Method for producing potassium fertilizer and aluminum oxide by comprehensively using potassium feldspar

A technology of potassium feldspar and alumina, which is applied in the field of comprehensive utilization of potassium feldspar to produce potash fertilizer and alumina, can solve the problems of ineffective utilization, low aluminum dissolution rate, high equipment requirements, etc., and achieves the improvement of comprehensive utilization effect, The effect of saving raw materials and improving economic benefits

Inactive Publication Date: 2012-07-04
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main problems of the current research method are: on the one hand, the energy consumption in the sintering process is high, and the requirements for equipment are also high; on the other hand, the dissolution rate of aluminum is not high, generally 50% to 80%. Converted to aluminosilicate and cannot be effectively utilized

Method used

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  • Method for producing potassium fertilizer and aluminum oxide by comprehensively using potassium feldspar
  • Method for producing potassium fertilizer and aluminum oxide by comprehensively using potassium feldspar
  • Method for producing potassium fertilizer and aluminum oxide by comprehensively using potassium feldspar

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Effect test

Embodiment 1

[0047] Potassium feldspar (K 2 O content 9.5%, Al 2 o 3 Content 10.3%) and calcium chloride are ground to 1mm particle size, according to mass ratio potassium feldspar: calcium chloride: potassium carbonate=1:1:2 Weigh the material in the crucible, after mixing into balls, in the muffle furnace Calcination at 800°C for 2 hours, after cooling down to room temperature, take out the crucible and wash it with deionized water, move the washing solution to the reactor for water leaching experiment for 2 hours; then filter the leaching solution and fully wash the filter residue; The filtrate was transferred to a 500mL volumetric flask, and the K content of the sample was analyzed after constant volume. Take 200mL of the filtrate and pass through it with a sufficient amount of CO 2 , and then separate the precipitate from the filtrate, and carry out accurate weighing to calculate the content of Al therein.

[0048] After detection and calculation, the dissolution rate of K is 71.1...

Embodiment 2

[0050] Potassium feldspar (K 2 O content 9.5%, Al 2 o 3 Content 10.3%) and calcium chloride are ground to 1mm particle size, according to mass ratio potassium feldspar: calcium chloride: potassium carbonate=1:2:2 Weigh the material in the crucible, after mixing into balls, in the muffle furnace Calcination at 800°C for 2 hours, after cooling down to room temperature, take out the crucible and wash it with deionized water, move the washing solution to the reactor for water leaching experiment for 2 hours; then filter the leaching solution and fully wash the filter residue; The filtrate was transferred to a 500mL volumetric flask, and the K content of the sample was analyzed after constant volume. Take 200mL of the filtrate and pass through it with a sufficient amount of CO 2 , and then separate the precipitate from the filtrate, and carry out accurate weighing to calculate the content of Al therein.

[0051] After testing, the dissolution rate of K was 76.2%, and that of Al...

Embodiment 3

[0053] Potassium feldspar (K 2 O content 9.5%, Al 2 o 3 Content 10.3%) and calcium chloride are ground to 1mm particle size, according to mass ratio potassium feldspar: calcium chloride: potassium carbonate=1:1:3 Weigh the material in the crucible, after mixing into balls, in the muffle furnace Calcination at 900°C for 2 hours, after cooling down to room temperature, take out the crucible and wash it with deionized water, move the washing liquid to the reactor for water leaching experiment for 2 hours; then filter the leachate and fully wash the filter residue; The filtrate was transferred to a 500mL volumetric flask, and the K content of the sample was analyzed after constant volume. Take 200mL of the filtrate and pass through it with a sufficient amount of CO 2 , and then separate the precipitate from the filtrate, and carry out accurate weighing to calculate the content of Al therein.

[0054] After testing, the dissolution rate of K was 80.4%. The dissolution rate of ...

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Abstract

The invention relates to a method for producing a potassium fertilizer and aluminum oxide by comprehensively using potassium feldspar. The method comprises the following steps of: (1) smashing potassium feldspar and inorganic chlorate, and burdening potassium feldspar, inorganic chlorate and potassium carbonate in the mass ratio of 1:(1-2):(1-10); (2) pelletizing the prepared material, and sintering at the temperature of 500-1,200 DEG C for 1-5 hours to obtain a sintered material and generate CO2 gas simultaneously; (3) soaking the material obtained in the step (2) into water and filtering; (4) introducing a filtrate obtained in the step (3) into the CO2 gas obtained in the step (2) to obtain an aluminum hydroxide precipitate, and filtering; (5) adding a filtrate obtained in the step (4) into nesquehonite, introducing CO2 gas to obtain a complex salt precipitate, filtering and crystalizing a filtrate to obtain a potassium chloride chemical fertilizer; and (6) adding water for dissolving a complex salt obtained in the step (5) to obtain a solid of nesquehonite, circularly using, heating a potassium bicarbonate solution for decomposing to obtain a potassium carbonate solution for circularly using, and repeating the step (1) to the step (6).

Description

technical field [0001] The invention relates to the comprehensive utilization of potassium feldspar, in particular to a method for comprehensively utilizing potassium feldspar to produce potash fertilizer and alumina. Background technique [0002] my country is the largest agricultural country in the world, and is currently facing many agricultural problems, the most important of which is the production and quality of grain. Potassium fertilizer, as a basic fertilizer, has obvious effects on promoting photosynthesis of crops, improving the absorption and utilization of nitrogen by crops, enhancing the stress resistance of crops, and increasing food production. At present, the supply of potassium salt (fertilizer) in my country is far from meeting the needs of industry and agriculture. Most of the potash fertilizer (nearly 80%) depends on imports. not high. my country is rich in insoluble potassium ore resources, with reserves of nearly 10 billion tons, distributed almost al...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05D1/04C01F7/20
Inventor 李志宝高文成王均凤
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI
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