The invention belongs to the technical field of
resource utilization of industrial by-products and preparation of inorganic functional materials, and discloses a method for preparing high-purity
magnesium metavanadate based on synergistic conversion of the industrial by-products.
Ammonium metavanadate extracted from a chlorination process
titanium dioxide byproduct
hydrochloric acid, a thermal power
plant magnesium desulfurization byproduct
magnesium sulfite and an aluminum
oxide process is used as a
raw material, and the method sequentially comprises the following steps: dissolving
ammonium metavanadate in hot water, and acidifying with the byproduct
hydrochloric acid to obtain an acidic
vanadium-containing solution; adding a byproduct
magnesium sulfite under heating and stirring, carrying out a deep
impurity removal reaction, and carrying out
solid-liquid separation to obtain a purified solution; adjusting the pH value of the purified liquid to be nearly neutral to initiate a synthetic reaction; directional
crystallization is carried out by adopting programmed cooling and combining
seed crystal induction; and separating, washing and
drying to obtain the high-purity magnesium metavanadate. According to the method, synergistic high-value utilization of three industrial byproducts is achieved, the process is simple, the cost is low, the method is
environmentally friendly, the purity of the obtained product is larger than or equal to 99.2%, the
crystal form is regular, and the method is suitable for catalysts or
electrode materials.