Application of silver-based cationic energy-containing metal organic framework as laser direct detonating agent composition

A metal-organic framework and laser direct technology, applied in explosives, explosives processing equipment, offensive equipment, etc., can solve problems such as accidental explosions, personnel and property losses, and achieve low ignition time, high product quality, and good safety.

Active Publication Date: 2019-11-15
INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the primary explosives used in my country mainly include lead azide, metal salts of picric acid and stefanic acid, etc., but most of the

Method used

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  • Application of silver-based cationic energy-containing metal organic framework as laser direct detonating agent composition
  • Application of silver-based cationic energy-containing metal organic framework as laser direct detonating agent composition
  • Application of silver-based cationic energy-containing metal organic framework as laser direct detonating agent composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Step 1: Preparation of laser direct detonation agent powder

[0028] Take 1.0g of the prepared silver-based cationic energetic metal-organic framework [Ag(ATCA)ClO 4 ] n Mixed with 50mg of molybdenum disulfide, and ground into 100um powder material;

[0029] Step 2: Charging and packaging of laser direct detonation agent powder

[0030] The prepared laser direct detonation powder is divided into two times and pressed into the detonator. The lower 500mg powder is pressed into the detonator with a pressure of 30MP, and the pressure is kept for 5min before unloading; after the upper layer of 500mg is loaded, the pressure is released immediately after the pressure of 1MP. Press and seal the detonator with window glass.

[0031] Step 3: Laser initiation performance test based on femtosecond laser

[0032] A femtosecond laser with a wavelength of 800 nm was used to test the detonation performance of the laser detonator prepared by the above method. When the frequency of ...

Embodiment 2

[0034] Step 1: Preparation of laser direct detonation agent powder

[0035] Take 1.0g of the prepared silver-based cationic energetic metal-organic framework [Ag(ATCA)ClO 4 ] n Mixed with 30mg of molybdenum disulfide, and ground into a 50um powder material;

[0036] Step 2: Charging and packaging of laser direct detonation agent powder

[0037] The prepared laser direct detonation powder is divided into two times and pressed into the detonator. The lower layer of 500mg powder is pressed into the detonator at a pressure of 20MP, and the pressure is kept for 5 minutes before the pressure is unloaded; after the upper layer of medicament is loaded with 500mg, the pressure is released immediately after the pressure of 5MP. Press and seal the detonator with window glass.

[0038] Step 3: Laser initiation performance test based on femtosecond laser

[0039] A femtosecond laser with a wavelength of 800 nm was used to test the detonation performance of the laser detonator prepared ...

Embodiment 3

[0041] Step 1: Preparation of laser direct detonation agent powder

[0042] Take 1.0g of the prepared silver-based cationic energetic metal-organic framework [Ag(ATCA)ClO 4 ] n Mixed with 20mg of molybdenum disulfide, and ground into a 300um powder material;

[0043] Step 2: Charging and packaging of laser direct detonation agent powder

[0044] Press the prepared laser direct detonation powder twice into the detonator. The lower layer of 500mg powder is pressed into the detonator with a pressure of 35MP, and the pressure is kept for 5min before unloading; after loading the upper layer of 500mg of medicament, it is released immediately after the pressure of 2MP. Press and seal the detonator with window glass.

[0045] Step 3: Laser initiation performance test based on femtosecond laser

[0046]A femtosecond laser with a wavelength of 800 nm was used to test the detonation performance of the laser detonator prepared by the above method. When the frequency of the femtosecon...

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Abstract

The invention discloses application of a silver-based cationic energy-containing metal organic framework as a laser direct detonating agent composition. The energy-containing metal organic framework material with the chemical formula of [Ag(ATCA)ClO4]n is used as a core material, wherein ATCA in the formula is a neutral ligand of 3-amino-1H-1,2,4-triazole-5-carbohydrazide; meanwhile, a small amount of molybdenum disulfide is added as an assistant agent. According to the application of the silver-based cationic energy-containing metal organic framework as the laser direct detonating agent composition, the novel lead-free green laser detonating agent composition is more environmentally friendly. Meanwhile, the composition has a high ignition response to femtosecond lasers, the ignition timeof the composition is shorter, the ignition energy of the composition is lower, and the composition is better than detonating agents such as lead azide. A preparation method of the composition is simple in process flow, convenient to operate, mild in reaction condition and high in safety and product quality.

Description

technical field [0001] The invention relates to the technical field of novel energetic materials, and more specifically relates to the application of a silver-based cationic energetic metal-organic framework as a laser direct priming agent formula. Background technique [0002] At present, the primary explosives used in my country mainly include lead azide, metal salts of picric acid and styphonic acid, etc., but most of these primary explosives are extremely sensitive to external stimuli, often causing accidental explosions, resulting in heavy losses of personnel and property. Therefore, it is necessary to urgently seek a safer new type of detonating agent in production and use, which should have characteristic sensitivity, can be reliably ignited or detonated by flame, electric heating wire, laser, and will not be affected by external sudden stimulation (static electricity). , impact, friction, etc.) are more blunt. [0003] At present, researchers in this field around th...

Claims

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Application Information

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IPC IPC(8): C06B43/00C06B21/00
CPCC06B21/00C06B43/00
Inventor 张祺王霆威
Owner INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS
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