The invention belongs to the technical field of energetic materials, and discloses a core-shell structure aluminum-based
microwave energetic material and a preparation method and application thereof.The preparation method comprises the steps that in order to construct an
interface layer on the surface of aluminum
powder, the aluminum
powder is added into a
silane coupling agent solution, a
cyclodextrin solution, a butyl
titanate solution and a perfluorododecyl mercaptan /
dopamine hydrochloride solution, and four kinds of suspension liquid A are formed; adding the suspension B containing the bimetallic
composite oxide into the suspension A, and stirring to obtain four suspensions C; and filtering, washing and
drying the suspension C to obtain the aluminum-based
microwave energetic material with the core-shell structure. According to the invention, interface chemical bonds or
electrostatic interaction is constructed between aluminum and AB2O4 by using the
interface layer, so that oxidation of aluminum is effectively prevented, interface polarization is enhanced at the same time, and a core / shell structure further shortens the
mass and
heat transfer distance of a reaction between fuel and
potassium oxide, so that the
microwave ignition delay time is remarkably shortened, and the microwave ignition efficiency is improved. Efficient microwave
energy coupling and controllable
combustion performance are achieved, and excellent
microwave response characteristics are shown.