The invention belongs to the technical field of preparation of perfluorinated
sulfonic acid resin, and particularly relates to a bipolar membrane
electrodialysis device for preparing a perfluorinated
sulfonic acid resin solution and a preparation method. The device comprises an electrolytic bath, an
anode plate arranged at one end of the electrolytic bath, a
cathode plate arranged at the other end of the electrolytic bath, and an
anode chamber, a bipolar membrane
assembly and a
cathode chamber which are arranged between the
anode plate and the
cathode plate, wherein the anode chamber and the cathode chamber are connected in series; the bipolar membrane
assembly comprises a bipolar membrane, an acid chamber, a cation exchange membrane and an alkali chamber. According to the preparation method of the
perfluorosulfonic acid resin solution, the bipolar membrane
electrodialysis device is used for transformation preparation of the
perfluorosulfonic acid resin solution for the first time, a bipolar membrane is used for directly dissociating water to generate H < + > and OH, the
perfluorosulfonic acid resin solution is transformed into the perfluorosulfonic acid resin solution through a one-
step method, and compared with a traditional method, the preparation method has the advantages that the cost is low, and the efficiency is high. According to the method disclosed by the invention, the transformation rate and the yield are greatly improved, the
time cost and the labor cost are greatly saved, and
pollutant-free emission can be realized.