The invention relates to a solar thermochemical adsorption seasonal efficient energy storage device and method, and belongs to the technical field of solar thermal storage. When solar thermal energy is stored in summer, a solar thermal collector, a heating circulating pump, a heating switching valve and a solid-gas chemical reactor heat exchange coil are connected one another, a cooling tower, a cooling circulating pump, a cooling switching valve and a liquid accumulator heat exchange coil are connected one another, and solar efficient thermal storage is realized by converting solar thermal energy into chemical adsorption potential energy; and when solar thermal energy is released for supplying heat in winter, an internal reaction heat cascaded regeneration technology is carried out, a low-temperature reactor heat exchange coil, a heat regeneration circulating pump, a heat regeneration valve and a high-temperature liquid accumulator heat exchange coil are connected one another, a high-temperature reactor heat exchange coil, a heat supply circulating pump, a heat supply valve and a heat user are connected one another, and the warm-up heating to the outside through the stored solar heat is realized by converting chemical adsorption potential energy into thermal energy. Compared with the prior art, the device has the remarkable advantages that the energy storage density is high, the thermal loss is small during the seasonal energy storage period, the energy stored quality is enhanced, and the like.