Catalyst for treating waste water, method for preparing the same and process for treating waste water

Abstract

This invention discloses a method for oxidizing and / or decomposing organic and / or inorganic oxidizable substances in waste water by wet oxidation with a use of a catalyst, wherein the oxidizable substances are oxidized and / or decomposed with an oxygen containing gas in the presence of the catalyst under pressure such that said waste water retains the liquid phase thereof at temperature of 50 to less than 170° C.; the catalyst contains activated carbon; and controlling an oxygen concentration in an exhaust gas in the range from 0 to 5 vol %. The present inventive method is capable of treating waste water efficiently for a long period in a stable manner at the reduced temperatures and as compared with the substantially higher temperatures and pressures used in many of the prior art method.

Description

[0001] 1. Field of the Invention[0002] This invention relates to a process for treating waste water containing organic and / or inorganic oxidizable substances by wet oxidation with a use of a catalyst performed in the presence of an oxygen-containing gas, and more particularly pertains to a process for treating waste water efficiently for a long period in a stable manner by using a solid catalyst containing activated carbon and by regulating the oxygen concentration in an exhaust gas.[0003] This invention further relates to a process for suppressing deterioration of the catalytic activity of the solid catalyst at the time of temperature rising when starting up a operation of the wet oxidation and / or at the time of temperature lowering when suspending the operation by protecting the catalyst according to needs, or to a process for efficiently recovering the degraded catalytic activity of the solid catalyst containing activated carbon according to needs.[0004] 2. Description of the Rel...

AI Technical Summary

Benefits of technology

[0022] The present invention has been accomplished to solve these problems. Accordingly, an object of the present invention is to provide a catalyst for oxidizing and / or decomposing organic and / or inorganic oxidizable substances in the waste water by catalytic wet oxidation efficiently in a stable manner and the preparation method thereof.

[0023] Another object of the present invention is to provide a method for treating waste water efficiently for a long period in a stable manner by wet oxidation using a catalyst containing activated carbon at low temperature and under low pressure.

[0024] Further object of the present invention is to provide a method for suppressing deterioration of the catalytic activity of the solid catalyst at the time of temperature rising when starting up the operation of the wet oxidation and / or at the time of temperature lowering when suspending the operation of the wet oxidation.

[0025] Still further object of the present invention is to provide a method for efficiently recovering the deteriorated catalytic activity of the catalyst containing activated carbon.

[0031] Further object of the present invention can be accomplished by the method which is characterized in that a catalyst protection liquid which contains easily decomposable substances is supplied at the time of temperature rising when starting up a operation of the wet oxidation and / or at the time of temperature lowering when suspending the operation.

[0032] Still further object of the present invention is accomplished by the method which is characterized in that a catalyst recovering liquid which contains easily decomposable substances is supplied to the catalyst under temperatures in the range from 55.degree. C. to less than 200.degree. C.

Problems solved by technology

Biological treatment has a disadvantage in consuming a long time to decompose the oxidizable substances in the waste water.

Further, this treatment is limited to treat waste water of a low concentration.

The method demands a large space for the installation of facilities for diluting waste water.

Further, microorganisms that are used in the biological treatment are susceptible to change of the environment such as temperature.

These factors make it difficult to stably operate the waste water treatment for a long time.

Such a low temperature and low pressure condition contributes to loosening the requirements for reaction.

Therefore, it has been impossible to utilize activated carbon as a catalytic component for wet oxidation.

Specifically, in the case where a catalyst containing activated carbon is employed, it is often the case that the catalyst does not have heat resistance of resisting a high temperature such as 170.degree. C. or more.

Even if the catalyst exhibits a high catalytic activity at an initial stage of reaction, the catalytic activity deteriorates rapidly within 100 hours or less.

Therefore, utilization of the catalyst containing activated carbon has been practically impossible.

On the other hand, in the case where there is not provided sufficient measures for protecting the catalyst during its use even at a low temperature such as 170.degree. C. or less, the activated carbon itself is subjected to combustion due to existence of oxygen containing gas.

Consequently, the catalytic activity also deteriorates within a short period such as within one hundred to several hundreds hours.

Thus, utilization of the activated-carbon-containing catalyst was impossible in the conventional wet oxidation for treating waste water.

This technique is not applicable to treating an organic compound having two or more carbon atoms per molecule or inorganic compound.

Also, this publication does not fully consider durability (heat resistance) of the catalyst in which a precious metal is supported on activated carbon.

The above problems such as a possibility of combustion of activated carbon itself and deterioration of catalytic activity were also observed when treating waste water containing organic and / or inorganic oxidizable substances at the time of temperature rising by starting up the operation of the wet oxidation apparatus and / or at the time of temperature lowering by suspending the operation if the treatment is performed under the same oxidization atmosphere as in the conventional system.

As a result, it is likely that the catalytic activity of the catalyst containing activated carbon is deteriorated at the time of starting up the operation of the apparatus prior to actual treatment of waste water as well as during suspension of the operation of the apparatus, namely, suspension of supply of the waste water.

This technique, however, is not desirable in the aspect of cost performance and necessity of cumbersome operation.

There has also been a problem that the catalytic activity is lowered due to existence of oxygen that has remained in the apparatus or adsorbed to the catalyst even during non-supply period of oxygen-containing gas.

This publication, however, does not propose a technique of suppressing deterioration of catalytic activity.

In such a case, durability of the activated-carbon-containing catalyst is liable to deteriorate.

In the case where the decomposing rate of the oxidizable substances that have been adsorbed to the activated carbon is extremely slow, oxidation and decomposing ability of the catalyst gradually decrease during waste water treatment.

Further, in the case where waste water treatment is performed for a long period, a problem involved in waste water treatment such as disorder of the apparatus and erroneous operation of the apparatus cannot be avoided, which may deteriorate the catalytic activity of the activated-carbon-containing catalyst.

The above mentioned method, however, is not sufficient in recovering the catalytic activity of the activated-carbon-containing catalyst.

Conversely, this process may likely to cause deterioration of catalytic activity.

Further more the gaseous phase reduction employing hydrogen or carbon monoxide also has a problem because it is difficult to implement the reduction in a state that the catalyst is filled in a waste water treating apparatus as itself.

Such an arrangement, however, is practically unexecutable.

This recovering process, however, does not completely recover the catalytic activity of the activated-carbon-containing catalyst.

Conversely, this recovering process may cause deterioration of the catalytic activity and corrosion of the parts constituting the apparatus.

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