The invention belongs to the technical field of high-performance
polyurethane elastomers, and discloses a super-strong and super-tough thermosetting
polyurethane elastomer capable of being self-repaired and recycled as well as a preparation method and application of the super-strong and super-tough thermosetting
polyurethane elastomer.
Polycaprolactone is used as a
soft segment, 4, 4 '-dicyclohexylmethane diisocyanate is used as a hard segment,
dibutyltin dilaurate is used as a catalyst, oxalyl dihydrazine and
carbohydrazide are used as chain extenders, and 3-
aminophenylboronic acid is used for blocking, so that a polyurethane
straight chain is generated through reaction; and carrying out
vacuum drying and
dehydration to obtain the super-strong and super-tough thermosetting
polyurethane elastomer which has
boric acid ester bonds and can be self-repaired and recycled. The
polyurethane elastomer forms a double dynamic network of
hydrogen bonds and
boric acid ester bonds, dissociation and recombination under
thermal stimulation can be achieved, and the self-repairing performance of the
elastomer is achieved. Meanwhile, strong multiple
hydrogen bond interaction is formed between the two
hydrazide chain extenders, so that a sample is endowed with excellent energy dissipation capability, and excellent mechanical properties are achieved.