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2862 results about "Sodium sulfite" patented technology

Sodium sulfite (sodium sulphite) is a soluble sodium salt of sulfurous acid (sulfite) with the chemical formula Na₂SO₃. It is used as a preservative to prevent dried fruit from discoloring, and for preserving meats, and is used in the same way as sodium thiosulfate to convert elemental halogens to their respective hydrohalic acids, in photography and for reducing chlorine levels in pools. In boiler systems, sulfite and bisulfite are the most commonly employed oxygen scavengers used to prevent pitting corrosion. Sodium sulfite is also a byproduct of sulfur dioxide scrubbing, a part of the flue-gas desulfurization process.

Temperature-resistant salt-resistant efficient gel, and preparation and use thereof

The invention discloses a temperature resistant salt tolerant high efficiency gel and a preparation method and application thereof. The preparation method is characterized in that the preparation method comprises the following steps: preparing a comb-shaped associated copolymer PAH containing macromonomers and functional hydrophobic monomers into an aqueous solution having the concentration of 0.1 to 4g/L, the crosslinking agent concentration of 0.01 to 1.0g/L, the surfactant concentration of 0.01 to 8mmol/L and the sodium sulfite thermal stabilizer concentration of 0.005 to 1.0g/L; adding the aqueous solution into a mixing container with a stirring device; stirring the aqueous solution evenly at the room temperature; regulating the pH value of the solution to be equal to between 4 and 11, and obtaining a temperature resistant salt tolerant high efficiency gel polymer solution system used for tertiary oil recovery and scavenge, displacement modification, profile modification or water shutoff. The polymer solution system has micro-crosslinking to form the gel during the flowage inside the oil reservoir. The gel has good elasticity, not easy dehydration, stable gelling performance, and excellent tackification, temperature resistance, salt tolerance, shearing resistance and ageing resistance.
Owner:CHENGDU UNIVERSITY OF TECHNOLOGY

Method of preparing taurine

The invention relates to method for preparing taurine, comprising the following steps: (1) reacting epoxy ethane with sodium sulfite under 0.05 to 0.1MPa, with pH value of 6.5 to 7.5 and at temperature between 75 and 85 DEG C to obtain hydroxyethyl sodium sulfonate; (2) carrying out ammonolysis reaction on the hydroxyethyl sodium sulfonate and liquid ammonia under 14 to 21MPa and at temperature between 160 and 280 DEG C to obtain ammonolysis solution containing sodium taurate; (3) introducing the ammonolysis solution into a single flash evaporator for primary flash evaporating at a temperature between 160 and 200 DEG C and under 1.3 to 2.0MPa; introducing the flash evaporated liquid into a secondary flash evaporating and falling film evaporator, using the primary flash vapor as a heating medium to carry out flash evaporating and falling film evaporating on the primary flash evaporated liquid in the secondary flash evaporating and falling film evaporator at a temperature between 110 and 140 DEG C and at 0.1 to 0.6MPa; evaporating and concentrating the flash evaporated liquid subjected to secondary flash evaporating and falling film evaporating with flash vapor and steam as heating media in a multi-effect flash evaporating and falling film evaporator; and (4) neutralizing the sodium taurate by sulphuric acid to obtain the taurine. The method for preparing the taurine has the advantages of short time, high yield and low cost, and is easy for industrialized production. In addition, by primary flash evaporating and secondary flash evaporating processes, almost all the ammonia and 40% to 60% of water in the flash evaporated liquid can be removed, thus having double effects of removing ammonia and condensing.
Owner:王代龙 +1

Acrylic amide modified polymer micro-crosslinking gel and preparation thereof

The invention discloses acrylamide modified polymer micro-crosslinking gel and a preparation method thereof. The preparation method is characterized in that the method comprises the following steps that: acrylamide modified polymer PAE containing functional macro monomer is prepared into an aqueous solution with the concentration between 0.1 and 4g/L, the concentration of crosslinking agent between 0.01 and 1.0g/L, the concentration of surface active agent between 0.01 and 8mmol/L and the concentration of heat stabilizer sodium sulfite between 0.005 and 1.0g/L; the aqueous solution is added in a mixing container with a stirring device and is stirred evenly at room temperature; the pH value of the solution is adjusted between 4 and 11 to prepare a polymer solution system of the acrylamide modified polymer micro-crosslinking gel used for tertiary oil recovery and displacement, oil displacement modification, profile modification or water plugging; and the polymer solution system undergoes micro crosslinking during flowing inside an oil layer to form the gel. The acrylamide modified polymer micro-crosslinking gel has ideal elasticity, difficult dehydration, stable performance and excellent performances on tackifying, temperature resistance, salt resistance, shearing resistance and ageing resistance.
Owner:CHENGDU UNIVERSITY OF TECHNOLOGY

Comprehensive recycling method of waste and old lithium-ion battery

The invention provides a comprehensive recycling method of a waste and old lithium-ion battery, and relates to the lithium-ion battery. The method comprises the following steps of: performing explosion-proof magnetic smashing and atomized spraying smashing on the waste and old lithium-ion battery, thereby separating an outer shell and a battery material; carbonizing and roasting in a constant-temperature roaster at high temperature and under negative pressure, thereby removing an isolated membrane and a cathode; recycling the outer shell and an anode material in a grading manner by using a centrifugal disintegrator, thereby separating the outer shell and the anode material containing nickel and cobalt; leaching out by adding sodium sulfite into H2SO4 at the normal pressure by utilizing the characteristics of the anode material; regulating the pH value by adding carbonate into an leaching liquid; preliminarily removing Ca and Mg by adding a fluoride salt; extracting and removing impurities by using P2O4, thereby removing the impurities such as Fe, Cu, Zn, Ca, Mg and the like; performing selective extraction for cobalt-nickel separation by using P507, thereby obtaining a high-purity nickel sulfate solution and a high-purity cobalt sulfate solution in which the content of the Fe, the Cu, the Zn, the Ca and the Mg is respectively less than or equal to 2.0mg / L. The method is efficient, simple and convenient and low in production cost, and has wide applicability and a high additional value.
Owner:XTC NEW ENERGY MATERIALS(XIAMEN) LTD

Gel plugging agent for deep profile control of higher temperature oil reservoir and preparation method of gel plugging agent

The invention relates to a gel plugging agent for deep profile control of a higher temperature oil reservoir, and a preparation method of the gel plugging agent. The gel plugging agent comprises 0.3-0.8 percent of nonionic polyacrylamide, 0.6-1.3 percent of a cross-linking agent A, 0.45-1.44 percent of a cross-linking agent B, 0.02-0.04 percent of a temperature stabilizer and 0.01-0.08 percent of a pH value regulator, wherein the cross-linking agent A is methenamine; the cross-ling agent B is hydroquinone or resorcinol; the temperature stabilizer is sodium thiosulfate, sodium bisulfite or sodium sulfite; and the pH regulator is sodium hydroxide, potassium hydroxide, sodium carbonate or sodium bicarbonate. The gel plugging agent disclosed by the invention has strong temperature resisting performance and can be used for the profile control operation of the high temperature oil reservoir with 100-160DEG C; the gel plugging agent has the characteristics of high strength after being gelatinized, stronger plugging capability for the stratum and favorable thermal stability; and in addition, after the gel plugging agent is stood at the temperature of 130 DEG C for 90 days, the strength change is little and gel breaking and hydration are avoided.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Sulphuric acid tail-gas deep desulfurization method

The invention discloses a deep desulfurization method of sulfate acid tail gas. The method additionally arranges a desulfurization tower behind a second adsorption tower of a sulphuric acid device; after the waste gas discharged from the second adsorption tower enters the desulfurization tower, an ammoniation absorbent is used for adsorbing SO2 in the waste gas to generate ammonium sulfite; the tail gas after the desulfurization passes through a demisting layer in the tower to eliminate acid fog; the purified tail gas is discharged through a chimney at high altitude; the ammonium sulfite in the absorbent is aerated and oxidized to be ammonium sulfate solution at the bottom of the tower; and after the concentration of circulation liquid ammonium sulfate meets the requirement, the circulation liquid ammonium sulfate is sent to a follow-up process to be processed and used. The deep desulfurization method of sulfate acid tail gas can cause the concentration of the SO2 in the tail gas to be lower than 100mg/m<3> in a standard state, greatly reduces the emission of the SO2 in the tail gas, is beneficial to the improvement of the atmospheric environment quality, meets the construction principles of energy conservation, emission reduction and sustainable development and has good social benefits; in addition, the deep desulfurization method can increase the recovery amount of the ammonium sulfate, and has certain economic benefits.
Owner:GUIZHOU KAILIN GRP CO LTD

Copper-zinc separation beneficiation method

InactiveCN101428250ARaise the gradeRealize zinc suppression and floating copperFlotationSulfite saltSulfate
The invention relates to a copper-zinc separation beneficiation method which comprises the following steps: (1) primary grinding, that is, adopting a combined depressant comprising lime, sodium sulfide, zinc sulfate, and sodium sulfite under the condition that the size and the content of grinding particles are respectively -0.074 mm and 65 to 70 percent; (2) copper rough concentrates regrinding and concentration, that is, selecting out high-quality copper concentrates which contain high-grade copper and silver, but low zinc by adopting single groove speed flotation method and continually using the combined depressant constituted by lime, sodium sulfide, zinc sulfate, and sodium sulfite, so as to realize the zinc depressing and copper flotation; (3) zinc-sulfur separation, that is, using butyl xanthate as a collecting agent to float zinc, obtaining zinc-sulphur bulk concentrate, conducting pulp conditioning by adding lime so as to depress sulfur and float copper and obtain zinc concentrates and partial sulfur concentrates, conducting the iso-flotation on the tailings and further adding the butyl xanthate to conduct flotation and obtain partial sulfur concentrate. The invention has the advantages of adopting the processes of ore blending, primary grinding, copper rough concentrates regrinding and concentration, and zinc-sulphur iso-flotation technological process, thereby better solving the problem that the copper concentrates contain too much zinc or the copper content in the zinc concentrates is over standard.
Owner:杭州建铜集团有限公司

Method for displaying and quantitatively determining retained austenite or island martensite- austenite in TRIP steel

The invention relates to a display and quantitative detection method of residual austenite or island martensite-austenite (MA island for short) in TRIP steel. The method comprises the steps: (1) a TRIP tapping sample is prepared into a metallographic specimen; (2) after grinding and polishing, the metallographic specimen is light etched for 5 to 8 seconds in Nital of 1 to 3 percent by weight, and water is sprinkled on a flannel polishing disk for 1 to 2 seconds; sodium pyrosulfite water solution of 1 to 3 percent by weight and picral of 2 to 6 percent by weight are mixed by volume ratio of 1:1 to prepare corrosive liquid, then the metallographic specimen is put into the corrosive liquid for etching of 55 to 65 seconds; (3) the structure of the TRIP steel is observed under a metallurgical microscopy: the delta ferrite is minus blue, the residual austenite or MA island is white, and bainite is brownish-black; and (4) each phase in the structure is carried out quantitative analysis. The method presents different colors, each phase of structure has distinct layers which are easy to distinguish; and a quantitative image analysis method is utilized to fix amount of the feature object structure, which is objective and accurate and has good repeatability.
Owner:WUHAN IRON & STEEL (GROUP) CORP

Dye compound reducing agent and method of using the same

The invention discloses a composite reducing agent for dye, comprising the following compositions in weight portion: 8 to 20 portions of vat powder, 5 to 40 portions of thiourea dioxide, and 5 to 15 portions of sodium sulfite. The invention also discloses a method for dyeing by the reducing agent, comprising the following steps that: a reducing agent and sodium hydrate are used for reducing the dye by a vatting method; the weight ratio of a reducing solution to the dye is 37.5: 0.8 to 2.0 and the mixture is for later use; a leveling agent and the fiber penetrating swelling agent are added to dye or a buffering agent is added to adjust the pH value and is dyed by vat acid, the temperature is reduced and the mixture is washed; the mixture is subjected to oxidization to develop color, fixing, reducing temperature and washing; the fresh water bath is performed, the dye composite reducing agent is reduced and washed, and the temperature is reduced and the fiber penetrating swelling agent is produced. The composite reducing agent for the dye is a special reducing agent used for reducing the dye, a sulfur dye, a perylene dye and a leuco body, and improves the stability of the leuco body, color yield percentage, the color reproducibility, the color fixation and the color evenness degree, meanwhile, the dye composite reducing agent avoids the harm of formaldehyde on the environment and the human body.
Owner:SHANGHAI TEXTILE GRP DETECTION STANDARD CO LTD

Pemetrexed disodium freeze-dried injection and preparation method thereof

The invention relates to a pemetrexed disodium lyophilized powder injection, which consists of pemetrexed disodium, mannitol and sodium sulfite in the following weight portions: 50 portions of the pemetrexed disodium, 10 to 50 portions of mannitol, and 0.1 to 1 portions of sodium sulfite; and the pH value of the pemetrexed disodium lyophilized powder injection is between 7.0 and 8.0. The process for preparing the pemetrexed disodium lyophilized powder injection comprises the following steps: placing the mannitol in a sterile chamber; adding 80 percent of water for injection into the sterile chamber to dissolve the mannitol; adding the sodium sulfite to the mixture after the water for injection is cooled to a temperature of between 15 and 25 DEG C, and evenly stirring the solution for dissolving the sodium sulfite; then, adding the pemetrexed disodium into the solution, and stirring the solution to completely dissolve the pemetrexed disodium and evenly mixing the pemetrexed disodium, and adjusting the pH value of the solution to between 7.0 and 8.0; decarbidizing; after an intermediate compound passes examination, carrying out volume fixing, filtering, filling, partially stopping, traying, lyophilizing, nitrogen aerating, stopping and unboxing, sealing by a plastic-aluminum combined cap, and packaging after passes quality inspection to obtain the pemetrexed disodium lyophilized powder injection. The invention has the advantages of simple preparation process, convenience and practicality, good repeatability and low production cost, and can realize industrial large-scale production easily.
Owner:JIANGSU AOSAIKANG PHARMA CO LTD

Method for using cyaniding barren solution to float, reclaim and cyaniding copper plumbum and zinc in tailings

A method that cyanide barren solution is used for recovering the copper-lead-zinc from cyanide tailing by means of floatation belongs to the field of nonferrous metal separation. The processing procedures of the method are as following: (1) mashing: the cyanide barren solution is added into the cyanide tailing and stirred to ore slurry, the concentration of which is 35 to 40 per cent; (2) lead-zinc preferential flotation: after being stirred, the ore slurry is put into flotation machine and lime, Ethyl thiocarbamate and Sodium n-butyl xanthate synthetic are added in to the ore slurry. The course of once rough floatation, twice scavenging and twice concentration is processed to recover Zinc and Lead; (3) Cu-S separation: after the tailing of lead and zinc bulk flotation is concentrated, the cyanide barren solution is added into the tailing and the tailing is made into the ore slurry with the concentration of 35 to 40 per cent. And then, the ore slurry is put into the floatation machine and sulfate, sodium sulfite, Z-200 and ammonium butyl aerofloat are added into the tailing. The course of once rough floatation, twice scavenging and twice concentration is processed to recover copper. And the tailing can be for sale as sulfur concentrate; (4) Reuse of separation tailing water: the press filtrate of bulk concentrate, the overflow of thickener, the press filtrate of copper concentrate and the press filtrate of the sulfur concentrate return to the buffer slot of the cyanide barren solution to be used for replacement fluid. The invention has the advantages of good flotation effect, high recovery rate of the copper-lead-zinc and zero discharge of waste water and residue.
Owner:UNIV OF SCI & TECH BEIJING

Composite decarbonizing solution for gathering carbon dioxide in mixed gas

The invention discloses a composite decarbonizing solution for gathering carbon dioxide in mixed gas, belonging to the technical field of gas separation. The composite decarbonizing solution is characterized by consisting of main absorption components including MEA and AEE, auxiliary absorption components including AHPD, AMP, TEA and MDEA, active components including PZ, HEPZ, AEP and DEA, sodium vanadate as an inhibiter, sodium sulfite and copper acetate as antioxidant, and a mixed solvent including NMP, polyethylene glycol and propylene carbonate and water. Because the mixed solvent is used for the composite decarbonizing liquid, on the one hand, the absorption capacity, the purification degree and the desorption rate are improved, and the reaction temperature range is enlarged, and on the other hand, regeneration energy consumption is greatly improved. The invention has the advantages that the composite decarbonizing solution is used for gathering carbon dioxide in various kinds of chemical reaction tail gas, burning stack gas and natural mixed gas and eliminating carbon oxide in city gas, natural gas, and the like, and has social benefit and economic benefit.
Owner:DALIAN UNIV OF TECH

Technology for extracting tellurium dioxide from tellurium-containing smelting slag

The invention relates to a technology for extracting tellurium dioxide from tellurium-containing smelting slag. The technology comprises the following steps: ball-milling tellurium slag, leaching by water, carrying out reduction alkali leaching, vulcanizing, carrying out silicon removal purification, and neutralizing to precipitate tellurium. The method has the advantages of tellurium leaching rate improvement, reduction of the alkali application amount in the leaching operation, and production cost reduction. The method is characterized in that sodium hydrosulphite is adopted as a transition agent to transit insoluble high-valence tellurium to low-valence tellurium, so the leaching rate leaching rate is increased. The total tellurium leaching rate can reach above 90% under a suitable technological condition; and after recovering tellurium through neutralizing, the TeO2 grade of the smelting slag can reach above 50%, and the content of tellurium in the waste liquid obtained after the neutralizing is 0.1-0.3g / L. The method also has the advantages of further enrichment of copper, lead, bismuth, antimony and precious metals in the leaching slag, realization of the resource reuse, production cost reduction, and energy saving, and is of great importance to the resource recovery and the environmental protection.
Owner:CHENZHOU CITY JINGUI SILVER IND CO LTD

Method for treating tail gas of acyl chlorination

The invention relates to a processing method of thionyl chloride acyl-chlorinated tail gas. Mixed tail gas produced by a acyl chlorinating process contains hydrogen chloride and sulfur dioxide; the sulfur dioxide is liquefied under a certain temperature condition; the incondensable hydrogen chloride and a little sulfur dioxide are absorbed in two stages by water; the absorbed tail gas in a first stage is pure hydrogen chloride gas; after being absorbed in a second stage, the qualified chlorhydric acid is obtained; first-stage falling film absorption liquid is resolved by heating; then the tail gas is sent to a liquefying process again; the liquid sulfur dioxide can be canned as a product; or after being vaporized, the liquid sulfur dioxide is absorbed by 30 percent of sodium hydroxide solution to obtain sodium sulfite aqueous solution which is further dried after low temperature crystallization or distillation to obtain 97 percent of sodium sulfite solid. With the method, the hydrogen chloride, the sulfur dioxide and a little thionyl chloride produced by an acyl chlorination synthetic process can be separated out to obtain the chlorhydric acid and the pure sodium sulfite solid. The processing method of the thionyl chloride acyl-chlorinated tail gas of the invention is capable of effectively recovering the thionyl chloride acyl-chlorinated tail gas, which has the advantages of safety process and easy control.
Owner:JIANGSU YANGNONG CHEM +2

Illegal cooking oil lubricant and preparation method thereof

The invention discloses an illegal cooking oil lubricant and a preparation method thereof. The illegal cooking oil lubricant comprises the following components in percentage by weight: 40%-60% of illegal cooking oil, 0.5%-1.5% of sodium sulfite, 1%-3% of sorbide oleate, 0.02%-0.04% of antioxidants, 0.2%-0.3% of extreme-pressure antiwear agents, 0.05%-0.1% of formaldehyde, 1.0%-1.2% of sodium hydroxide and the balance of water. Through the illegal cooking oil lubricant disclosed by the invention, the problem that torque and friction resistance are reduced through lubrication in the drilling process of a horizontal well is effectively solved, moreover, a new way is provided for the recycling of the illegal cooking oil, and the preparation cost of the lubricant can be reduced.
Owner:BC P INC CHINA NAT PETROLEUM CORP +1
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