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1442results about "Sludge treatment by oxidation" patented technology

Apparatus and process for mediated electrochemical oxidation of materials

A unique apparatus unique apparatus and process that uses mediated electrochemical oxidation (MEO) for: (1) Destruction of: a) nearly all organic solid, liquid, and gases materials, except fluorinated hydrocarbons; b) all biological solid, liquid, and gases materials; c) and/or dissolution and decontamination (such as cleaning equipment and containers, etc.) of nearly all inorganic solid, liquid, or gas where higher oxidation states exist which includes, but is not limited to, halogenated inorganic compounds (except fluorinated), inorganic pesticides and herbicides, inorganic fertilizers, carbon residues, inorganic carbon compounds, mineral formations, mining tailings, inorganic salts, metals and metal compounds, etc.); and d) combined materials (e.g. a mixture of any of the foregoing with each other); henceforth collectively referred to as materials. (2) Sterilization/disinfection of equipment, glassware, etc., by destroying all existing infectious materials. (3) Dissolution of transuranic/actinide materials and/or destruction of the oxidizable components in the hazardous waste portion of mixed waste. (4) Generation of hydrogen and oxygen from MEO of materials. (5) Alteration of organic, biological, and inorganic materials by MEO to produce other compounds from these materials. The materials are introduced into an apparatus for contacting the materials with an electrolyte containing the oxidized form of one or more reversible redox couples, at least one of which is produced electrochemically by anodic oxidation at the anode of an electrochemical cell. The oxidized forms of any other redox couples present are produced either by similar anodic oxidation or reaction with the oxidized form of other redox couples present and capable of affecting the required redox reaction. The oxidized species of the redox couples oxidize the materials molecules and are themselves converted to their reduced form, whereupon they are reoxidized by either of the aforementioned mechanisms and the redox cycle continues until all oxidizable material species, including intermediate reaction products, have undergone the desired degree of oxidation. The entire process takes place at temperatures between ambient and approximately 100° C. The oxidation process may be enhanced by the addition of reaction enhancements, such as: ultrasonic energy and/or ultraviolet radiation.
Owner:SCIMIST LNC

Sludge anhydration and burning process, and its systematic device

The invention relates to a sludge drying and burning technique and its system devices, applying to the handling of active sludge in urban sewage treatment plants, its process flows through: wet sludge stock house, measuring bin, sludge mixer, sludge dryer, granular splitter, cooler, drying products storage bin, incinerator, smoke gas cleaning devices, which is characterized by: said incinerator is bubbling fluid bed incinerator with coal economizer, air heater fixed in its end part, high-heat smoke gas generated by burning is used to heat heat-conducting oil and cool air individually, and heat-conducting oil after being heated is transferred to sludge dryer through the circulating pump to dry wet-sludge. The invention is characterized by: take heat-conducting oil as heating medium, use the heat generated by burning dry sludge to heat heat-conducting oil and then dry wet-sludge to make full use of resources; the volume-reducing quantity after drying and burning could reach over 90%; the percentage of desulphurization in incinerator could reach 75% as a result of adopting two stage technology of sulfur removal, and the gross percentage of desulphurization meets national environmental legislation requirements. The invention accomplishes the resources, volume reduction, and innocence of sludge.
Owner:贵州筑信水务环境产业有限公司

Sludge-dewatering compound conditioning agent and application method thereof

The invention provides a sludge-dewatering compound conditioning agent and an application method thereof. The sludge-dewatering compound conditioning agent comprises a Fenton reagent or / and similar Fenton reagent and a skeleton construct, and the weight ratio of the Fenton reagent or / and similar Fenton reagent and the skeleton construct is 1: (0.05-300); and the skeleton construct adopts a powder body. The application method comprises the following steps: adding the Fenton reagent or / and similar Fenton reagent into sludge slurry, and mixing for oxidation; and adding the skeleton construct into the sludge slurry with the Fenton reagent or / and similar Fenton reagent, and mixing. Due to synergy of the Fenton reagent or / and similar Fenton reagent and the powder type skeleton construct, extracellular polymeric substances in sludge can be destructed effectively, the compressibility of organic substances can be reduced, and the sludge dewatering performance of the sludge-dewatering compound conditioning agent can be improved greatly. The procedures of the application method are simple, the conditions can be controlled easily, the sludge dewatering time can be shortened, and the large-scale treatment of the sludge can be realized.
Owner:UNIVERSTAR SCI & TECH SHENZHEN +1

Method for promoting sludge to be reduced by ozone

The invention relates to a method for promoting sludge to be reduced by ozone, in particular to a technology used for pretreating the sludge and accelerating anaerobic sludge digestion speed by utilizing ozone oxidation technique, which is widely applied to the sludge treatment technique of a sewage plant. The method comprises: the residual sludge of the sewage plant is concentrated and then treated by a sludge pretreatment reactor; due to the strong oxidizing property of ozone, the cell wall and the cell membrane of microorganism inside the sludge are broken, and a great deal of organic matter is released out of cells; after being treated by the ozone, the sludge enters into an anaerobic digestion reactor, and anaerobic digestion can be carried out in a closed anaerobic state; gas generated by digestion is treated by a gas purifying device, and methane can be obtained; after anaerobic digestion, the sludge is treated by flocculation and dehydration, and dewatering sludge can be obtained; then, final treatment can be carried out, for example, the sludge can be used for manufacturing agricultural fertilizer, bricks, porcelain granules or auxiliary fuel of fire coal; and anaerobic supernate is treated by biological filtering bed technique, so that the organic matter, ammonia and nitrogen in the solution can be removed.
Owner:NANJING UNIV OF TECH

Method for improving dewatering performance of excess sludge by combining biological acidification and Fenton-like oxidation

The invention relates to a method for improving dewatering performance of excess sludge by combining biological acidification and Fenton-like oxidation, which belongs to the technical field of sludge treatment. The method comprises that: under the condition of adding a sufficient quantity of substrates, indigenous acidification bacteria serving as inoculation liquid are cultured and acclimatized from sludge; the inoculation liquid is added to excess sludge in order to perform biological acidification on the sludge under an aerobic stirring condition in the presence of a sufficient quantity of substrates till the pH of the sludge is 2 to 3; under the catalytic action of Fe2+ and Fe3+, H2O2 produces strong oxidative free radicals and other Fenton-like oxidized sludge; Ca(OH)2 solution is added to the treated sludge to regulate the pH of the sludge to be between 6 and 7; and the treated sludge is dewatered by a plate-frame pressure filtration method or a centrifugal dewatering method in order to obtain dewatered sludge with water content between 65 and 75 percent. The combination of biological acidification and Fenton-like oxidation for improving the dewatering performance of excess sludge can improve reaction efficiency, shorten reaction time, increase treatment capacity and reduce cost for sludge treatment.
Owner:BEIJING FORESTRY UNIVERSITY

Wet sludge anhydration burning processing system and process

The invention relates to a wet sludge drying and incineration processing system. The system comprises a low-temperature pyrolytic reaction device, a centrifuging filtering device, a steam condensation device, a filtrate recovery device and a sludge incineration device; the low-temperature pyrolytic reaction device is used for carrying out low-temperature pyrolytic reaction between wet sludge and saturated steam in order to convert macromolecular organics in the wet sludge into low-molecular organics and destroy a sludge water-holding structure; the centrifuging device is used for carrying out centrifuging filtering to the wet sludge after pyrogenation; the steam condensation device is used for condensing and collecting bled steam converted from saturated steam in the low-temperature pyrolytic reaction device; the filtrate recovery device is used for collecting filtrate produced in the centrifuging device and for collecting condensed fluid from the steam condensation device; the sludge incineration device is used for incinerating semidry sludge after being dehydrated in the centrifuging device and insoluble gas remained in the steam condensation device as fuel. The system also relates to a process for carrying out the processing of wet sludge drying and incineration by adopting the processing system. The system and the process can solve the problem of sludge resource regeneration in a mode of environmental protection, energy conservation, high resource utilization rate and low operating cost.
Owner:SHENZHEN ECO SOLUTION TECH CORP

Resource regeneration processing method and equipment for urban sewage sludge

The invention discloses a resource treatment method for municipal sludge and equipment thereof. The method comprises the following steps that: the dried sludge is subject to carbonization treatment with a carbonization temperature range of between 450 and 650 DEG C and molded to produce a solid product; carbonization fractions in the carbonization treatment are reclaimed and a condensate is separated off; purified wood coal gas is comprehensively utilized; through a carbonization process adopting a biomass dynamic carbonization and pyrogenation comprehensive treatment technology, feeding, drying, carbonization, carbon generation, the dust removal of wood coal gas, condensation, washing and the separation of various byproducts can be continuously completed; carbonization equipment can realize automatic operation and can carry out resource treatment to biomass; the adopted process has strong adaptability to the variety and humidity of the biomass and has small loss of biomass and high treatment efficiency in the treatment process; as the process adopts a full-closed carbonization furnace, product yield is all products, wherein, the produced wood coal gas is used as fuel for drying, carbonization or power generation, thereby reducing production cost; and the whole system has perfect design and reasonable economical technology.
Owner:谢忠诚 +1

Silt pretreatment method for enhancing dehydration property and digestibility of silt

The invention relates to a silt pretreatment method for enhancing dehydration property and digestibility of silt and belongs to the field of sewage treatment. The invention is characterized in that when the method is used for enhancing the dehydration property of the remained silt, adding a peroxide solution to the silt (0.4-0.6 g H2HO/g dry silt), evenly stirring, and treating the silt by microwaves at 60-80 DEG C for 3-5 minutes; and when the method is used for enhancing the anaerobic digestion efficiency of the silt, adding a peroxide solution to the silt (0.8-1.2 g H2HO/g dry silt), evenly stirring, and treating the silt by microwaves at 80-120 DEG C for 5-8 minutes. The method enhances the dehydration property of the remained active silt and reduces the amount of the silt by utilizing the feature of high-speed high-efficiency heating and the strong oxidizing action of the free hydroxide radicals resulting from peroxide under microwave radiation. The method can also be used for enhancing the anaerobic digestion efficiency of the subsequent silt, thereby reducing the energy consumption and the amount of the silt. The method has the advantages of simple equipment, convenient operation and maintenance, does not produce any secondary pollution, and has wide application prospects in sewage treatment plants in large, medium-and-small-sized cities, and at sewage treatment stations in enterprises.
Owner:NINGBO UNIVERSITY OF TECHNOLOGY

Supercritical dissolved air cavitation equipment and method for reinforcing sludge reduction by adopting same

The invention provides supercritical dissolved air cavitation equipment and a method for reinforcing sludge reduction by adopting the same, belonging to the technical field of municipal sewage sludge treatment. The equipment is characterized in that when sludge flows through a shrinking spray pipe at a high speed, air is injected into a dissolved air cavitation cavity from an air suction pipe to be mixed with the sludge, then the air and the sludge enter a primary diffusion pipe and a secondary diffusion pipe in sequence and then are sprayed into an oxidation reaction kettle from cavitation nozzles, and finally the sludge subjected to dissolved air cavitation treatment is discharged from a sludge output pipe. The supercritical dissolved air cavitation equipment can operate in combination with a biochemical reaction tank, a reflux and excess sludge tank or a sludge homogenization tank. The equipment and the method have the beneficial effects that as a target vortex cavitation generator is combined with the oxidation reaction kettle, the conditions of supercritical wet oxidation reaction are achieved, the refractory organics in the sludge are directly decomposed into CO2, H2O and the like, and refractory organic macromolecular chains are broken into micromolecular chains and are further oxidized into fatty acids, so that the BOD (biochemical oxygen demand) / COD (chemical oxygen demand) ratio is increased, and favorable conditions are created for subsequent biochemical reaction, thus reducing the sludge; and after the equipment and the method are used by sewage plants, the sludge yield is reduced by 60-70%.
Owner:DONGGUAN YUANKONG ENVIRONMENTAL PROTECTION TECH CO LTD
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