The invention relates the microwave radio-frequency radiation cross-linking biodegradation material, comprising starch, cellulose, A, aminocaprolactam or polyatomic alcohol, B, coupling agent, C, nucleation agent, D, undecylenic acid, calcium carbonate, natrii chloridum, and urea. The method comprises the following steps: mixing the raw material, cross linking with microwave radio-frequency device, foaming, forming, and getting the product. The invention solves the problems of no degradation, complex procedure, high cost and hard technology. The product has the advantages of good draftability, suppleness and obstructing property. The invention has the advantages of wide application area, completely degradation and non pollution. The invention also has the advantages of simple technology, easy operation and low cost.