749results about "Gas purification with selectively adsorptive solids" patented technology

Systems for converting a carbonaceous feedstock into a plurality of gaseous products are described. The systems include, among other units, two separate gasification reactors to convert a carbonaceous feedstock in the presence of an alkali metal catalyst into the plurality of gaseous products including at least methane. Each of the gasification reactors may be supplied with the feedstock from a single or separate catalyst loading and/or feedstock preparation unit operations. Similarly, the hot gas streams from each gasification reactor may be purified via their combination at a heat exchanger, acid gas removal, or methane removal unit operations. Product purification may comprise trace contaminant removal units, ammonia removal and recovery units, and sour shift units.

A low-temperature gasification system comprising a horizontally oriented gasifier is provided that optimizes the extraction of gaseous molecules from carbonaceous feedstock while minimizing waste heat. The system comprises a plurality of integrated subsystems that work together to convert municipal solid waste (MSW) into electricity. The subsystems comprised by the low-temperature gasification system are: a Municipal Solid Waste Handling System; a Plastics Handling System; a Horizontally Oriented Gasifier with Lateral Transfer Units System; a Gas Reformulating System; a Heat Recycling System; a Gas Conditioning System; a Residue Conditioning System; a Gas Homogenization System and a Control System.

Systems to convert a carbonaceous feedstock into a plurality of gaseous products are described. The systems include, among other units, four separate gasification reactors for the gasification of a carbonaceous feedstock in the presence of an alkali metal catalyst into the plurality of gaseous products including at least methane. Each of the gasification reactors may be supplied with the feedstock from a single or separate catalyst loading and/or feedstock preparation unit operations. Similarly, the hot gas streams from each gasification reactor may be purified via their combination at a heat exchanger, acid gas removal, or methane removal unit operations. Product purification may comprise trace contaminant removal units, ammonia removal and recovery units, and sour shift units.

Systems to convert a carbonaceous feedstock into a plurality of gaseous products are described. The systems include, among other units, four separate gasification reactors for the gasification of a carbonaceous feedstock in the presence of an alkali metal catalyst into the plurality of gaseous products including at least methane. Each of the gasification reactors may be supplied with the feedstock from a single or separate catalyst loading and/or feedstock preparation unit operations. Similarly, the hot gas streams from each gasification reactor may be purified via their combination at a heat exchanger, acid gas removal, or methane removal unit operations. Product purification may comprise trace contaminant removal units, ammonia removal and recovery units, and sour shift units.

Systems to convert a carbonaceous feedstock into a plurality of gaseous products are described. The systems include, among other units, three separate gasification reactors for the gasification of a carbonaceous feedstock in the presence of an alkali metal catalyst into the plurality of gaseous products including at least methane. Each of the gasification reactors may be supplied with the feedstock from a single or separate catalyst loading and/or feedstock preparation unit operations. Similarly, the hot gas streams from each gasification reactor may be purified via their combination at a heat exchanger, acid gas removal or methane removal unit operations. Product purification may comprise trace contaminant removal units, ammonia removal and recovery units, and sour shift units.

The present invention provides a control system for the conversion of carbonaceous feedstock into a gas. In particular, the control system is designed to be configurable for use in controlling one or more processes implemented in, and/or by, a gasification system for the conversion of such feedstock into a gas, which may be used for one or more downstream applications. Gasification processes controllable by different embodiments of the disclosed control system may include in various combinations, a converter, a residue conditioner, a recuperator and/or heat exchanger system, one or more gas conditioners, a gas homogenization system and one or more downstream applications. The control system operatively controls various local, regional and/or global processes related to the overall gasification process, and thereby adjusts various control parameters thereof adapted to affect these processes for a selected result. Various sensing elements and response elements are therefore distributed throughout the controlled system and used to acquire various process, reactant and/or product characteristics, compare these characteristics to suitable ranges of such characteristics conducive to achieving the desired result, and respond by implementing changes to in one or more of the ongoing processes via one or more controllable process devices.

The present invention provides a gas conditioning system for processing an input gas from a low temperature gasification system to an output gas of desired characteristics. The system comprises a two-stage process, the first stage separating heavy metals and particulate matter in a dry phase, and the second stage including further processing steps of removing acid gases, and/or other contaminants. Optional processes include adjusting the humidity and temperature of the input gas as it passes through the gas conditioning system. The presence and sequence of processing steps is determined by the composition of the input gas, the desired composition of output gas for downstream applications, and by efficiency and waste minimization.

The present invention relates to processes for preparing gaseous products, and in particular methane, via the catalytic hydromethanation of a carbonaceous feedstock in the presence of steam, syngas and an oxygen-rich gas stream.

The invention discloses a coking furnace capable of recycling heat energy, and the coking furnace comprises a furnace body, an exhaust gas recycling system and a raw coal gas treatment system, wherein the furnace body sequentially comprises a coal feeding segment, a rapid coal heating segment, a raw coal gas leading-out segment, a coal carbonization coking segment, a coke quenching and tempering segment, a dry coke quenching segment and a coke discharging segment from top to bottom; the exhaust gas recycling system comprises an exhaust gas leading-out unit, an exhaust gas heat exchanger, a commutator and the like; and the raw coal gas treatment system comprises a raw coal gas leading-out unit. By using the coking furnace disclosed by the invention, continuous coal carbonization coking canbe achieved and the exhaust gas after combustion is used for dry coke quenching in the furnace; pre-dried coal can be quickly heated to 300 DEG C during entering the furnace, the coal is carbonized and coked in the furnace body, and the exhaust gas generated by self-combustion is used for dry coke quenching at the furnace bottom after the exhaust gas is cooled by heat exchange with air, thus continuously producing coke; the pollution is less in the production process; the coal industrial chain is extended, the coking cost is lowered, the coking coal types are broadened, and the product quality is improved; the profit margins are expanded in a large extent; and the maintenance cost is low.

A method of producing synthesis gas by introducing a feed material to be gasified into a gasification apparatus comprising at least one fluidized component operable as a fluidized bed, wherein the gasification apparatus is configured to convert at least a portion of the feed material into a gasifier product gas comprising synthesis gas; and maintaining fluidization of the at least one fluidized component by introducing a fluidization gas thereto, wherein the fluidization gas comprises at least one component other than steam. A system for producing synthesis gas is also provided.

A gasifier is disclosed combining a fixed bed gasification section where coarse fuel is gasified and an entrained flow gasification section where fine fuel is gasified. The fixed bed section includes upper and lower sections. Coarse fuel is devolatilized in the upper fixed bed section and subjected to elevated temperatures sufficient to crack and destroy tars and oils in the effluent gases. The entrained flow gasification section is disposed in a lower plenum adjacent the lower fixed bed section. A plurality of injection ports are configured to introduce oxygen, steam, or air into different sections of the gasifier to control temperature and operating conditions. Activated carbon may be formed in the upper fixed bed section and in the entrained flow section. The activated carbon may be used as a sorbent to remove pollutants from the effluent gases. The gasifier may be used with various coarse and fine fuel feedstocks.

Systems and processes for producing synthesis gas. A carbonaceous feedstock can be combined with one or more low-oxygen carrier fluids having a high heating value. The feedstock and carrier fluid, in the presence of one or more oxidants, can be gasified to provide a synthesis gas. In one or more embodiments, at least a portion of the synthesis gas can be recycled for use as the carrier fluid.

A Waste to Liquid Hydrocarbon Refinery System that transforms any municipal solid wastes and hazardous industrial wastes, Biomass or any carbon containing feedstock into synthetic hydrocarbon, particularly, but not exclusively, diesel and gasoline and/or electricity and co-generated heat, comprising three major subsystems: i) the Pyro-Electric Thermal Converter (PETC) (10) and Plasma Arc (PA) waste and biomass gasification subsystem (1); ii) the hydrocarbon synthesis subsystem (2); and iii) the electricity generation and heat co-generation subsystem (3).

A system and process are disclosed for the controlled combustion of a wide variety of hydrocarbon feedstocks to produce thermal energy, liquid fuels, and other valuable products with little or no emissions. The hydrocarbon feeds, such as coal and biomass, are first gasified and then oxidized in a two-chamber system/process using pure oxygen rather than ambient air. A portion of the intermediate gases generated in the system/process are sent to a Fischer-Tropsch synthesis process for conversion into diesel fuel and other desired liquid hydrocarbons. The remaining intermediate gases are circulated and recycled through each of the gasification/oxidation chambers in order to maximize energy production. The energy produced through the system/process is used to generate steam and produce power through conventional steam turbine technology. In addition to the release of heat energy, the hydrocarbon fuels are oxidized to the pure product compounds of water and carbon dioxide, which are subsequently purified and marketed. The system/process minimizes environmental emissions.

Disclosed is a process for humidifying syngas to achieve a water to carbon monoxide molar ratio in the product syngas within a desired range and in which the molar ratio which can be varied over time in response to changes in downstream syngas requirements. The raw syngas is produced by reacting a carbonaceous material with oxygen, water, or carbon dioxide and can be combined with a diluent to produce a diluted syngas stream which can be cooled and contacted with liquid water to give a humidified syngas. The H₂O:CO molar ratio of the humidified syngas may be adjusted in response to time-varying downstream syngas requirements by changing the amount and/or temperature of the diluent that is combined with the raw syngas stream, by adjusting quench and heat exchange conditions, or a combination thereof. The application of the process to the coproduction of chemicals and power are also disclosed.

The invention concerns a method and a plant for producing hydrocarbon based fuels from waste and biomass including wood and/or other cellulose containing biomass, where biomass and/or waste is gasified in anaerobic conditions, heating the formed syngas in for decomposition and subsequent condensation in anaerobic conditions, subjecting the heat treated biosyngas to cleaning measures for removing elements/compounds which are poisonous towards the catalysts of the Fischer-Tropsch synthesis, and passing the cleaned heat treated biosyngas through a Fischer-Tropsch synthesis for production of biofuels.

The present invention provides for a process for purifying carbon monoxide-containing gas streams that contain impurities such as hydrocarbons by using a cryogenic adsorption process. Preferably this process is a temperature swing adsorption process at cryogenic temperatures below −75° C. Alternatively, the carbon monoxide-containing gas streams may be purified using the cryogenic adsorption process with membrane separation units or vacuum swing adsorption units or cryogenic distillation.

A self-sustaining process for producing liquid fuels from biomass in which the biomass is hydropyrolyzed in a reactor vessel containing molecular hydrogen and a deoxygenating catalyst, producing a partially deoxygenated pyrolysis liquid, which is hydrogenated using a hydroconversion catalyst, producing a substantially fully deoxygenated pyrolysis liquid and a gaseous mixture comprising CO and light hydrocarbon gases (C₁-C₄). The gaseous mixture is reformed in a steam reformer, producing reformed molecular hydrogen, which is then introduced into the reactor vessel for hydropyrolizing the biomass. The deoxygenated liquid product is further processed to produce diesel fuel and gasoline.

The invention discloses a method for preparing liquefied natural gas by converting raw materials of coke oven gas and blast furnace gas. In the technology, the coke oven gas and the blast furnace gas are taken as the raw materials, the raw materials are subjected to normal-temperature normal-pressure dry desulfurization, gas compression, gas adsorption purification, gas isothermal-adiabatic serial methanation, gas adsorption drying and demetalization, freezing liquefication separation and other technical processes, and high-quality liquefied natural gas with the purity of over 99 percent is produced. By the technology, harmful impurities such as sulfur, naphthalene, tar, benzene, mercury and the like in the gas can be efficiently and easily removed fully at low cost, and components with low value, such as H2, CO, CO2 and the like are completely converted into required CH4 component with high value, so the method has the characteristics of low requirement on quality of feed gas, high yield of liquefied natural gas product, high product purity, low production energy consumption, no environmental pollution, reliable flow, low investment, simple operation and good economic benefit.

The present invention is directed to a process for treating, reducing, and/or stabilizing various wastes or flue gases. In one embodiment, the process is directed to treatment of alkali bearing wastes that include nitrate and/or nitrite-rich wastes. Optionally, the disclosed method can be utilized for treatment of hazardous wastes, including radioactive hazardous waste compounds. In general, the present invention includes processing a waste or gaseous stream with the addition of suitable carbon-containing additives to treat and reduce nitrogen-containing compounds in the waste. Additives may be gaseous, liquid or solid reduction-promoting agents, catalysts, and the like. The reaction products obtained from the process of the invention include mainly alkali carbonate, nitrogen, hydrogen, carbon monoxide and carbon dioxide.

Systems, compositions, and methods for removing a substance or substances from a material, such as a gas or liquid material, are described. The compositions can comprise composite removal particles. In some embodiments, the composite removal particles can be comprised of support particles made from an inexpensive carrier material, and a reactive particle borne on the support particle. The reactive particle reacts with the substance or substances in the material. The reacted composite removal particles can then be removed from the material, which reduces the amount of the substance or substances present in the material. The composite removal particles are useful for removing pollutants, such as mercury, from exhaust gases, such as flue gas from a power plant combustion unit, and from other materials such as natural gas, liquefied natural gas, fuels, hydrocarbons, petrochemicals, and refinery streams.