The invention provides high-reactivity coke and a manufacture method thereof, and the coke has an internal and external structure, wherein a core is prepared from blended coking coals and an external layer is prepared from high-volatile coals and blended coking coals through mixing. The method comprises: 1, blending coals; 2, preparing coal cores, comprising weighing 45% - 50% of coking coals, preparing the coal cores through crushing, binder addition, and ball-pressing, and sending into a soft asphalt spray room to spray asphalt to get the coal core; 3, processing external coking coals, comprising weighing 20% -25% of high-volatile coals, drying, crushing, screening and then sending particles with a grain size of less than 3 millimeters into a pre-mixer to evenly mix with 30% - 35% of coking coals; 4, preparing raw materials of finished products, comprising sending the external coking coals into a micro-swing mixing tank, and then putting in the coal cores to bond the external coking coals by mixing; 5, coking to get the finished coke. The high-reactivity cokes and manufacture method thereof are not only suitable for the present coke process to produce a high-reactivity and high-strength metallurgical coke with a low cost, but also can improve the operation of blast furnace production, thereby further reducing the ironmaking cost.