This invention discloses a Co4S3 / Ni3S2@C-CNF catalytic material, its preparation method, and its application. The method includes: 1. Dissolving Ni(NO3)2·6H2O, Co(NO3)2·6H2O, and
urea in a
mixed solution of isopropanol and deionized water, stirring until homogeneous, and then transferring the solution to a hydrothermal reactor. Maintaining the temperature at 100–120°C for 12–16 h, followed by washing and
drying, yields a basic
carbonate; 2. Dissolving the basic
carbonate and
thioacetamide in
anhydrous ethanol and stirring until homogeneous, transferring the solution to a hydrothermal reactor, maintaining the temperature at 120–130°C for 6–12 h, followed by washing and
drying, yields NiCo2S4; 3. Weighing
hydrochloric acid... 4. Mix
dopamine and NiCo2S4, add
Tris solution to the mixture, stir in the dark to form NiCo2S4@PDA solution, filter to obtain NiCo2S4@PDA
composite material; 5. Disperse
bacterial cellulose BC and NiCo2S4@PDA
composite material in deionized water and stir evenly, dry to obtain NiCo2S4@PDA / BC
composite material; 6. Place NiCo2S4@PDA / BC composite material in a
tube furnace and carbonize at high temperature to obtain Co4S3 / Ni3S2@C-CNF composite material, which has good
adsorption effect on sulfides and improves the electrochemical performance of Li-S battery.