31 results about "Fluorapatite" patented technology

The invention discloses a process and system for recovering phosphorus and fluorine from ardealite leachate, which comprises the following steps: feeding the ardealite leachate into an induced crystallization reactor for induced crystallization, discharging generated large-particle fluorapatite crystals from a crystal discharge port at the bottom of the induced crystallization reactor, and collecting and recycling; aluminum hydroxide flocs and fine-particle fluorapatite crystals enter a cyclone separator along with the effluent, the fine-particle fluorapatite crystals are separated and then flow back to the induced crystallization reactor, the aluminum hydroxide flocs form precipitates in the flocculation sedimentation tank through flocculation to be removed, and the effluent of the flocculation sedimentation tank enters a multi-stage treatment system. According to the method disclosed by the invention, fluorine and phosphorus in the phosphogypsum leachate are recovered together, the recovered fluorapatite finished product is high in purity and can be recycled, and the amount of chemical sludge is also greatly reduced, so that the treatment cost of the sludge is reduced.

The invention discloses a process and equipment for synthesizing fluorapatite from wastewater, the equipment comprises a blending tank, a dispensing tank, a crystallization fluidized bed reactor, a reaction tank, a coagulation tank, a flocculation tank, a sedimentation tank, a pH detection device, a lift pump and a control system, fluorine-containing sewage and phosphorus-containing sewage are mixed in the blending tank, so that the molar ratio of fluorine to phosphorus is 0.34-0.4; the method comprises the following steps: adding fluorapatite into a reaction tank, adjusting the pH value to 7.5-8.5, pumping the fluorapatite and lime slurry into a crystallization fluidized bed reactor according to a calcium-phosphorus molar ratio of (3-3.5): 1, carrying out a crystallization reaction, naturally airing the generated fluorapatite crystals, carrying out a reaction on crystallization treatment water and the lime slurry in the reaction tank to remove fluorine and phosphorus, carrying out coagulation, flocculation and precipitation treatment, and discharging the effluent after reaching the standard. The high-quality fluorapatite product is prepared from the fluorine-containing sewage and the phosphorus-containing sewage, so that the preparation cost is low, and resourceful treatment of the fluorine-containing sewage and the phosphorus-containing sewage is realized.

The invention provides an enamel veneering repair material and a preparation method thereof, and belongs to the technical field of ceramic forming products. In order to further improve the attaching property of a tooth veneering material, reduce the amount of abraded tooth tissues and reduce the risks of ceramic collapse and falling off. Zirconium oxide, aluminum oxide, hydroxyapatite, silica dimethylsilylate, silicon dioxide, fluorapatite, magnesium oxide, thermosetting acrylic resin, aluminum hydroxide gel, a silane coupling agent, polyvinyl alcohol, sodium phytate and the like are adopted as raw materials, all the components are matched according to a certain proportion, and a special technology is adopted for preparing the tooth patch. While good biocompatibility, high hardness and wear resistance are ensured, the adhesion can be further improved, the removal amount of tooth tissues by grinding is reduced, the risks of ceramic collapse and falling are reduced, the service life is prolonged, and better use experience is provided.

The invention belongs to the technical field of environmental protection and resource recovery, and relates to a method for preparing fluorapatite based on PFAS. The preparation method comprises the following steps: mixing pretreated calcium oxide, phosphorus-containing calcium salt and PFAS, grinding and calcining to obtain the fluorapatite. According to the method, the low-cost calcium-containing oxide is used as a reactant, directional conversion and stabilization treatment of the pollutant PFAS are achieved, the reaction product is recyclable phosphate ore, and a new reference thought is provided for degradation of the PFAS in the environment.

According to the method, phosphate concentrate is used as a main material, a compression molding agent and a roasting auxiliary are used as auxiliary materials, and the bulk purified phosphate concentrate is prepared through material mixing, standing, scattering, aging, compression molding, drying and roasting in sequence. A compression molding process is adopted, the addition amount of water in the material is accurately controlled, an auxiliary material compression molding agent is introduced, it is guaranteed that the material has enough plasticity and is smoothly pressed and molded, meanwhile, a roasting auxiliary agent is introduced in a targeted mode, the compact block phosphate concentrate with certain hardness is obtained, the sintering vitrification temperature is effectively reduced, and the quality of the product is improved. Release, purification and utilization of fluorapatite in the phosphate concentrate are achieved to the maximum extent, a theoretical basis is provided for large-scale production, and the method is suitable for the field of ore utilization.

[Problems] To provide a column-use adsorbent having an excellent balance of adsorption capacity and durability, and an adsorption apparatus. [Means to solve problems] A column-use adsorbent made of powder of a porous particle group of hydroxyapatite or fluoroapatite formed by replacing at least part of a hydroxyl group of hydroxyapatite with fluorine atom, the porous particle group being a group of a plurality of porous particles having different particle sizes, the porous particle group meeting the condition of DAv × 45 / 100 <_ D10 ≤ DAv × 75 / 100, in which DAv (µm) is an average particle size, and D10 (µm) is a particle size at which a cumulative volume of the porous particles from the small size side based on a particle size distribution is 10%.

The application belongs to the technical field of phosphogypsum resource utilization, and particularly relates to a method for directionally recovering fluorapatite from phosphogypsum leaching solution. The method comprises the following steps: performing rough filtration and flocculation pretreatment on the phosphogypsum leaching solution to remove suspended solid matters; then adding an alkaline precipitant to adjust the pH to 6-12 to remove precipitates; then adding a Ca source according to a Ca:P:F molar ratio of (4.8-5.2):(2.8-3.2):(0.8-1.2), or simultaneously adding the Ca source and a P or F source, adjusting the pH to a favorable crystallization interval of 7-9, introducing fluorapatite crystal seeds to stir and crystallize or to stir and crystallize by cooling, and performing solid-liquid separation, so that the obtained solid phase is Ca5(PO4)3F. Through specific synergistic regulation, conditioning, adjustment and induced crystallization process, the method can directionally recover high-purity fluorapatite from the phosphogypsum leaching solution.

The application provides a fluorapatite phosphate ore reverse flotation magnesium removal collector and application thereof, which comprises basic substances and water, and the basic substances are mixed according to the mass ratio, wherein the ratio of fatty acid soap, surfactant and additive is 11:3:2; the fatty acid soap is one or a mixture of two of sodium oleate, oxidized paraffin soap; the surfactant is one or any ratio of sodium dodecyl sulfonate, sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, sodium citrate, sodium acetate and sodium benzoate; and the additive is sodium naphthenate. The fluorapatite phosphate ore reverse flotation magnesium removal collector provided by the application can effectively separate apatite and dolomite, significantly improve the collecting capacity and selectivity by adding surfactants and additives, and the surfactant composition weakens the influence of Fe 3+ on the flotation system.

The invention belongs to the technical field of ardealite resource utilization, and particularly relates to a method for recycling fluorapatite from ardealite leacheate through ion activity control. The method comprises the following steps: carrying out on-line detection on a fluorapatite saturation index on a phosphogypsum leacheate stock solution, and adjusting the supplementing amount of a Ca source / a P source / an F source in real time to keep a system supersaturated; adding background electrolyte, a complexing agent and a crystal face regulating agent into the treated solution to obtain a crystal precursor solution; controlling the temperature to be 50-90 DEG C, adjusting the pH value of the system to be 6.4-6.9, supplementing Ca < 2 + >, adding FA seed crystal, and uniformly stirring and mixing; the temperature is increased to 70-95 DEG C, the pH is increased to 6.8-7.8, a surface rearrangement accelerant is added for directional crystallization and solid-liquid separation, a solid product is washed and dried, and fluorapatite is obtained. FA crystal nucleation is controlled and regulated through ion activity, so that the yield and the purity of a target product are remarkably improved.

The present invention belongs to the fields of luminescent materials and biomedical materials, and provides a fluorapatite material with both upconversion fluorescence and photothermal conversion and a preparation method thereof. The preparation method includes the following steps: (1) Dissolve a Ca 2+ source, a Ln1 3+ source, and a Ln2 3+ source in deionized water to obtain solution A; dissolve a PO4 3‑ source, an F ‑ source, and a MoO4 2‑ source in deionized water to obtain solution B; (2) Drop solution B into solution A, and stir for 1-2 h after the dropping is completed to obtain a reaction precursor solution; (3) Perform a hydrothermal reaction on the reaction precursor solution; (4) Perform a thermal activation treatment on the obtained hydrothermal product; (5) Disperse the obtained activated powder in an aqueous solution of Fe 3+ , perform a hydrothermal reaction, wash, and dry to obtain the product. The present invention can endow an upconversion fluorescent material with good photothermal conversion performance without compounding a photothermal conversion agent, and simplifies the preparation method of a material with both upconversion fluorescence and photothermal conversion performance.

The invention provides a red shale whitening method and system based on microwaves, and the method comprises the following steps: crushing red shale, and carrying out ultrasonic-ball milling treatment to obtain rock particles with hydroxyl active sites generated on the surfaces; coating the rock particles and the prepared fluorapatite-szaibelyite core-shell particles with a modified gelatin solution to form an organic-inorganic composite interface layer; a microwave field is applied in a roller kiln, and after the calcination temperature is controlled to be 850-950 DEG C and the reaction is performed for a preset time, a whitened red shale particle product is obtained. Compared with a traditional high-temperature whitening process, the method has the advantages that the energy consumption and the treatment temperature are remarkably reduced, and the Fe < 3 + > removal rate and the product whiteness are improved.

This invention provides a dental enamel veneer restorative material and its preparation method, belonging to the technical field of ceramic molding products. To further improve the adhesion of dental veneer materials, reduce the amount of tooth structure removed, and decrease the risk of chipping and detachment, this invention uses zirconium oxide, alumina, hydroxyapatite, dimethylsilylated silica, silicon dioxide, fluorapatite, magnesium oxide, thermosetting acrylic resin, aluminum hydroxide gel, silane coupling agent, polyvinyl alcohol, and sodium inositol hexaphosphate as raw materials. These components are combined in specific proportions, and a special process is used to prepare the dental veneers. While ensuring good biocompatibility, high hardness, and wear resistance, this invention further improves adhesion, reduces the amount of tooth structure removed, decreases the risk of chipping and detachment, extends service life, and provides a better user experience.

The present application relates to coal chemical wastewater treatment technical field, specifically to a kind of coal chemical wastewater fluorine and hardness removal technology pellet directional induction seed, the pellet directional induction seed, including following weight parts components: quartz sand 100-200 parts, cement 20-30 parts, fluorapatite 75-100 parts, composite modified volcanic rock 35-50 parts, zeolite powder 60-80 parts.The pellet directional induction seed obtained in the present application is composed of quartz sand, cement, fluorapatite, composite modified volcanic rock and zeolite powder, wherein the composite modified volcanic rock can make calcium, magnesium and other metal ions crystallize and form crystals by adsorption, and can limit the flow of crystals, thereby achieving efficient removal of metal ions in wastewater, zeolite powder has porous structure and mobile point on the surface, and by dynamic adsorption, fluorine ions are linked together to form a network and then crystallize and precipitate, and through the cooperation of each component, fluorine and hardness removal of wastewater can be efficiently achieved.

The invention provides a preparation method of water purification ceramic capable of improving microbial activity, and belongs to the technical field of ceramic. The water purification ceramic is prepared from the following raw materials in parts by mass: 25 to 45 parts of quartz powder, 5 to 25 parts of talcum powder, 10 to 35 parts of modified kaolin, 1 to 10 parts of tin oxide powder, 0.5 to 8 parts of nickel oxide powder, 5 to 20 parts of titanium dioxide powder, 1 to 15 parts of fluorapatite powder, 0.1 to 1 part of high-temperature anti-agglomeration aid, 0.5 to 5 parts of adhesive and 35 to 55 parts of solvent. Through the synergistic effect of all the components in a certain range, the prepared ceramic is used in a water environment, the metabolic rate of beneficial microorganisms can be increased, the growth and activity of the beneficial microorganisms can be promoted, and the ceramic has an obvious inhibition effect on bacteria such as staphylococcus aureus and the like and shows relatively high purification efficiency.

The invention discloses a tooth whitening strip and a preparation method, and relates to the technical field of oral care. According to the invention, the two key components, namely the adhesive and the desensitization protective agent, of the tooth paste are respectively designed and the synergistic effect of the adhesive and the desensitization protective agent is fully exerted, so that on one hand, the adhesion of the gel layer of the wet tooth paste on the tooth surface and the toughness of the tooth paste are improved, and the gel layer is not easy to fall off or break or remain on the tooth surface; on the other hand, calcium ions, phosphate ions and fluorine ions released by the desensitization protective agent promote generation of acid-resistant fluorapatite and induce remineralization on the enamel surface, and microscopic damage is repaired; and a cross-linked network formed by the adhesive in a gel layer matrix is beneficial to enriching the ions and leading the ions to a to-be-repaired part quickly. The tooth whitening paste can better protect and repair the tooth surface while playing a whitening role, and better oral care experience is provided for a user.

The invention relates to the technical field of ceramic materials, and discloses an impact-resistant composite ceramic material as well as a preparation method and application thereof. The preparation method of the impact-resistant composite ceramic material comprises the following steps: mixing potassium feldspar, quartz, kaolin, wollastonite, bentonite, calcium silicate, talc, aluminum oxide and reduced composite modified zirconium oxide powder to obtain a green body material; mixing potassium feldspar, albite, quartz sand, calcite, dolomite, kaolin, talc, fluorapatite, aluminum oxide, zinc powder and silicon carbide whiskers to obtain a mixture, and performing ball milling and sieving to obtain glaze slurry; preparing the green body material into a ceramic green body base body; and applying the glaze slurry to a ceramic green body matrix, and sintering step by step to obtain the impact-resistant composite ceramic material. The impact-resistant composite ceramic material provided by the invention has good glossiness and aesthetic degree, and has excellent impact resistance and thermal shock resistance.

The invention relates to the technical field of preparation of fluorapatite structure fluorescent powder, in particular to europium and terbium double-doped fluorapatite fluorescent powder as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving soluble strontium salt, soluble terbium salt, soluble europium salt, NH4H2PO4 and N2H4H2O into water together to obtain a mixed solution; and adding soluble hexafluorophosphate into the mixed solution, carrying out coprecipitation reaction, washing and centrifuging to obtain the europium and terbium double-doped fluorapatite fluorescent powder. The preparation method disclosed by the invention is simple and efficient, realizes reaction under the condition of room temperature, remarkably shortens the reaction time, reduces the energy consumption, realizes green synthesis of the fluorapatite fluorescent powder, and effectively overcomes the defects of a traditional high-temperature solid-phase method and a hydrothermal reaction method.

The invention relates to the field of glass product processing, and particularly discloses an anti-burst glass bottle and a preparation process thereof. The anti-burst glass bottle comprises an inner blank body, a middle layer and a protective layer which are sequentially contacted from inside to outside, and the inner blank body is prepared from the following raw materials: cordierite, bismuth oxide and AIN ceramic powder in a mass ratio of 1: (0.03-0.05): (0.2-0.4); the middle layer comprises the following raw materials: aluminum silicate fiber, polyethylene fiber and silicon dioxide aerogel in a mass ratio of 1: (0.3-0.4): (10-15); the protective layer comprises the following raw materials: wollastonite glass powder and fluorapatite glass powder in a mass ratio of 1: (0.2-0.3). The anti-burst glass bottle has the advantages that the anti-burst effect is good, the splashing condition of broken glass fragments is reduced, and the safety is high.

The application discloses europium-doped apatite-based red fluorescent powder and a preparation method thereof, and relates to the technical field of luminescent materials. 10‑x (PO4)6F2:xEu 3+ ; wherein x is Eu 3+ doping substitution Ca 2+ , and the molar ratio of Eu 3+ is 0.02<=x<=0.2. The preparation method mainly uses a calcium source, a fluorine source, a phosphate, and an Eu 3+ containing compound as raw materials, and the fluorescent powder can be obtained through hydrothermal heating at a temperature of 150-250 DEG C, cleaning and drying. The prepared fluorescent powder shows strong narrow-band red emission under excitation of ultraviolet light of 390 nm, the emission wavelength ranges from 579 nm to 696 nm, and the main peak is at 618 nm; the color temperature is 2138.74 K, and the color coordinates are about (0.5896, 0.3385), so the prepared fluorescent powder can be used as a red fluorescent powder with relatively good thermal stability. The preparation process is simple, green and environmentally friendly, and is convenient for large-scale production.

The invention belongs to the field of luminescent materials and biomedical materials, and provides a fluorapatite material with both upconversion fluorescence and photothermal conversion and a preparation method thereof. The preparation method comprises the following steps: (1) dissolving a Ca < 2 + > source, an Ln13 < + > source and an Ln23 < + > source in deionized water to obtain a solution A; dissolving a PO4 < 3-> source, an F <-> source and a MoO4 < 2-> source in deionized water to obtain a solution B; (2) dropwise adding the solution B into the solution A, and stirring for 1-2 hours after dropwise adding to obtain a reaction precursor solution; (3) carrying out hydrothermal reaction on the reaction precursor solution; (4) carrying out thermal activation treatment on the obtained hydrothermal product; and (5) dispersing the obtained activated powder in an aqueous solution of Fe < 3 + >, and carrying out hydrothermal reaction, washing and drying to obtain the Fe < 3 + >-doped porous carbon material. According to the invention, the upconversion fluorescent material can be endowed with good photothermal conversion performance on the basis of no need of compounding a photothermal conversion agent, and the preparation method of the material with both upconversion fluorescence and photothermal conversion performance is simplified.

The invention provides a fluorapatite phosphorite reverse flotation magnesium removal collecting agent and application thereof.The fluorapatite phosphorite reverse flotation magnesium removal collecting agent comprises basic substances and water, and the basic substances comprise fatty acid soap, a surfactant and an auxiliary agent according to the mass ratio of 11: 3: 2; the fatty acid soap is one or a mixture of sodium oleate and oxidized paraffin soap; the surfactant is one or any ratio of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, lauryl sodium sulfate, sodium citrate, sodium acetate and sodium benzoate; according to the fluorapatite phosphorite reverse flotation magnesium removal collecting agent, apatite and dolomite can be effectively separated, the collecting capacity and selectivity of the fluorapatite phosphorite reverse flotation magnesium removal collecting agent are remarkably improved by adding the surface active agent and the auxiliary agent, and meanwhile the influence of Fe < 3 + > introduced in the ore grinding process on a flotation system is weakened through the surface active agent component.

This invention relates to the field of ceramic materials technology, and discloses an impact-resistant composite ceramic material, its preparation method, and its application. The preparation method of the impact-resistant composite ceramic material includes the following steps: mixing potassium feldspar, quartz, kaolin, wollastonite, bentonite, calcium silicate, talc, alumina, and reduced-treated composite modified zirconium oxide powder to obtain a green body material; mixing potassium feldspar, sodium feldspar, quartz sand, calcite, dolomite, kaolin, talc, fluorapatite, alumina, zinc powder, and silicon carbide whiskers to obtain a mixture, which is then ball-milled and sieved to obtain a glaze slurry; forming the green body material into a ceramic green body matrix; applying the glaze slurry onto the ceramic green body matrix, and sintering in stages to obtain the impact-resistant composite ceramic material. The impact-resistant composite ceramic material of this invention has excellent gloss and aesthetics, and also exhibits excellent impact resistance and thermal shock resistance.

The invention discloses a fluoroapatite nanorod with a magnesium-rich amorphous layer on the surface and a preparation method thereof. The preparation method of the fluoroapatite nanorod with a magnesium-rich amorphous layer on the surface comprises the following steps: dissolving a soluble calcium salt and a soluble magnesium salt in water to obtain a mixed solution A; dissolving a soluble phosphate and a soluble fluoride salt in water to obtain a mixed solution B; slowly dropping the mixed solution B into the mixed solution A, and after the dropping process is completed, sequentially standing and aging at room temperature, centrifugal washing, and freeze drying are performed to obtain a fluoroapatite nanorod powder with a magnesium-rich amorphous layer on the surface; the invention regulates the crystallinity and morphology of the fluoroapatite nanorod by changing the concentration of magnesium ions in the mixed solution A and the dropping rate of the mixed solution B, and successfully realizes the large-scale preparation of the fluoroapatite nanorod powder with a magnesium-rich amorphous layer on the surface through a one-step method; the preparation process of the invention has simple raw materials, low cost, mild reaction, and simple operation.

Disclosed in the present invention are a toothpaste for repairing tooth enamel and a preparation method therefor. The toothpaste of the present invention comprises calcium phosphosilicate, calcium sodium phosphosilicate, porous silica, polyethylene glycol, sodium fluoride, olaflur, hydrated silica, and a toothpaste matrix component. According to the present invention, the release speed of calcium and phosphate ions is regulated and controlled by optimizing the ratio of the calcium phosphosilicate to the calcium sodium phosphosilicate, and in addition, the fluoride and the polyethylene glycol are loaded in the porous silica, such that the hydrogen bond effect between the fluoride and the polyethylene glycol can further reduce the release speed of the fluoride in the oral cavity, a small number of fluorine ions released in the early stage of tooth brushing can promote remineralization, and a large number of fluorine ions released in the later stage of tooth brushing can convert newly generated hydroxyapatite into fluorapatite with higher hardness.

The invention relates to the technical field of ceramics, in particular to a light-variable antique glazed tile and a preparation process thereof, and aims to solve the problems that an existing antique glazed tile is uneven in aging effect, raw material tradition and practicability are difficult to balance, and blank glaze matching is poor. The glazed tile comprises a green body and a composite glaze layer covering the surface of the green body, wherein the composite glaze layer is of a double-layer structure of base glaze and dark fringe functional glaze; the base glaze is based on porcelain clay, potassium feldspar and modified quartz, and mixed plant ash and the like are added; the dark fringe functional glaze takes tungsten oxide and fluorapatite as cores, and wollastonite short fibers and the like are added. The preparation process comprises the steps of green body pretreatment, composite glaze preparation, gradient glazing and segmented temperature control sintering. Natural aging can be achieved in a short time, the warm and moist feeling of a traditional glaze surface is reserved, the blank glaze matching performance and the glaze layer durability are improved, cost is reduced, and the method is suitable for ancient building repair and pseudo-classic buildings.

Object: To provide an adsorbent having improved durability and improved adsorbability of a substance to be adsorbed, and a method for manufacturing the adsorbent. Resolution means: An adsorbent of the present invention is to be packed in a column, and is composed of powder containing particles whose surface is made of hydroxyapatite or fluorapatite in which at least some of hydroxyl groups of the hydroxyapatite have been replaced with fluorine atoms, the powder being composed of porous bodies with pores, the powder having an average particle size of 10 µm or more and 90 µm or less, the powder having an average particle compressive strength of 7.4 MPa or more and 8.9 MPa or less, and a modal pore size in a pore size distribution of the pores of the powder being 32.0 nm or more and 60.0 nm or less.

The application belongs to the technical field of phosphogypsum resource utilization, and particularly relates to a method for recovering fluorapatite from phosphogypsum leaching solution by ion activity control. The method comprises the following steps: on-line detection of fluorapatite saturation index of phosphogypsum leaching solution original solution, real-time adjustment of Ca source / P source / F source supplementing amount to keep the system supersaturated; addition of background electrolyte, complexing agent and crystal face control agent in the above-processed solution to obtain a crystallization precursor solution; control of temperature to 50-90 DEG C, adjustment of system pH to 6.4-6.9, supplementing of Ca 2+ and addition of FA crystal seeds to stir and mix uniformly; increase of temperature to 70-95 DEG C and increase of pH to 6.8-7.8, addition of surface rearrangement promoter for directional crystallization, solid-liquid separation, washing and drying of the solid product to obtain fluorapatite. The application controls and regulates FA crystal nucleation through ion activity control, thereby significantly improving the yield and purity of the target product.

The application discloses a tooth appliance with a surface-modified antibacterial composite coating and a preparation method thereof. The tooth appliance with the surface-modified antibacterial composite coating is prepared by the following steps: preheating a Tris·HCl solution, adding minocycline hydrochloride into the solution, adjusting the pH of the solution, adding dopamine hydrochloride into the solution to obtain a mixed solution, immersing a pretreated tooth appliance in the mixed solution under stirring, taking out the tooth appliance, washing and drying the tooth appliance, and obtaining the tooth appliance with a polydopamine coating loaded with minocycline. The tooth appliance is placed in 1.5 times of a simulated body fluid with fluorine ions, immersed in a constant-temperature shaking table, washed with deionized water, and dried to obtain the tooth appliance with a composite coating composed of polydopamine and fluorapatite and loaded with minocycline. The tooth appliance with the modified coating has excellent antibacterial performance in a simulated oral environment, and can reduce the adhesion amount of bacterial biofilm and inhibit the proliferation of bacterial biofilm.

The present invention discloses a method for analyzing the vertical evolution of the relative ancient water depth during the deposition period of organic-rich mud shale, and belongs to the technical field of petroleum geology. The method for analyzing the vertical evolution of the relative ancient water depth during the deposition period of organic-rich mud shale proposed by the present invention comprises the following steps: taking core samples from different depth areas along the vertical surface of the formation from a mud shale coring well containing carbon fluoroapatite nodules; for core samples from different depth areas, the longest transverse diameter and the longest vertical diameter of the carbon fluoroapatite nodules are statistically calculated from deep to shallow in the corresponding statistical area, and the ratio of the longest vertical diameter to the longest transverse diameter is calculated; the vertical change process of the ancient water depth during the deposition period of the mud shale is obtained by analyzing the change trend of all the longest transverse diameters and all the calculated ratios of the longest vertical diameters to the longest transverse diameters. The present invention obtains the vertical change process of the ancient water depth during the deposition period of the mud shale based on the characteristic analysis of the carbon fluoroapatite nodules.

The invention discloses a treatment method of high-fluorine silicon-containing waste acid, and belongs to the technical field of industrial wastewater treatment and resource recovery. According to the method, aluminum salt is preferentially added to precipitate silicon under the condition that the pH value is 2.5-4.0, calcium salt and phosphate are added to co-precipitate fluorine under the condition that the pH value is 6-8, fluorapatite is generated, deep purification can be further combined with an adsorption column, the removal efficiency of fluorine and silicon is remarkably improved, the sedimentation and separation performance of precipitates is improved, and the method is suitable for industrial production. Meanwhile, resource recycling of silicon and fluorine in the form of aluminosilicate and fluorapatite is achieved, and the comprehensive advantages of being simple in process, thorough in treatment and high in recycling value are achieved.