The invention relates to a braking-free brick mainly prepared from polyaluminum chloride waste residues and red mud and a preparation method thereof. Raw materials for preparing the braking-free brick comprise the red mud, the polyaluminum chloride waste residues, an active mineral material, lime and gypsum. The preparation method comprises the following steps: uniformly mixing the raw materials in proportion, adding 8-12 parts of water, stirring, mixing, carrying out compression molding, sprinkling water and curing. The preparation method has the advantages that the red mud and the PAC (polyaluminum chloride) waste residue are used as the main raw materials, pulverized fuel ash, cement, the lime and the gypsum are added, so that the using amount of an excitant is reduced, the strength of the brick is improved, the usability of the braking-free brick can be improved, meanwhile the national standard requirements are completely satisfied, a gel material does not need to be added in a production process, the heat energy does not need to be consumed, the accumulation of the red mud and the PAC is reduced in a larger sense, and the pollution to environments due to the emission of the red mud and the PAC waste residues is solved.