-containing solution to prepare vanadyl sulfate; and carrying out magnetic separation on the leaching residues to obtain magnetite, and taking residual tailings as a cement raw material. According to negative pressure roasting, the normal pressure calcification roasting temperature is reduced, the cost is greatly saved, meanwhile, an iron component in the vanadium slag is converted into magnetic ferroferric oxide, the utilization rate of iron is increased, in addition, carbon dioxide enrichment is achieved through the closed furnace, a light calcium carbonate product is prepared through trapping and mineralization, and full-quantization high-value utilization of the vanadium slag component is achieved.

The invention discloses a process and system for preparing an auxiliary cementing material by calcining granular coal gangue coupled with a cement clinker sintering system, and the process comprises the following steps: treating large undisturbed coal gangue to obtain granular coal gangue, and quantitatively analyzing minerals in the granular coal gangue; feeding the granular coal gangue raw material into an activating calcining kiln for activating and calcining; then feeding into a grate cooler for cooling to obtain calcined activated coal gangue; wherein an activation calcination heat source comes from high-temperature section hot air of a grate cooler and hot air at an outlet of a C4 preheater, the proportion of the high-temperature section hot air, the hot air at the outlet of the C4 preheater and combustion-supporting air is controlled, and temperature and oxygen concentration adjustment at the activation calcination stage is achieved. According to the invention, the system for preparing the auxiliary cementing material by calcining the coal gangue is coupled with the original cement clinker sintering system, so that the on-line doping of the auxiliary cementing material in the cement clinker is realized, and meanwhile, the carbon emission is reduced.

The invention relates to a portland cement product for negative temperature and application thereof, in particular to application of a negative temperature product containing portland cement clinker and an anti-freezing agent in preparation of a negative temperature product capable of maintaining mechanical properties under a negative temperature condition. According to the present invention, the negative temperature environment applicability is strong, the temperature range of the conventional winter construction can be reached, the rapid strength development rate can be maintained in the negative temperature environment, the hydration heat release peak is advanced by 2-3 h, the construction requirement without the external heat source can be met, the hydration product mainly comprises ettringite and C-S-H, and the foundation is established for the cement product strength. The adopted mixing solution not only can prevent freezing, but also can accelerate coagulation. On one hand, the anti-freezing agent is added into the water, so that the vapor pressure of the water is changed, and the freezing point of the solution is reduced; and on the other hand, the anti-freezing agent contains a component for promoting hydration of the sulfur silicate cement, so that the sulfur silicate cement can be rapidly hydrated under a negative temperature condition, and the purposes of rapid setting and hardening and strength improvement of a cement product are achieved.

The invention discloses a condensation solar cement calcining kiln with a heat storage function and a working method thereof, and belongs to the field of energy and building material production, the condensation solar cement calcining kiln comprises a solar condenser, a cement calcining kiln, a solid heat storage material, a circulating heat release unit and a system control device, the solar condenser focuses solar energy through a daylighting opening of the cement calcining kiln, and cement clinker sintering is achieved; low-temperature gas discharged from the calcining kiln enters the raw material preheating tank to provide raw material preheating heat; the solid heat storage material in the kiln cavity absorbs sunlight and raw material radiant heat to store heat; when solar irradiation fluctuates, the circulating heat release unit enables air to exchange heat with a heat storage material, and high-temperature air required by continuous calcination is provided; the system control device regulates and controls the position, temperature and reaction process of the kiln body. Through integration of light condensation, heat absorption and heat storage, calcination of the zero-carbon cement is achieved, high-temperature CO2 gas and high-temperature air in the calcination process can be used for preheating raw materials, and gradient utilization of solar energy is achieved.

The application relates to a cement rotary kiln control parameter optimization method, which comprises the following steps: firstly, obtaining each target bit number data type related to the cement f-CaO content under the target cement rotary kiln working state; then, obtaining each to-be-referenced optimal control parameter vector based on a vector composed of each target bit number data type data value at each to-be-analyzed time point; then, obtaining the to-be-referenced optimal control parameter vector with the highest similarity to the current vector in each to-be-referenced optimal control parameter vector based on a current vector composed of the data values of each target bit number data type of the target cement rotary kiln under the current working state, and forming a target optimal control parameter vector; finally, adjusting each target bit number data type corresponding to the current working state of the target cement rotary kiln with the target optimal control parameter vector as the target; in this way, the working condition gradually approaches or reaches the historical best level, so that the output and quality of the clinker are effectively improved.

The invention relates to the technical field of building materials, in particular to a shotcrete coagulating early strength agent and a preparation method thereof. Comprising the following components in percentage by mass: 45%-70% of sulphoaluminate cement clinker, 20%-45% of an early strength exciting material, 5%-15% of a nano reinforcing material, 3%-9% of a magnesium oxide expanding agent, 1%-3% of a retarding material, 0.8%-3% of a water retention material and 0.1%-1% of a dispersing agent. The coagulant early strength agent for sprayed concrete provided by the invention takes powder as a main material, can significantly improve the compressive strength of the sprayed concrete at an extremely early age, enables the compressive strength of the sprayed concrete at 3h to be greater than or equal to 1.2 MPa, the compressive strength of the sprayed concrete at 8h to be greater than or equal to 10MPa, the compressive strength of the sprayed concrete at 1d to be greater than or equal to 15MPa and the compressive strength of the sprayed concrete at 28d to be free from shrinkage, and is relatively convenient to transport and store, relatively good in stability and free from layering and caking problems; and the manufacturing process is relatively simple.

A system and process for preparing low-carbon cement by grading and respectively grinding, comprising a grinding system and a mixing system. The grinding system comprises a first elevator (25), a first conveying device (26), a vertical mill (27), a first dust collector (29), and a first tail exhaust fan (30) which are sequentially connected. The first conveying device is used for conveying materials in the first elevator to the vertical mill. The grinding system further comprises the first dust collector, a ball mill (31), a second elevator (32), a separator (33), a second dust collector (34), and a conveying chute (36) which are sequentially connected. The grinding system can achieve relative disturbance of mixed materials in opposite directions, thereby improving the mixing efficiency of the mixed materials, and by means of the system provided with the vertical mill and the ball mill, grinding can be respectively conducted for the characteristics of different components of low-carbon cement, thereby ensuring that all the components of the low-carbon cement reach the optimal grinding degree, improving the performance of the cement, reducing the use amount of clinker, and reducing the carbon emission intensity of the cement.

The invention discloses a cement clinker f-CaO content prediction method and system based on transfer learning, and belongs to the field of cement industry intelligent manufacturing and soft measurement. According to the method, process variable data of three sub-systems in a cement production line are collected, a CNN-Transform prediction model is constructed, local time sequence features of the sub-systems are extracted through three independent one-dimensional convolutional neural networks, a cross-variable cross attention mechanism is introduced to capture a dynamic coupling relationship among the different sub-systems, and the dynamic coupling relationship among the sub-systems is determined. A Transform encoder is used for learning global time sequence dependence, and an f-CaO content prediction value is output; according to the method, a transfer learning strategy is adopted, a model is pre-trained on source domain large sample data, and a specific layer freezing and fine tuning strategy is adopted on target domain small sample data for adaptation, so that the prediction precision of the f-CaO content and the generalization ability across production lines are remarkably improved, and effective support is provided for real-time optimization control in the cement production process.

The utility model provides a dry process cement clinker firing device which comprises a preheating mechanism, a decomposing furnace, a material spraying assembly, a rotary kiln and a cooling machine, the preheating mechanism is used for preheating raw materials, the decomposing furnace is connected with the preheating mechanism, the decomposing furnace is used for receiving and decomposing the preheated raw materials, the material spraying assembly is connected with the decomposing furnace, and the rotary kiln is connected with the cooling machine. The material spraying assembly is used for evenly spraying preheated raw materials into the rotary kiln, the rotary kiln is used for calcining the raw materials to form clinker, the rotary kiln sequentially comprises a shell, at least two heat insulation layers and a heat-resistant lining from outside to inside, and the cooling machine is used for cooling the clinker. Due to the fact that the material spraying assembly evenly sprays the preheated raw materials into the rotary kiln, the raw materials can be heated more sufficiently and evenly in the rotary kiln, the calcining process is more thorough, and the clinker quality is further guaranteed. In addition, due to the fact that the rotary kiln comprises at least two heat insulation layers, the heat insulation effect of the rotary kiln is better, and the calcination process is more thorough.

The invention discloses microcapsule self-regeneration-based long-acting formaldehyde-removing cement and a preparation method thereof, and belongs to the field of building materials and environmental functional materials. The material is composed of Portland cement clinker and a functional composite additive, wherein the additive comprises Zn < 2 + > modified zeolite, a manganese-based catalyst, a pH-responsive sustained-release microcapsule and alpha-semi-hydrated gypsum. According to the invention, through the cooperation of zeolite selective adsorption, non-photocatalytic oxidation of the manganese-based catalyst in an alkaline environment and pH-triggered microcapsule self-regeneration, an adsorption-catalysis-regeneration function closed loop is formed, efficient and lasting removal of formaldehyde under a dark condition is realized, and the mechanical properties of a cement matrix are not damaged. According to the preparation method, the functional components are pre-compounded and then co-ground with the cement clinker, the process is simple, and the preparation method is suitable for industrial production.

The invention discloses high-durability quick-hardening concrete and a preparation method thereof, and belongs to the technical field of building materials. The concrete is prepared from the following raw materials: aluminoferrite cement, vitreous calcium aluminate clinker, a coagulant nucleation agent, a nano hybrid siliceous material, a calcium-magnesium composite expanding agent, a self-healing agent, a hydration heat regulating agent, a water reducing agent, an early strength agent, a defoaming agent, a thickening agent, a retarder, an air entraining agent and aggregate. The coagulating nucleating agent is prepared from semi-hydrated gypsum, ferrous sulfate and aluminum potassium sulfate; the nano hybrid siliceous material is prepared by reacting acidic silica sol with sodium methyl silicate at 40-60 DEG C for 1-3 hours. According to the high-durability quick-hardening concrete and the preparation method thereof, the iron aluminate cement, the vitreous calcium aluminate clinker, the coagulant nucleation agent, the nano hybrid siliceous material, the calcium-magnesium composite expanding agent, the self-healing agent and the hydration heat regulating agent are utilized to form a brand-new high-durability and high-adaptability quick-hardening system. The mechanical property, the volume stability and the durability are comprehensively superior to those of the traditional quick-hardening concrete.

The application provides a cement rotary kiln batching and feeding method for synergistically treating flue gas adsorbents, and relates to the technical field of cement clinker production, and comprises the following steps: sampling flue gas adsorbents for high-temperature thermogravimetric analysis, and establishing a batch fuel characteristic file; calculating a mixed equivalent calorific value according to the calorific values of new and old batches, and adjusting the mixed equivalent calorific value according to the calorific value difference gradient; sampling from a homogenizing bin discharge pipeline for high-temperature thermogravimetric analysis to obtain a measured calorific value and a real-time combustion characteristic index; comparing the measured calorific value with the calibrated mixed equivalent calorific value, and performing corresponding operations according to the deviation degree; establishing a heat load balance model to determine the optimal feeding amount of flue gas adsorbents and coal powder; determining the combustion type according to the real-time combustion characteristic index, and determining the mixing mode of flue gas adsorbents and raw materials, feeding after mixing according to the optimal feeding amount and raw materials, and simultaneously spraying coal powder into the cement rotary kiln. The scheme can improve the temperature stability of the cement rotary kiln, and realizes the recycling of flue gas adsorbents.

The invention relates to an on-line prediction method for carbon emission of a cement clinker calcination process, and belongs to the technical field of on-line monitoring of carbon emission. According to the method, the problem of difficulty in online accurate prediction caused by fuel raw material switching fluctuation, working condition time lag and extensive carbon emission data accounting is solved. According to the technical scheme, the method comprises the steps of obtaining and preprocessing multi-source data, constructing a multi-source carbon emission time-lag feature matrix, establishing a prediction model, and predicting and updating the model in real time. According to the method, minute-level online prediction and change trend real-time display of the carbon emission of the cement clinker calcination process are realized, carbon emission intensity analysis and diagnosis and standard exceeding early warning of a production level can be supported, and the method has the beneficial effects of accurate prediction, high adaptability and the like.

The present disclosure relates to a method for manufacturing a composite cement, the method comprising the steps of providing a cement raw meal, preheating the cement raw meal to provide a preheated cement raw meal, pre-calcining the preheated cement raw meal to provide a pre-calcined cement raw meal, sintering the pre-calcined cement raw meal in a rotary kiln to provide a cement clinker, and cooling the cement clinker in a cooler. Further, a step of adding the zeolite to the cement clinker in the cooler at a location that provides energy for calcining the zeolite to obtain the composite cement at the temperature of the cement clinker is included. Furthermore, the present disclosure relates to an apparatus (1) for manufacturing composite cement having a feed, transport and feed system (2), a cooler (4) and a kiln (5) wherein the kiln (5) feeds heated cement clinker (2000) into the cooler (4) and the feed, transport and feed system (2) feeds zeolite (1000) into the cooler (4), the zeolite (1000) is calcined in the cooler (4) by means of the heat provided by the cement clinker (2000). In addition, the present disclosure relates to composite cement manufactured with the method and / or in the apparatus.

To prevent CO from being generated due to incomplete combustion of a solid content when ammonia is supplied into a calcination furnace.SOLUTION: A method for producing a cement clinker includes: a first supplying step of supplying, into an interior (S) of a calcination furnace (30), a heat energy source containing a solid content by one or more first supply members (60); and a second supplying step of supplying, into the interior (S) of the calcination furnace (30), ammonia by one or more second supply members (70). A position at which the one or more second supply members (70) supply ammonia is arranged on an upstream side relative to a position at which the one or more first supply members (60) supply the heat energy source containing the solid content. A ratio of heat generation by the ammonia supplied into the preheater kiln (30) from the one or more second supply members (70) to a total heat generation by the heat energy sources supplied into the calcination furnace (30) from the one or more first supply members (60) and the one or more second supply members (70) is from 0.01 to 0.90.SELECTED DRAWING: Figure 2

The application discloses a kind of solid sealing chromium composite cementitious material and preparation method thereof, solid sealing chromium composite cementitious material includes the following mass percentage of substance: 65wt.%~75wt.% of clinker with heavy metal content, 20wt.%~34wt.% of poly-element auxiliary cementitious material, the rest is gypsum;Total chromium content in clinker with heavy metal content is greater than 150mg / kg;Poly-element auxiliary cementitious material includes the following mass percentage of substance: 30wt.%~50wt.% of microbial mineralization steel slag powder, 20wt.%~40wt.% of metakaolin, the rest is fly ash;Microbial mineralization steel slag powder is prepared by carbonic anhydrase producing bacteria and steel slag powder carbon fixation grinding.The application is based on the synergistic effect between clinker with heavy metal and the overall chemical composition of poly-element composite auxiliary cementitious material, and the pH value of solidified body is reduced by secondary hydration.

The utility model discloses a novel efficient heat exchange low-pressure-loss preheater which achieves the technical effects of reducing system resistance, improving separation efficiency and reducing C1 outlet temperature by increasing the height of a volute in a gradient mode, prolonging the length of an inner barrel in a proportion mode, optimizing the structure of an air inlet pipe and improving a material scattering device. The method is particularly suitable for energy-saving transformation of a 5000t / d cement clinker production line, and has the characteristics of low investment, quick effect, lasting effect and the like.

This invention provides an ultra-high ductility cement-based composite material for marine engineering and its preparation method. The ultra-high ductility cement-based composite material comprises, by weight, the following raw materials: 250-500 parts cement clinker, 400-600 parts fly ash, 200-300 parts mineral powder, 100-150 parts silica fume, 160-240 parts metakaolin, 600-900 parts quartz sand, 10-20 parts organic synthetic fiber, 20-30 parts organic rust inhibitor, 180-240 parts water, and 1-8 parts water-reducing agent. The organic rust inhibitor provided by this invention can inhibit steel corrosion and chloride ion intrusion into concrete through the dual effects of binding chloride ions and forming a passivation film, thereby improving concrete durability. By controlling the mix proportions of the four mineral admixtures and the dosage of the synthetic fiber component, the concrete can better balance high strength, high ductility, high durability, high flowability, and excellent resistance to deformation.