1377 results about "Phosphorus containing" patented technology

The invention relates to the technical field of phosphorus-containing and fluorine-containing wastewater treatment, provides a phosphorus and fluorine removal agent and a preparation method thereof, and solves the problems that an existing phosphorus and fluorine removal agent is high in manufacturing and using cost, poor in fluorine removal effect and likely to cause secondary pollution due to the fact that the existing phosphorus and fluorine removal agent is greatly influenced by pH. The dephosphorization and defluorination agent is composed of calcium chloride, calcium oxide and active magnesium oxide; the preparation method comprises the following steps: preparing calcium chloride, calcium oxide and active magnesium oxide according to purity and particle size; mixing calcium chloride, calcium oxide and active magnesium oxide according to the molar ratio; adding active magnesium oxide into the premixed calcium chloride and calcium oxide according to the mass ratio of calcium oxide to calcium chloride to active magnesium oxide of 1: 2: (7-12); the mixed powder is subjected to refining treatment through a fine grinding machine, and the refined powder is subjected to secondary screening; and sealing, packaging and storing the refined powder. The use condition is simple, and only active magnesium oxide is required to be mixed with calcium oxide and calcium chloride in proportion.

The invention belongs to the technical field of flame-retardant materials, and particularly relates to preparation of a phosphorus, nitrogen and silicon macromolecular flame retardant and application of the phosphorus, nitrogen and silicon macromolecular flame retardant in epoxy resin. The preparation method comprises the following steps: firstly, carrying out substitution reaction on chlorosilane and syringaldehyde or vanillic aldehyde to synthesize a silicon-containing intermediate, then carrying out Schiff base reaction on the silicon-containing intermediate and an amine compound, and finally carrying out addition reaction on the silicon-containing intermediate and a phosphorus-containing compound to prepare the phosphorus, nitrogen and silicon macromolecular flame retardant. The flame retardant has a good flame-retardant effect, can be used for preparing flame-retardant epoxy resin, can effectively improve the limit oxygen index and the vertical combustion grade of the epoxy resin, and can endow the epoxy resin with good transparency and molten drop resistance.

The invention discloses a method for selectively recycling phosphorus pollutants in low-concentration phosphorus-containing sewage and preparing high-quality blue iron ore and application, and belongs to the technical field of water treatment and recycling thereof. According to the method, the low-concentration phosphorus-containing sewage is adsorbed by a phosphorus specific nano adsorption material HFO-201, and then the material is desorbed by adopting sodium hydroxide and sodium chloride with specific concentrations. The desorbed filtering material and the filtered material can be repeatedly used for adsorbing phosphorus in low-concentration sewage. After the pH value of the filtered desorption solution is adjusted to a certain concentration, FeCl2 with a certain concentration is added, and high-quality blue iron ore (Fe3 (PO4) 2.8 H2O) can be generated by keeping the pH value through sodium hydroxide under an anaerobic condition. The phosphorus product recovered by the process can be used for preparing a high-value phosphate fertilizer and a high-energy-density energy storage material, namely lithium iron phosphate (LiFePO4). The HFO-201 used in the invention can realize low-concentration phosphorus adsorption through an ammonium group combined with a D-201 matrix and loaded HFO nanoparticles. And moreover, after alkali desorption, the damage to the material is very low, and the material can be repeatedly used. And finally, the process of producing the high-quality blue iron ore through phosphorus recovery of the desorption solution is simple and easy to operate. Through XRD, ICP and other detection, it is found that the phosphorus recovery product is determined to be the blue iron ore, and the purity is very high. Through economic analysis and life cycle evaluation, it can be found that the method has remarkable economical efficiency, and the influence on the environment in the production process is small.

The invention relates to the field of sludge treatment, and particularly discloses a method for recycling phosphorus in sludge pyrolysis residues, a flocculant synthesis method and application. The invention discloses a method for recovering phosphorus in sludge pyrolysis residues. The method comprises the following steps: drying the sludge pyrolysis residues, grinding and sieving; the sludge pyrolysis residues are put into a hydrochloric acid solution to react, and solid-liquid separation is carried out after the reaction; treating the phosphorus-containing extracting solution through adsorption resin to obtain a phosphorus purification solution; adjusting the pH value of the phosphorus purification liquid to 9-11, and carrying out a crystallization reaction under the condition that the molar ratio of magnesium to nitrogen to phosphorus is (0.8-1.2): (1-1.6): 1 to obtain struvite; a synthetic method of the flocculating agent is as follows: the flocculating agent is prepared from residual sludge residues. The method for recycling phosphorus in the sludge pyrolysis residues has the advantages that phosphorus resources are recycled from the sludge pyrolysis residues, and the residues are secondarily utilized. The flocculating agent is applied to municipal sewage treatment.

The invention relates to a heat-resistant, water-resistant and flame-retardant backboard composite material as well as a preparation method and application thereof. The heat-resistant, water-resistant and flame-retardant backboard composite material comprises a phosphorus-containing epoxy acrylate oligomer, common epoxy resin, toughened epoxy resin, phosphorus-containing epoxy resin, a filler, an additive flame retardant, a dicyandiamide curing agent, an accelerant, nitrogen-containing phenolic resin, a latent curing agent, a UV absorbent and an antioxidant. The phosphorus content in the material is improved by synthesizing the phosphorus-containing epoxy acrylate oligomer, so that the flame retardant property of the product is improved, and the problem of low flame retardant efficiency caused by direct addition of a phosphorus flame retardant is solved.

The invention discloses a synthesis method of phosphorus-containing polysilazane. The synthesis method comprises the following steps: S1, preparing solid methyl hydrogen polysilazane; s2, solid methyl hydrogen polysilazane is dissolved in an organic solvent, phosphate ester is added, the mixture is stirred to be uniform, then a Karst catalyst is added, and a phosphorus-containing polysilazane solution is obtained after a heating reaction. The phosphorus-containing polysilazane solution obtained through combined action of polysilazane and phosphate containing a vinyl structure is applied to an anti-corrosion coating, the anti-corrosion coating with the thin thickness can be obtained, and the adhesive force and the salt spray resistance are excellent. According to the invention, self-made phosphorus-containing polysilazane is adopted, phosphate is connected to polysilazane through chemical modification, the salt spray resistance effect is improved, the storage stability is good, phosphorus liquid passivation treatment is not needed, and the process is green and environment-friendly.

The invention discloses a process and equipment for synthesizing fluorapatite from wastewater, the equipment comprises a blending tank, a dispensing tank, a crystallization fluidized bed reactor, a reaction tank, a coagulation tank, a flocculation tank, a sedimentation tank, a pH detection device, a lift pump and a control system, fluorine-containing sewage and phosphorus-containing sewage are mixed in the blending tank, so that the molar ratio of fluorine to phosphorus is 0.34-0.4; the method comprises the following steps: adding fluorapatite into a reaction tank, adjusting the pH value to 7.5-8.5, pumping the fluorapatite and lime slurry into a crystallization fluidized bed reactor according to a calcium-phosphorus molar ratio of (3-3.5): 1, carrying out a crystallization reaction, naturally airing the generated fluorapatite crystals, carrying out a reaction on crystallization treatment water and the lime slurry in the reaction tank to remove fluorine and phosphorus, carrying out coagulation, flocculation and precipitation treatment, and discharging the effluent after reaching the standard. The high-quality fluorapatite product is prepared from the fluorine-containing sewage and the phosphorus-containing sewage, so that the preparation cost is low, and resourceful treatment of the fluorine-containing sewage and the phosphorus-containing sewage is realized.

The invention relates to a phosphorus-free zinc-free seawater special-purpose scale and corrosion inhibitor, which comprises, by weight, 20-25% of sulfonic acid modified polyaspartic acid, 8-12% of quaternized chitosan, 5-10% of a sulfonate copolymer, 5-10% of polyepoxysuccinic acid, 1-3% of benzotriazole or methyl benzotriazole, 0.5-1% of sodium tungstate, and the balance of deionized water. According to the formula, traditional corrosion inhibitors such as phosphorus and zinc are completely abandoned, functions are achieved through natural polymer derivatives such as sulfonic acid modified polyaspartic acid and quaternized chitosan, and the scale and corrosion inhibitor has the following environmental protection advantages that the scale and corrosion inhibitor does not contain phosphorus and zinc elements at all, and water eutrophication and heavy metal accumulation caused by a traditional phosphorus and zinc formula are avoided.

The invention is suitable for the technical field of flame retardance of high polymer materials, and provides a core-shell structure graphite phase carbon nitride derivative and a preparation method thereof.The derivative is prepared by the steps that a precursor containing phosphorus and boron elements is mixed with melamine, and phosphorus / boron co-doped graphite phase carbon nitride is prepared through a high-temperature thermal polymerization reaction; and then assembling the phytic acid copper on the surface of the graphite-phase carbon nitride in an in-situ growth manner by adopting an aqueous solution self-assembly method to construct a derivative with a core-shell structure. The invention provides the graphite phase carbon nitride derivative with the core-shell structure, which is green, environment-friendly, efficient and flame-retardant and simple and convenient in process, and the preparation method of the graphite phase carbon nitride derivative, and the graphite phase carbon nitride derivative has wide application prospect and industrialization value.

The invention provides a method for degrading organic phosphorus and recycling phosphorus in water in an ozone oxidation system. According to the method, a mode of adding iron or iron salt solution step by step is innovatively adopted, so that the degradation rate of phosphorus-containing organic matters in water, the generation rate of phosphate radicals and the removal of total phosphorus in water are remarkably improved. Besides, the treatment effect is evaluated by monitoring the organophosphorus mineralization rate (taking the generation amount of phosphate radicals as an index) and the removal rate of total phosphorus in water, experiments show that the method can increase the organophosphorus mineralization rate by 30% or above, and the removal rate of total phosphorus reaches 95%. Compared with the conventional one-time addition of iron or iron salt, the method has the advantages that the mineralization rate of organophosphorus and the removal rate of total phosphorus are effectively improved through a step-by-step addition strategy, the direct precipitation of an organophosphorus intermediate product is promoted, the use amount of ozone and the addition amount of iron are remarkably reduced, the reaction time is greatly shortened, and the recovery efficiency of phosphorus resources is further improved. The method is low in cost and suitable for advanced treatment of organic phosphorus-containing wastewater in the industries of pesticides, electroplating and the like.

The invention relates to the technical field of materials, and discloses a fiber-waste-containing high-temperature-resistant insulation board and a preparation method thereof.The insulation board is prepared by taking thermosetting phenolic resin as a base material and taking ceramic fiber waste, glass fiber waste, aerogel and the like as auxiliary materials through mixing and foaming. Wherein the aerogel material is a cross-linked loofah sponge aerogel material with bentonite as a supporting framework, the aerogel material contains a large number of pore structures and can limit heat transfer and improve the heat preservation performance of the heat preservation plate, and cross-linked loofah sponge is prepared by cross-linking a phosphorus-containing derivative cross-linking agent and loofah sponge, so that the structure contains a large number of phosphorus-based flame-retardant structures, and the heat preservation performance of the heat preservation plate is improved. An organic-inorganic synergistic flame-retardant effect can be generated with bentonite, so that the flame-retardant and fire-resistant performance of the insulation board is improved. By adding the waste fiber material and fully utilizing the high-strength characteristic of the fiber waste material, the recycling of the waste material is realized, and the mechanical strength of the insulation board can be positively enhanced.

The invention relates to the technical field of design synthesis and application of flame retardants, in particular to a phosphorus-nitrogen-containing synergistic ionic liquid flame retardant as well as a preparation method and application thereof. The phosphorus-nitrogen-containing synergistic ionic liquid flame retardant has a structure as shown in a formula I; wherein R1 is selected from a straight chain alkyl group of C1 to C18, a branched chain alkyl group of C1 to C18 or a cycloalkyl group of C3 to C18; r < 2 > and R < 3 > are independently selected from a straight chain alkyl group of C1 to C18, a branched chain alkyl group of C1 to C18, a cycloalkyl group of C3 to C18 or an aryl group of C6 to C24; and R4 is selected from an alkyl group of C1 to C18, an alkenyl group of C2 to C18 or an aryl group of C6 to C24. The phosphorus-nitrogen-containing synergistic ionic liquid flame retardant provided by the invention has the advantages of high flame retardant efficiency, simple production process, realization of industrialization, almost no influence on mechanical properties of high polymer materials and the like. The flame-retardant polymer material prepared from the flame retardant has very high commercial application value.

The invention discloses a phosphorus-sulfur synergistic flame retardant with high gas phase activity, a durable flame-retardant nylon fabric and a preparation method of the flame-retardant nylon fabric, and relates to the technical field of flame-retardant nylon fabric preparation.The preparation method of the phosphorus-sulfur synergistic flame retardant comprises the steps that 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and polyepoxide are mixed and heated to be molten for a reaction, and the phosphorus-sulfur synergistic flame retardant is obtained; obtaining an intermediate after the reaction is finished; the intermediate and a thiophenethiol derivative are subjected to a click chemical reaction, and a 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide derivative containing phosphorus and sulfur is obtained; the preparation method comprises the following steps: dissolving a 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide derivative containing phosphorus and sulfur into a mixed solvent of ethanol and water, so as to obtain the phosphorus-sulfur synergistic flame retardant with high gas phase activity. The raw materials are safe and environmentally friendly, the preparation method is simple, and the prepared flame-retardant nylon fabric is excellent in flame retardance and washing resistance and free of pollution in the using process.

Disclosed are an aluminum diethylphosphinate crystal with a low fine powder content, a preparation method therefor and use thereof in flame retardance of glass fiber-reinforced engineering plastics. In the present invention, a phosphorus-containing aluminum salt complex is used as a seed crystal and is added in a crystallization process of preparing aluminum diethylphosphinate, such that the crystallization process can be effectively regulated and controlled, aluminum diethylphosphinate crystal particles with a low fine powder content, narrow distribution and a large particle size can be obtained, and the problems that the existing aluminum diethylphosphinate powder is prone to bridging, unsmooth feeding and the like can be solved. The present application is applicable to a processing technology of halogen-free flame retardant glass fiber-reinforced engineering plastics. The prepared aluminum diethylphosphinate includes a small amount of phosphorus-containing aluminum salt complex seed crystals, and the flame retardant property of the aluminum diethylphosphinate is not affected.

Disclosed are a build-up adhesive film for a flame-retardant FC-BGA packaging substrate, a preparation method therefor, and a use thereof, said film comprising, in parts by weight: 30-40 parts of an epoxy resin; 20-25 parts of a curing agent; 1-3 parts of a phenoxy resin; 0.05-0.1 parts of a curing accelerator; 80-100 parts of an inorganic filler, the inorganic filler being selected from one or two of modified boron nitride nanotubes and modified silica; the curing agent comprises a phosphorus-containing cyanate. The present invention uses the curing agent and the inorganic filler to form a composite flame retardant system on the basis of the epoxy resin, the phenoxy resin, the curing accelerator and other components to ensure the application of the build-up adhesive film in FC-BGA packaging substrates; the curing agent uses a phosphorus-containing cyanate, and when it burns, the phosphorus-containing group generates a phosphaphenanthrene group in the gas phase, which can form a stable structure and provide a free radical quenching function; in addition, the nitrogen-containing structure can also obtain a hindered amine structure having a quenching effect, forming a non-flammable gas, providing a gas phase dilution function, and effectively improving the flame retardant effectiveness of the build-up adhesive film.

The invention provides an anaerobic adhesive composition, an anaerobic adhesive and a preparation method of the anaerobic adhesive. The anaerobic adhesive composition comprises a main agent and a promoting primer, and the main agent comprises the following components in parts by weight: 30-70 parts of an acrylate monomer, 5-20 parts of an acrylate oligomer, 5-20 parts of a tackifier and 1-10 parts of an amide monomer; the accelerating primer is prepared from the following components in parts by weight: 0.01 to 30 parts of phosphorus-containing acrylate monomer and 0.001 to 1 part of reaction accelerator; wherein the reaction accelerant is an organic compound containing transition metal. According to the anaerobic adhesive composition, the curing degree of the anaerobic adhesive can reach the standard in a short time (within 3 min), and high drawing strength and an excellent damage form are achieved, so that the bonding requirement of a silicon steel sheet of a motor iron core is met; and the anaerobic adhesive has the advantages of high temperature resistance, no cracking, high drawing strength, vibration resistance, good oil-resistant stability and the like.

The invention relates to the technical field of wastewater purification, in particular to a phosphorus-containing wastewater treatment system. Comprising a pre-purification unit, a deep purification unit, a membrane concentration unit and a multi-effect evaporation unit which are sequentially connected, the pre-purification unit is used for diluting phosphorus-containing wastewater and filtering impurities; the deep purification unit is used for receiving the wastewater treated by the pre-purification unit and filtering multivalent metal cations, macromolecular substances and divalent salts in the wastewater; the membrane concentration unit is used for receiving the wastewater treated by the deep purification unit and evaporating water at low temperature under vacuum negative pressure and steam heating so as to concentrate phosphoric acid; and the multi-effect evaporation unit is used for receiving the phosphoric acid concentrated by the membrane concentration unit and further evaporating water under steam heating so as to further concentrate the phosphoric acid, so that a phosphoric acid product with the concentration reaching the selling standard is obtained. The method is simple in process and low in operation energy consumption, phosphorus-containing wastewater can be efficiently recycled, pollution to the environment is reduced, and economic benefits are improved through recycling of phosphorus resources.

The present invention relates to a method for treating wastewater with high phosphorus content, high turbidity and high oil content, comprising S1, using a sand settling tank to remove sand and gravel in the wastewater; S2, using an oil removal and decolorization tank to remove pigments and oil in the wastewater; S3, passing the wastewater into a reaction tank, adding a suitable weight of lime to the reaction tank according to the phosphorus content, and then adding a suitable weight of flocculant to the reaction tank, the flocculant and the suspended matter in the wastewater undergo flocculation reaction to generate large particles of solid; S4, using an inclined tube sedimentation tank to remove large particles of solid; S5, using a phosphorus adsorption filler layer in a deep filtration tank to adsorb the residual phosphorus in the wastewater, and a filter material layer to filter out small particles of solid in the wastewater; S6, after the water quality test is qualified, the wastewater is discharged. The present invention can remove pigments and oil in the wastewater, reduce pollutants, and improve the quality of effluent water by setting an oil removal and decolorization tank. The deep filtration tank can further remove micro suspended matter and pollutants such as phosphorus in the wastewater to improve the quality of effluent water.

The invention provides a phosphate modified positive electrode material as well as a preparation method and application thereof. The preparation method comprises the following steps: 1) dissolving a metal salt and a phosphorus source in deionized water, and reacting to form a mixed solution; 2) dispersing a coated substrate material in the mixed solution formed in the step 1) to obtain a turbid solution; (3) carrying out stirring reaction on an anti-solvent and the turbid solution formed in the step (2), centrifuging, washing and drying to obtain substrate powder coated with metal phosphorus-containing species; and 4) calcining the substrate powder formed in the step 3) to obtain the phosphate modified positive electrode material. The metal phosphate modified positive electrode material particles obtained by the invention can be used for realizing a stable positive electrode material of a high-specific-energy energy storage lithium ion battery.

The invention relates to the field of phosphorus-nitrogen flame retardants, and discloses a preparation method and application of a novel phosphorus-containing nitrogen oxide flame retardant, the preparation method comprises the following steps: S1, under the protection of nitrogen, dissolving diphenylphosphinyl hydroxylamine and triethylamine in a tetrahydrofuran solvent to prepare a reaction substrate solution; s2, slowly dropwise adding a diphenylphosphinyl chloride solution into the solution, and then sufficiently carrying out the reaction in a staged heating and heating reflux mode; s3, cooling and filtering to remove solid byproducts generated by reaction, and concentrating filtrate to obtain a crude product solid; and S4, recrystallizing and purifying the crude product by using ethyl acetate, and finally heating and drying the obtained crystal under a vacuum condition to obtain the product. An N-O group is innovatively introduced into the molecular structure of the flame retardant, so that the effect of efficiently capturing gas-phase free radicals in cooperation with a phosphorus-containing group is achieved, and the substantive technical progress that the material can be endowed with excellent flame retardant property with extremely low addition amount is realized.

The invention relates to the technical field of catalysts, and particularly discloses a phosphorus-containing porous organic polymer supported nickel catalyst which is prepared from a Ni precursor and a phosphorus-containing porous organic polymer, the loading amount mass fraction of Ni in the catalyst is 0.1-10%, and the phosphorus-containing porous organic polymer is a random copolymer and has a structural general formula I; the invention also provides a preparation method and application thereof. After the porous organic polymer containing the phosphorus ligand provided by the invention and transition metal salt form a catalyst, the phosphorous acid diester compound can be efficiently catalyzed and synthesized, the phosphorous acid diester compound can be recycled after the reaction, and the performance cannot be obviously reduced in the cyclic catalysis process.

The invention discloses preparation of isotropic flame-retardant bacterial cellulose aerogel and fire early warning application of the isotropic flame-retardant bacterial cellulose aerogel, and belongs to the technical field of aerogel materials. The preparation method of the aerogel comprises the following steps: (1) adding phosphorus / nitrogen-containing bridged organosiloxane and tetraethyl orthosilicate into bacterial cellulose dispersion liquid in proportion, and then stirring to obtain milk white uniform and stable turbid liquid; and (2) heating and curing the milky white turbid liquid, then precooling, and finally freeze-drying to obtain the isotropic flame-retardant bacterial cellulose aerogel. The aerogel disclosed by the invention is a cellulose-based aerogel material with flame-retardant and heat-insulating properties, has a remarkable isotropic flame-retardant characteristic, can effectively resist flame spread in all directions, is high in carbonization efficiency, can realize early detection and early warning of a fire disaster, and has a great application prospect in the field of fire disaster early warning.

The invention discloses a grading reaction crystallization recovery process and system for semiconductor fluorine-containing and phosphorus-containing waste liquid, the fluorine-containing and phosphorus-containing waste liquid and a lime solution react in a fluorine recovery crystallization reactor under the condition that the pH is 3-4 to form calcium fluoride crystals, and the calcium fluoride crystals are dehydrated to obtain calcium fluoride particle crystal products; the effluent of the fluorine recovery crystallization reactor, the calcium fluoride crystal dehydration filtrate, the lime solution and the calcium chloride solution react in a secondary reaction tank under the condition that the pH is 5-6, and calcium fluoride, fluorapatite, silicon dioxide and silicon-aluminum precipitates are removed through coagulation, flocculation and precipitation; effluent of the second-stage reaction tank, the lime solution and the calcium chloride solution react in the phosphorus recovery crystallization reactor under the condition that the pH is 7-8 to generate hydroxyapatite crystals, and the hydroxyapatite crystals are dehydrated to obtain hydroxyl calcium phosphate particle crystal products. Meanwhile, a high-purity calcium fluoride crystal product and a hydroxyl calcium phosphate crystal product are produced, and fluorine and phosphorus are recycled.

The present invention discloses a method for measuring the hydroxyl value of a polyether polyol using nuclear magnetic resonance phosphorus spectroscopy, comprising: 1) adding a polyether polyol sample to be tested and an internal standard bisphenol A to a deuterated reagent and dissolving them by ultrasonication; 2) adding a phosphorus oxychloride compound and an acid binding agent to the mixture and allowing them to react fully to obtain corresponding different derivatized phosphorus-containing products; 3) performing a phosphorus spectroscopy test in a nuclear magnetic resonance analyzer to obtain nuclear magnetic resonance phosphorus spectroscopy data, processing and analyzing the data, integrating the nuclear magnetic resonance characteristic peak areas of the phosphorus-containing products after derivatization of the polyether polyol sample and the internal standard bisphenol A, and normalizing them to 100%, and calculating the hydroxyl value of the sample to be tested based on the molar ratio relationship between the products. The hydroxyl value result obtained by the present method has a relative deviation of less than 5% from the result obtained by the phthalic anhydride acylation method in the national standard GB / T 12008.3-2009, and the two results are close and highly accurate. The analytical testing method of the present invention is simple, has low pollution, and is short in time.

The invention relates to a preparation method of high-purity vanadium pentoxide, in particular to the field of high-purity vanadium pentoxide, which comprises the following steps: adding an impurity removal agent into a phosphorus-containing vanadium solution to remove impurities, and then carrying out solid-liquid separation to obtain filtrate; the obtained filtrate is sequentially subjected to first pH value adjustment, second pH value adjustment, ammonium salt vanadium precipitation, dehydration, calcination deamination and melting, and high-purity vanadium pentoxide is obtained; wherein the impurity removing agent is prepared from calcium salt and a flocculating agent; the final pH value of the first pH value adjustment is 4.5-5.5; the final pH value of the second pH value adjustment is 1.8-2.2. According to the preparation method provided by the invention, the vanadium in the vanadium liquid is efficiently recovered by matching the metallographic phase specific impurity removal process of the vanadium liquid with pH value adjustment, the purity of the obtained vanadium product is greater than or equal to 99.9%, and the recovery rate of the vanadium is greater than or equal to 98%.

The present invention relates to molecular sieve preparation technology, and aims to provide a preparation method and application of a phosphorus-aluminum-containing ZJM-9 molecular sieve. The method includes: adding an aluminum source, a phosphorus source and a silicon source to a template solution under stirring, uniformly mixing to form a gel; performing a hydrothermal crystallization reaction, filtering, washing and drying the product to obtain a ZJM-8 molecular sieve; performing high-temperature roasting to obtain a roasted ZJM-8 molecular sieve; mixing it with water, filtering, drying and roasting it twice at 100 to 800 ° C to obtain a phosphorus-aluminum-containing ZJM-9 molecular sieve product. The ZJM-9 molecular sieve provided by the present invention is a new type of phosphorus-aluminum molecular sieve product, which enriches the types of molecular sieves. The molecular sieve can selectively adsorb water at room temperature, and therefore plays an important role in the dehydration field of gas and alcohol.

The invention provides a phosphorus-based ionic liquid flame-retardant polymer solid electrolyte and a preparation method and application thereof, belongs to the technical field of polymer solid electrolyte materials, and relates to a phosphorus-containing group flame-retardant ionic liquid polymer electrolyte and a preparation method thereof. The invention aims to overcome the problems that the polymer electrolyte in the prior art is poor in safety and the battery performance needs to be further improved, and provides the ionic liquid polymer electrolyte with the flame-retardant characteristic, the polymer electrolyte can greatly improve the safety performance of the battery while improving the battery performance, and the service life of the battery is prolonged. The phosphate group-containing ionic liquid has the advantages that the phosphate group-containing ionic liquid can be used as a polymer matrix of a polymer solid electrolyte, so that enough mechanical strength is ensured, phosphate radicals play a flame-retardant effect in a reaction process, a combustion reaction can be interrupted, and the safety performance of a battery can be greatly improved while the performance of the battery is improved.

This invention relates to a highly efficient functional ceramsite for purifying phosphorus-containing wastewater, its preparation method, and its application. Based on a complementary functional strategy, it uses natural clay rich in Al2O3 and SiO2 as a binder and calcium-rich industrial solid waste as the calcium-rich active component. Functional additives are also added to mitigate pH changes caused by calcium oxide reactions. The above raw materials are calcined at high temperature to obtain inexpensive, calcium-rich functional ceramsite with high mechanical strength, large adsorption capacity, and ecological safety. This effectively solves the common problems of increased water pH and poor phosphate adsorption capacity at neutral pH in calcium-based ceramsite, achieving highly efficient phosphorus purification in water. This invention uses inexpensive and readily available natural clay and calcium-rich industrial solid waste as raw materials, resulting in low cost, good effect, and effective application in the treatment of low-pollution water.

The utility model relates to a biological phosphorus removal and capacitive deionization combined enhanced phosphorus removal and phosphorus recovery device. Phosphorus-containing sewage is pretreated and then enters an anaerobic zone of a bioreactor to release phosphorus; after effluent of the anaerobic zone is settled by a first settling pond, supernate enters a capacitive deionization system for phosphorus recovery; supernate after phosphorus recovery is mixed with sludge in the first sedimentation tank and then flows through an anoxic zone and an aerobic zone of the bioreactor in sequence; part of mud-water mixture at the tail end of the aerobic zone flows back to the anoxic zone; after the rest part of sludge-water mixture is settled by a second settling pond, part of sludge in the second settling pond flows back to the anaerobic front end, and the rest part of sludge is transported outwards after being dewatered; according to the utility model, phosphorus recovery is carried out on the anaerobic terminal supernatant through the capacitive deionization system, the rear-end phosphorus load is reduced, the biological phosphorus removal process is enhanced, the sludge granulation is promoted, the requirement of the traditional biological phosphorus removal on a carbon source is reduced, and the purposes of phosphorus resource recovery and effective control on the effluent quality are achieved.

The invention belongs to the technical field of chemical synthesis, and particularly relates to a method for preparing 5-methylfurfural by using 2-methylfuran. The special solid acid catalyst is used for replacing traditional phosphorus oxychloride, hydrogen chloride and phosphorus-containing wastewater are eliminated from the source, and the sulfolane is used for replacing DMF (Dimethyl Formamide), so that solvent residues in the product are reduced. The solid catalyst SO4 < 2-> is modified to form a strong Bronsted acid site (-SO3H) which cooperates with Ce < 3 + > / Ce < 4 + > redox to inhibit carbon deposition, selectively activate 2-methylfuran alpha-C and inhibit side reactions, so that the selectivity and yield of a target product are improved. Na2CO3 neutralization is replaced by electrochemical neutralization, salt slag solid waste is eliminated, and environmental pollution is reduced. After the organic phase is dried and dewatered through a molecular sieve, most of the solvent is removed through rotary evaporation, and the residual crude product is subjected to centrifugal molecular distillation, so that unreacted raw materials and trace impurities are effectively removed, and the product purity is remarkably improved.