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321 results about "Carbonatation" patented technology

Carbonatation is a chemical reaction in which calcium hydroxide reacts with carbon dioxide and forms insoluble calcium carbonate...

Method for preparing high-alkali value (TBN400) synthesized calcium alkyl benzene sulfonate

The invention provides a method for preparing high base number (TBN400) synthetic calcium alkyl-benzene sulfonate. The method comprises the following steps of: adopting a mixed acid of long-chain linear alkyl-benzene sulfonic acid and high-boiling heavy alkyl-benzene sulfonic acid, calcium oxide and/or calcium hydroxide, low-carbon alcohol, alkaline-earth metal halide or nitrate, and a mixture of alkaline-earth metal alkylphenol or alkaline-earth metal alkylphenate and polyisobutylene succinic anhydride for a neutralization reaction in the presence of a solvent and cutback oil at a temperature of between 40 and 80 DEG C; then, passing through carbon dioxide to a product of the neutralization reaction at a temperature of between 40 and 60 DEG C for a carbonation reaction; and producing high base synthetic alkyl-benzene sulfonate with a total base number (TBN) of 400mgKOH/g by adopting a process of a one-step method. The product is divided into high-base number (TBN400) synthetic alkyl-benzene sulfonate containing chlorine and high-base number (TBN400) synthetic alkyl-benzene sulfonate without the chlorine. The product produced by adopting the method with low viscosity, small turbidity, easy filtration, light color and no skin formation has the advantages of excellent high-temperature detergency, excellent anti-foaming property and excellent heat storage stability.
Owner:JINZHOU DPF TH CHEM CO LTD

Method for extracting metal gallium from coal ash

The invention relates to a method for extracting metal gallium from coal powder ashes, in particular suitable for the ashes of a circulating fluidized bed. In the method, a mother liquor of sodium meta-aluminate is obtained through acid dissolving and alkali dissolving; then aluminum hydroxide is obtained simultaneously during enriching and spearing the gallium through carbon content by steps. The main steps include as follows: CO2 is led into the mother liquor of sodium meta-aluminate to carry out carbon content decomposing; the primary separation between the aluminum and the gallium is realized by primary carbonatation to filter out sodium hydroxide; secondary carbonatation is carried out on the filtrate to obtain the deposit of the complex salt of gallium and aluminum; a sodium carbonate crystal is obtained after the filtered filtrate is condensed and vaporized; the deposit of the complex salt of gallium and aluminum is dissolved in the mother liquor of sodium meta-aluminate; the processes are repeated until the proportion of gallium and aluminum in the complex salt of gallium and aluminum is larger than 1 / 340; then the complex salt of gallium and aluminum is added into the NaOH liquor and electrolyzed, thus obtaining the metal gallium with a purity larger than 99.9 percent which reaches the level of 3; simultaneously, the byproducts of the aluminum hydroxide and the sodium carbonate during the process of carbonatation by steps are obtained. The method has the advantages of simple technique, easy operation, low cost, high comprehensive benefits, and the like.
Owner:JILIN UNIV

Carbonated steel slag aggregate and preparation method thereof

The invention discloses a carbonated steel slag aggregate and a preparation method thereof. The method comprises the following steps: sieving steel slag subjected to iron separation, taking particles with size between 0.5-25 mm particle for high pressure water flushing, and naturally drying the particles; immersing the dried steel slag particles in a mixed solution of 20-300 g/L caustic soda and 60-300 g/L sodium carbonate for 24 h, and maintaining the temperature at 20-60 DEG C; draining the soaked steel slag particles, immediately placing the particles in a sealed carbonation reactor, and introducing CO2 gas with purity over 99.9% for curing at the temperature of 70-90 DEG C for 0.5 h, and with the CO2 gas pressure at 0.2-0.5 MPa; cooling the steel slag particles subjected to carbonation treatment under natural conditions to room temperature, so as to obtain the carbonated steel slag aggregate. The steel slag aggregate treated by the method has compact surface structure to reduce water for concrete mixing; free magnesium oxide and free calcium oxide are conversed into carbonate precipitation to eliminate the hidden trouble of adverse stability; CO2 can be stored stably; the amount of natural aggregate is reduced to save nonrenewable resources; and the method has easily available raw materials and simple process.
Owner:UNIV OF JINAN

Method for catching carbon dioxide by pressurized fluidized bed combustion combined recycle generating system

InactiveCN101539037AReasonable realization of graded conversionRaise the inlet temperatureGas turbine plantsSteam engine plantsEngineeringCarbonatation
The invention relates to a method for catching carbon dioxide by a pressurized fluidized bed combustion combined recycle generating system, which is a method for catching the carbon dioxide by using CaO generated by calcining limestone or dolomite aiming at a gasification/semi-coking pressurized fluidized combustion combined recycle generating system of a coal pressurized part, coal enters into a pressurized fluidized bed gasification furnace using air as gasifying agent so as to be gasified to generate coal gas and semicoke, the coal gas is combusted after being purified to produce high-temperature fuel to enter a combustion turbine for applying work and generating electricity. Exhaust gas containing CO2 enters into a carbonatation furnace and a calciner double fluidized system, CO2 in the exhaust gas is catched by using circulation carbonatation/calcining reaction of CaO. Steam produced by a coal gas cooler and the double fluidized bed system enters into the turbine system for applying work and generating electricity, therefore, a fuel gas/steam combined recycle generating system catching CO2 is formed. The system has high generating efficiency and low energy consumption, and can realize near-zero exhaust of a plurality of pollutants of SO2, CO2 and the like.
Owner:SOUTHEAST UNIV

Technology for producing sodium bicarbonate from mirabilite

A technology for producing sodium bicarbonate from mirabilite comprises steps as follows: mirabilite and distillation waste liquor mixed liquor is used as a raw material, sodium carbonate is added to the solution after absorption of ammonia, magnesium, iron and calcium ions in the solution are removed after the solution is subjected to a precipitation reaction at 15-50 DEG C, and a refined solution is obtained; carbon dioxide is added to the refined solution for carbonatation, and sodium bicarbonate solids and heavy alkali mother liquor are obtained through separation after the refined solution is subjected to a replacement reaction at 15-50 DEG C; lime is added to the heavy alkali mother liquor, and ammonia gas, carbon dioxide, calcium sulfate and distillation waste liquor are obtained after distillation reaction at 15-120 DEG C; ammonia gas and carbon dioxide are recovered to ammonia absorption and carbonatation procedures respectively; the distillation waste liquor and mirabilite in Step A are mixed to be recycled. The technology has the characteristics that mirabilite is directly utilized, ammonia is recycled, the comprehensive utilization rate of distillation waste liquor waste is high, the production cost is low, the waste residue discharge is low, the technology is environment-friendly, and the like.
Owner:CHINA LIGHT IND INT ENG CO LTD

Method, system and equipment for gasification-liquefaction disposal of municipal solid waste

A gasification-liquefaction disposal method, system and equipment for MSW are disclosed. The method involves the MSW pretreatment of dehydrating and separating, thus reducing water and inorganic substance content of the waste. Then, the MSW is introduced into a plasma gasifier (23) by a carbon dioxide air-sealed feeding device (13) and gasified therein to obtain hydrogen-rich syngas. The hydrogen-rich syngas is then cooled, deacidified, dedusted and separated to obtain carbon dioxide. Then, the hydrogen-rich syngas is catalyzed to produce methanol product in a methanol synthesis reactor (52). The separated carbon dioxide is sent back to a carbonation reaction chamber (2007) of a gasification system to perform carbonation reaction with calcium oxide, thereby releasing heat to provide assistant heat energy for gasification and avoiding greenhouse gas from being discharged into environment. Exhaust gas is returned to the plasma gasifier (23) for remelting treatment, thus forming a closed-loop circulation production system and realizing the disposal of the MSW with zero discharge and no pollution, thereby avoiding dioxin pollution and converting the MSW to chemical raw materials and fuel needed by mankind The method, system and equipment are suitable for harmless and recycling disposal of MSW, industrial high polymer waste, composting waste and waste in waste sorting sites.
Owner:QUZHOU CITY GUANGYUAN DOMESTIC GARBAGE LIQUEFY TECH INST

Method for preparing lithium carbonate and ternary precursor by recycling waste ternary lithium battery

The invention discloses a method for preparing lithium carbonate and a ternary precursor by recycling a waste ternary lithium battery, and belongs to the field of solid waste recycling. Graphite and abinder carried in black powder obtained after pretreatment of a waste ternary battery are adopted as reducing agents, and the structure of the ternary material is destroyed through self-reduction phase inversion; lithium carbonate is converted into lithium bicarbonate which is easy to leach with water by adopting a carbonation water leaching method, so as to realize the preferential leaching of lithium; and sulfuric acid leaching is directly performed on the material subjected to lithium extraction without adding a reducing agent to obtain a nickel-cobalt-manganese solution. Copper, iron, calcium and other impurities in the solution are deeply removed through an impurity removal procedure, the content of aluminum and magnesium in the solution is controlled, then nickel, cobalt and manganese in the solution are extracted into an organic phase through synchronous extraction, a nickel sulfate solution, a cobalt sulfate solution and a manganese sulfate solution are obtained after reverseextraction is conducted through sulfuric acid, and a high-quality ternary positive electrode material precursor can be prepared after the metal proportion is adjusted. The method provided by the invention has the advantages of high recovery rate of valuable metals including lithium, nickel, cobalt and manganese, short flow, good product quality, economy and environment-friendliness.
Owner:UNIV OF SCI & TECH BEIJING

Method for preparing ultrafine alumina and coproducing and white carbon black by utilizing coal series kaolin

The invention belongs to the field of the comprehensive utilization of coal series kaolin, and in particular relates to a method for preparation of ultrafine alumina and white carbon black through an alkaline method by utilizing coal-based kaolin. The method comprises the following steps: carrying out crushing, roasting, alkaline leaching and filtration on the coal series kaolin, thereby obtaining a sodium silicate solution and alkali leaching residues; carrying out carbonatation treatment on the sodium silicate solution, thereby obtaining an orthosilicic acid precipitate filter cake and a desilicication solution; aging and roasting the orthosilicic acid precipitate filter cake, thereby obtaining the white carbon black; treating the alkali leaching residues by utilizing a soda-lime sintering process; carrying out self-pulverization, water quenching and filtration on the sintered clinker aggregates, thereby obtaining a NaAlO2 solution; carrying out the carbonation treatment on the NaAlO2 solution; and finally roasting the carbonated NaAlO2 solution, thereby obtaining the ultrafine alumina. According to the production method, the requirement to equipment is low; and all byproducts are recycled, so that the zero discharge is realized and the energy consumption is low. Thus, the method is economic and environment-friendly. In addition, the comprehensive utilization rate of resources and the additional value of the product are high.
Owner:CHINA UNIV OF MINING & TECH (BEIJING)

Ammonia circulation-based method and device for carbonating fixation of CO2 in coal-fired flue gas

The invention discloses an ammonia circulation-based method and device for carbonating fixation of CO2 in coal-fired flue gas. The method comprises the following steps that ammonia water is sprayed for absorbing CO2 in the coal-fired flue gas, part of absorption liquid generated in reaction is recycled for use, the rest of the absorption liquid flows into a regeneration pool through tower bottom so as to be reacted with added carbide slag slurry to be converted into calcium carbonate and ammonia water, after sediment through a sedimentation basin, supernatant liquor which is rich in ammonia flows into an absorption liquid mixed pool, and then a proper amount of ammonia water is added into the absorption liquid mixed pool so as to be sent to a CO2 absorption tower through a pump for reuse, after filtration of calcium carbonate sediment in the sediment pool, calcium carbonate is recycled, and the filtrate is sent to the absorption liquid mixed pool for reuse. According to the method, CO2 in the coal-fired flue gas is directly converted into calcium carbonate under normal temperature and pressure by taking ammonia water as an absorbent and taking carbide slag as a regenerant. Compared with the technology that CO2 of high concentration is obtained by ordinary ammonia water absorption and regeneration and carbonation seal is performed, the method has obvious technical economy advantages.
Owner:SOUTHEAST UNIV

Vanadium extraction method of high-calcium and high-phosphor vanadium slag clinker

The invention provides a vanadium extraction method of a high-calcium and high-phosphor vanadium slag clinker. The method comprises the following steps: crushing, grinding and screening the high-calcium and high-phosphor vanadium slag clinker with greater than 7wt% of CaO and greater than 0.6wt% of P2O5 until the particle size is 0.050-0.154mm, wherein the mass ratio of CaO to V2O5 is greater than 0.7, then carrying out carbonation leaching in a Na2O3 solution with a concentration of 3-20wt% or a NaHCO3 solution with a concentration of 4-25wt%, wherein a solid-liquid ratio is 1:1mL / g-1:15mL / g, the leaching temperature is 50-99 DEG C, the leaching time is 30-120 minutes and the stirring rate is higher than 150 revolutions per minute during leaching; carrying out solid-liquid separation to obtain a vanadium-containing leaching liquid; and then preparing a vanadium product by using the existing mature process of precipitating vanadium and deaminizing. According to the method, the leaching operation process is simple; a leaching agent is low in cost; a high vanadium leaching rate can be achieved; the leaching of phosphor in the vanadium slag clinker can be avoided; and the effective vanadium extraction of the high-calcium and high-phosphor vanadium slag clinker can be implemented.
Owner:UNIV OF SCI & TECH BEIJING

Method and device for immobilizing CO2 by enhancing mineral carbonation

InactiveCN102343199AFast catalytic reaction ratePromotes hydrationDispersed particle separationUltrasound - actionSlurry
The invention discloses a method and device for immobilizing CO2 in industrial tail gas by enhancing mineral carbonation. The device comprises a packed column absorber, a mineral leaching tank, a carbonation reactor and a belt type filter. The method comprises the steps of: enabling the industrial tail gas containing CO2 to enter the packed column absorber filled with immobilization carbonic anhydrase, rapidly transforming the CO2 into HCO3<-> under the catalysis action of the carbonic anhydrase; with a weak acidic solution containing the HCO3<-> as a mineral leaching agent, effectively leaching calcium ions from minerals in the mineral leaching tank under the action of ultrasonic waves to form a slurry enriching Ca<2+>; introducing the slurry enriching Ca<2+> into the carbonation reactor, adding a calcium-containing alkali material, regulating the pH of the slurry to be 7-9 to ensure that the HCO3<-> is transformed into CO3<2->, and generating a carbonation reaction with the Ca<2+> leached from the minerals to generate CaCO3. The invention can promote the CO2 to be rapidly transformed into the HCO3<->, can promote the calcium ions to be leached from the minerals and the carbonation reaction, and further realizes that the CO2 in the industrial tail gas is immobilized through direct carbonation under normal pressure.
Owner:SOUTHEAST UNIV

Method for extracting aniline and sodium carbonate and potassium carbonate from mixed alkaline residue in bipseudoindoxyl production

The invention discloses a method for extracting aniline, sodium carbonate and potassium carbonate from mixed caustic sludge in the production of indigo, which relates to a comprehensive treatment technology in the production of indigo. The adopted technical proposal is that the mixed caustic sludge forms aniline vapor and water vapor after calcination, water is on the upper layer and aniline is on the lower layer by natural settling after condensation, aniline is drawn out and put into a reaction kettle to produce sodium sulfanilate, dry mixed alkali produced is dissolved with water and filtrated, and CO2 is introduced for carbonatation treatment so as to produce potassium carbonate and sodium carbonate which are separated out after concentration, and finally the potassium carbonate and the sodium carbonate are dried, calcinated, naturally cooled and packaged. The method of the invention is characterized by simple extraction method, easy purchase of equipment, low cost, realization of cyclic economy, thus being beneficial to 'recycle and reclamation' and environmental protection. The method of the invention is applicable to the comprehensive treatment of indigo production industry.
Owner:重庆达华砼外加剂科技发展有限公司

Method for modifying surface of nano calcium carbonate

The invention discloses a method for modifying the surface of nano calcium carbonate. The method comprises the steps that 1, lime milk is added to a bubbling carbonatation reaction kettle, mixed gas containing carbon dioxide is introduced to the reaction kettle for a carbonatation reaction, carbonatation is conducted till the pH is equal to 7.0, carbonatation is completed, and a nano calcium carbonate suspension solution is obtained; 2, a stabilizer is added to the nano calcium carbonate suspension solution, the temperature is controlled within 50-60 DEG C, and heat preservation is conducted for 20-30 min; 3, a fatty acid modifier is heated and melted in water, an emulsifier is added to the fatty acid modifier, stirring is conducted for 10-30 min, and a modifier emulsion is obtained; 4, the nano calcium carbonate suspension solution obtained in the second step is added to the modifier emulsion, stirring is conducted for 30-60 min, and then through filter-pressing dehydration, drying and smashing, a nano calcium carbonate product is obtained. The prepared nano calcium carbonate has the advantages of good dispersity and processability, low oil absorption value, high thixotropy and activation rate, good stability, pH value close to neutral and the like. The method is low in production cost and simple in technology, facilitates industrial production and has good economic, social and ecological benefits.
Owner:ANHUI PROVINCE XUNCHENG CITY HUANA NEW MATERIAL TECH CO LTD

Novel method for comprehensively utilizing potassium feldspar

The invention discloses a novel method for comprehensively utilizing potassium feldspar. According to the method, NaOH-Na2CO3 is used for being mixed with sub-molten salt to decompose the potassium feldspar, and potassium feldspar decomposing mother liquid and kankrinite are obtained; the potassium feldspar decomposing mother liquid is subjected to carbonatation and filtration to obtain filter liquid containing potassium bicarbonate and salic filtering slag; filtering liquid is subjected to evaporation, crystallization and drying, and potassium carbonate can be obtained; meanwhile, the salic filtering slag is subjected to supplementing addition of KOH, Al(OH)3 and H2O for regulating the mixture ratio of the K2O/SiO2, the Al2O3/SiO2 and the H2O/SiO2; at a certain temperature, aging and crystallization are performed for a period of time; W molecular sieves are synthesized. The method has the characteristics that the decomposing temperature is low; the potassium ion dissolving rate is high; the decomposing mother liquid can be easily acidified; the product added value is high; the raw material utilization rate is high; no waste liquid and no waste slag are produced. The method conforms to the green production principle, and has good potential economic benefits.
Owner:FUJIAN NORMAL UNIV +1

High basic value (TBN300) sulfurized calcium alkyl phenate and preparation thereof

The invention relates to a high base number (TBN300) sulfuration alkylphenol calcium and a preparation method thereof; the chemical structural formula of the sulfuration alkylphenol calcium is shown at right, and alkyl phenolic compound, shielding phenolic compound, calcium oxide and/or calcium hydroxide and sulfur are put into a system containing solvent and diluent oil to have sulfuration/neutralization reaction to generate phenate intermediate; carbon dioxide is pumped into the system to have carbonatation reaction; alkyl polylol is added to take part in the reaction when the sulfuration/neutralization reaction is carried out, or the alkyl polylol is respectively added to take part in the reactions when the sulfuration/neutralization reaction and the carbonatation reaction are carried out; long chain carboxylic acid is added to take part in the reaction when the sulfuration/neutralization reaction or the carbonatation reaction is carried out, or the long chain carboxylic acid is respectively added to take part in the reactions when the sulfuration/neutralization reaction and the carbonatation reaction are carried out; the products are refined to prepare the finished goods. The sulfuration alkylphenol calcium is characterized by high base number, low viscosity and precipitation number, good heat storage stability, and the like; as having excellent cleanliness, hydrolysis invariability, alkali retentivity and good inoxidability, the sulfuration alkylphenol calcium causes no environmental protection problem when in use, and belongs to environment-friendly products; as one-step technique is adopted, the reactions are moderate, and filtration is easy.
Owner:JINZHOU DPF TH CHEM CO LTD

Comprehensive iron-aluminium paragenetic mineral utilization method

A comprehensive iron-aluminium paragenetic mineral utilization method belongs to the technical field of metallurgy. The comprehensive iron-aluminium paragenetic mineral utilization method is carried out according to the following steps: iron-aluminium paragenetic mineral is ground and made into pellets, and reducing gas is filled to pre-reduce the pellets, so that pre-reduced mineral is obtained;the pre-reduced mineral and lime are put into a reduction and melting furnace, and with oxygen as carrier gas, pulverized coal is jetted to carry out melting and reduction, so that molten iron and high-temperature aluminium-containing molten slag are obtained; the high-temperature aluminium-containing molten slag is cooled to normal temperature and naturally powdered, so that slag is obtained, and the slag is put into sodium carbonate solution and leached, so that leachate and leaching residue are obtained; the leachate is desiliconized under normal pressure and desiliconized under medium pressure, so that refined liquor is obtained; CO2 is filled into the refined liquor to carry out carbonation decomposition, so that decomposed mother liquor and aluminium hydroxide are obtained, and the aluminium hydroxide is roasted, so that alumina is produced; sodium carbonate is added into the decomposed mother liquor to replenish alkali, and the produced sodium carbonate solution is used for leaching. The comprehensive iron-aluminium paragenetic mineral utilization method not only can guarantee the high-efficiency dissociation and extraction of iron and aluminium, but also is feasible technically and economically, and the iron-aluminium paragenetic mineral resource in China is effectively and comprehensively utilized.
Owner:GUIZHOU BRANCH CHINA ALUMINUM IND +1
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