The invention belongs to the technical field of functional materials and electrochemical
water treatment, and discloses bi-crosslinked carbon
aerogel as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing a water-
soluble polymer solution with a solution containing
metal cations, performing crosslinking to form gel, performing curing and crosslinking treatment to form bi-crosslinked gel, performing
freeze drying to obtain bi-crosslinked
aerogel, soaking the bi-crosslinked
aerogel in a solution of an organic ligand, and performing
carbonization treatment to obtain the bi-crosslinked carbon aerogel. The prepared bi-crosslinked carbon aerogel material is uniform in morphology, internal structures are mutually communicated, migration and
diffusion of
calcium ions in a
carbon layer are facilitated, the highest specific surface area reaches 1195.12 m < 2 > / g, the
calcium ion adsorption capacity is higher than 7.5 mg / g, the specific
capacitance can reach 230 F / g, and the bi-crosslinked carbon aerogel material has high specific
capacitance and excellent
calcium ion adsorption performance, can be used for removing hard particles in water, and can be applied to the field of
water treatment. The method has unique advantages in
water desalination, enrichment of specific ions and removal of heavy
metal ions and organic pollutants, and has a wide application prospect.