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836 results about "Coal pyrolysis" patented technology

Three-fluidized-bed solid heat carrier coal pyrolysis, gasification and combustion cascade utilization method

The invention discloses a three-fluidized-bed solid heat carrier coal pyrolysis, gasification and combustion cascade utilization method. The method comprises the following steps of: mixing coal and high temperature circulating ash serving as a solid heat carrier in a fluidized bed pyrolysis furnace, pyrolyzing to separate out volatile, cooling and separating the volatile to obtain tar and pyrolysis gas, conveying pyrolysis semi-coke generated by pyrolyzing the coal to a fluidized bed gasification furnace, performing gasification reaction by using water vapor and O2 as gasification agents to prepare synthesis gas, conveying the semi-coke which is incompletely gasified in the gasification furnace to a circulating fluidized bed combustion furnace, blowing air for the conventional combustion or blowing O2/CO2 for oxygen-enriched combustion, heating the circulating ash serving as the solid heat carrier, and producing gasification agent vapor required by the gasification furnace by using high temperature flue gas generated by combustion. The method has the advantages that: the tar, the pyrolysis gas and the synthesis gas are co-produced through coal pyrolysis, gasification and combustion cascade utilization, the gasification condition of the semi-coke is reduced, and good economic benefits and social benefits are achieved.
Owner:ZHEJIANG UNIV

Method for upgrading coal pyrolysis

The invention provides a method for upgrading coal pyrolysis, comprising the following steps: (a) sending raw coal with granularity being less than and equal to 30mm into a rotary drier, so that the raw coal and hot flue gas are connected with each other by the means of parallel flow and directly change heat, and the raw coal exchanges heat indirectly with hot semicoke from a pyrolyzer in the rotary drier, to dry the raw coal; (b) mixing the dried raw coal with the high-temperature semicoke from a heating rotary kiln and sending the mixture into the pyrolyzer, wherein the coal material directly changes heat with the high-temperature semicoke and pyrolyzes to generate hot semicoke, tar steam and coal gas, wherein final pyrolyzing temperature is 500 DEG C-700 DEG C; and (c) sending a part of the hot semicoke generated into the heating rotary kiln for processing by means of heating, and sending the rest part of the hot semicoke into the rotary drier for exchanging heat directly with the raw coal. The method for upgrading coal pyrolysis has flexible operation, wide granularity range of the coal material, good quality of the generated semicoke and the generated tar, high cascade utilization of energy and high system thermal efficiency, properly solving the technical problems such as dust and tar blocking, high dust content in the tar, etc.
Owner:CHNA ENERGY INVESTMENT CORP LTD +1

Sludge reduction and recycling treatment device and sludge treatment method

Provided are a sludge reduction and recycling treatment device and a sludge treatment method. The method includes the steps of performing spray drying on dewatered sludge, mixing coal pyrolysis, using pyrolytic carbon incineration ash as a raw building material, recycling pyrolysis oil and pyrolysis gas as supplement energy, performing up-to-standard discharging on flue gas emitted by a pyrolysis furnace after subjecting the flue gas to treatment in a spray tower, a mist removal device and an activated carbon adsorption bed, and supplying an incinerator with low heat of the pyrolysis furnace. The sludge reduction and recycling treatment device and the sludge treatment method have the advantages of being capable of achieving a sludge recycling recovery rate of 95%, a sludge reduction rate of over 96%, a heavy metal solidification rate of 95% and zero emission of pollutants; the generation of harmful gas such as dioxin is inhibited due to fully-enclosed oxygen-free environment pyrolysis and sulfur in coal; residual dioxin can be decomposed by being burnt at the temperature above 950 DEG C so as to ensure no generation and emission of dioxin in an entire reaction process of a system; a mixture of flue gas, low heat, pyrolysis gas and pyrolysis oil can be recycled, so that energy consumption and treatment costs are reduced.
Owner:天津德人生态环境科技集团有限公司

Method for increasing yield of coal-pyrolysis-based tar in reaction atmosphere of methane-rich gas mixture in fluidized bed

The invention belongs to the technical field of energy and provides a method for increasing the yield of coal-pyrolysis-based tar in the reaction atmosphere of a methane-rich gas mixture in a fluidized bed. The method is characterized by comprising the following steps: feeding the methane-rich gas mixture into the fluidized bed from the bottom of a pyrolysis reactor; conducting reaction firstly on a catalyst layer, so as to activate the gas mixture; adding the activated gas mixture as a fluidized gas to the fluidized coal in the fluidized bed, and subjecting the fluidized gas and the fluidized coal to pyrolysis and coking in a fluidized state; and subjecting the generated pyrolysis products to the treatment in a gas-solid separator, a condenser and an oil-water separator where carbocoal, coal gas and tar are respectively obtained. Accordingly, the activated gas mixture and the coal come into full contact through the coal pyrolysis in the fluidized bed, thereby help combining activated molecules with free radicals generated through the coal pyrolysis; the yield of pyrolysis-based tar is higher than that of the tar based on the pyrolysis conducted in the hydrogen atmosphere or inert atmosphere under the identical conditions; moreover, the catalysts are indirectly mixed with coal, thereby facilitating the cyclic regeneration and repeated use.
Owner:DALIAN UNIV OF TECH

Method for preparing hydrogen and liquefied natural gas through using gas retort raw gas

The invention discloses a method for preparing hydrogen and liquefied natural gas through using a gas retort raw gas. The method comprises the following steps: carrying out adsorbing pretreatment of the gas retort raw gas for removing tar and naphthalene in the gas retort raw gas, and allowing the obtained gas retort raw gas to enter a coal gas holder for buffering; pressurizing the buffered raw gas, allowing the pressurized raw gas to enter a sulfur-tolerant shift conversion reactor, and reacting carbon monoxide with steam to generate carbon dioxide and hydrogen; carrying out PDS wet desulphurization of the obtained shift conversion gas to obtain a byproduct sulfur, and regenerating a desulphurization liquid; carrying out a two-stage PSA (pressure swing adsorption) technology of the desulphurized shift conversion gas for carbon removal and hydrogen extraction; sending the obtained hydrogen to a tar hydrogenating apparatus as a raw material; carrying out pressurization and fine desulphurization of the obtained hydrogen extracted and desorbed gas, allowing the obtained gas to enter a methanation reactor, carrying out a methanation reaction of hydrogen in the desorbed gas, carbon monoxide and carbon dioxide to generate methane, drying the obtained generated gas, and allowing the generated gas to enter a cooling box; and liquefying methane through adopting a mixed refrigerating agent liquefying process to prepare the liquefied natural gas. The method increases the recycling efficiency of hydrogen and the comprehensive utilization efficiency of the raw material, and realizes the efficient and comprehensive utilization fo the coal pyrolysis raw gas.
Owner:HUADIAN HEAVY IND CO LTD

Fine coal pyrolysis reaction carbon burning circulation system

The invention provides a novel pulverized coal pyrolysis reaction charcoal burning circulation system, including a charcoal burner, etc., the cyclone separator of the charcoal burner is located in the charcoal burner, the cyclone separator of the settler is located in the settler, and the settler is located in the On one side of the charcoal burner, the external heat extractor and the charcoal burner are connected through an inclined pipe. The heat carrier riser passes through the bottom of the charcoal burner and is connected to the riser reactor. The main air distributor is located at the charcoal burner In the bottom of the device, one end of the U-shaped pipe for heat carrier circulation passes through the bottom of the charcoal burner and is connected to the main air distributor, the other end of the U-shaped pipe for heat carrier circulation is connected to the settler, and the air stripping section is located at the bottom of the settler Inside, one end of the riser reactor is connected to the settler, the other end of the riser reactor is connected to the heat carrier standpipe, and the main air pipe part passes through the bottom of the charcoal burner. The invention improves the utilization rate of pulverized coal resources and does not cause environmental pollution.
Owner:胜帮科技股份有限公司

Moving bed pulverized coal pyrolysis and fluidized bed coke powder gasification coupled device and coupling method thereof

The invention discloses a moving bed pulverized coal pyrolysis and fluidized bed coke powder gasification coupled device and a coupling method thereof. The device comprises a moving bed pulverized coal pyrolysis furnace and a fluidized bed coke powder gasification furnace which is connected with the moving bed pulverized coal pyrolysis furnace, wherein the moving bed pulverized coal pyrolysis furnace is communicated with the inlet of the fluidized bed coke powder gasification furnace through a low pipe, and is connected with a high-temperature deep deduster; coke powder dedusted by the high-temperature deep deduster is discharged from the lower end of the high-temperature deep deduster; dedusted pyrolysis coal gas and tar vapor enter a gas cooler to be cooled; and the condensed tar and water enter a separator, tar is separated, the coal gas from the gas cooler passes through a static tar removing device for further removal of tar, and finally the coal gas enters a purification system. In the invention, high-temperature coal gas in the fluidized bed coke powder gasification furnace is used as a carrier, pulverized coal is subjected to low-temperature pyrolysis in the moving bed pulverized coal pyrolysis furnace to release volatile matters for producing coal gas and tar, the coke powder obtained after pyrolysis is returned to the fluidized bed coke powder gasification furnace to be gasified into coal gas, and thus, the combined production of coal gas, semicoke and tar is realized.
Owner:陕西华祥能源科技集团有限公司

Rotary furnace low-order powdered coal pyrolysis upgrading method with coal gas circulation

The invention provides a rotary furnace low-order powdered coal pyrolysis upgrading method with coal gas circulation. The rotary furnace low-order powdered coal pyrolysis upgrading method comprises the following steps: heating and drying raw material powdered coal with the granularity less than or equal to 30mm to be 110-280 DEG C in a low-order powdered coal rotary drying system with dust collection, and removing 85% of coal dust with the granularity less than 0.5mm in the powdered coal; feeding the dried coal with the granularity of 0.5-30mm to a downstream rotary pyrolysis system to react at 500-700 DEG C so as to generate upgraded coal and a high-temperature oil gas; feeding the high-temperature upgraded coal to a rotary cooling passivating furnace for primary cooling and medium / low temperature passivation, further cooling by using a spiral cooling machine, spraying water, and discharging out the product; feeding the high-temperature oil gas into an oil gas recycling system, and performing temperature reduction separation, thereby obtaining coal tar, pyrolysis water and pyrolysis coal gas; preheating a part of the pyrolysis coal gas, circulating back to the pyrolysis furnace, and discharging out the rest part of the pyrolysis coal gas.
Owner:SHAANXI COAL & CHEM IND GRP SHENMU TIANYUAN CHEM IND +1

Purifying and tar recovery system for high temperature gas containing ash and tar and method thereof

The invention discloses a purifying and tar recovery system for high temperature gas containing ash and tar and a method thereof. A high temperature cyclone dust collector, a high temperature electric dust collector, an exhaust-heat boiler, a first level electrical tar precipitator, an intercooler, a second level electrical light oil precipitator and a gas exhauster are connected in order. High-temperature raw gas containing ash and tar from coal pyrolysis technology successively passes through the high temperature cyclone dust collector and the high temperature electric dust collector to be subjected to high temperature dusting; dusted raw gas is subjected to waste heat recovery in the exhaust-heat boiler by cooling water to generate low pressure steam; after the exhaust-heat boiler is cooled, the raw gas is introduced into the first level electrical tar precipitator for tar precipitation; output raw gas is cooled in the intercooler by cooling water; outlet gas enters into the second level electrical light oil precipitator; and purified is sent out by the gas exhauster. The invention can realize cooling, heat recovery and effective tar precipitation of high-temperature pyrolysis gas containing ash and tar, and greatly reduce waste water discharge, so as to save energy and reduce emission.
Owner:ZHEJIANG UNIV

Circulated coal gas heat carrier fluidized bed ash coal pyrolysis device and method

The invention discloses a circulated coal gas heat carrier fluidized bed ash coal pyrolysis device and method. The device comprises a coal-adding system and a fluidized bed pyrolyzing furnace which is communicated with the coal-adding system and provided with a coke-discharging hole, wherein the gas distributor of the fluidized bed pyrolyzing furnace is communicated with a high temperature heating furnace, the coal gas outlet of the fluidized bed pyrolyzing furnace is communicated with a first-stage cyclone separator, a second-stage cyclone separator, a high temperature deep dust collector and a gas cooler in turn through a pipeline, the lower outlet of the gas cooler is communicated with a separator, and the gas outlet of the gas cooler is connected with the high temperature heating furnace and a coal gas delivering device respectively. The device has simple flow and does not require an air separation device; as the circulated coal gas contains a lot of hydrogen, the hydropyrolysis of coal is realized to a certain extent, the yield of oil is increased to above 12%; and the operating pressure can be increased to the medium/high level, and industrial clusters and polygeneration are applied on the basis of equipment scale expansion while the products such as coal gas with high calorific value, semicoke, tar and the like are prepared.
Owner:陕西华祥能源科技集团有限公司

Double-cyclone coal pyrolysis gasification step converting device and double-cyclone coal pyrolysis gasification step converting method

The invention discloses a double-cyclone coal pyrolysis gasification step converting device and a double-cyclone coal pyrolysis gasification step converting method, and relates to a combusting device and a combusting method. The device is characterized in that a cyclone pyrolyzing furnace is communicated with a cyclone gasifying furnace by a material backing device and a pyrolyzing semi-coke channel; the cyclone gasifying furnace is communicated with the cyclone pyrolyzing furnace by a high-temperature raw coal gas channel; the cyclone pyrolyzing furnace is communicated with a cooling device by a pyrolyzing gas-mixing channel; an oxidant spray nozzle and a vapor spray nozzle are arranged on the outer wall of the cyclone gasifying furnace. The method is as follows: firstly, feeding coal dust into the cyclone pyrolyzing furnace under blocking and feeding of the high-temperature raw coal gas; secondly, pyrolyzing the coal dust in the cyclone pyrolyzing furnace, exhausting the pyrolyzed gas mixture into the cooling device, cooling, and conveying back the pyrolyzed semi-coke to the cyclone gasifying furnace; thirdly, spraying the oxidant and the vapor into the cyclone pyrolyzing furnace by the oxidant spray nozzle and the vapor spray nozzle at the same time, wherein the produced high-temperature raw coal gas is re-fed into the cyclone pyrolyzing furnace as a coal pyrolyzing gas heater carrier; coal residue in the cyclone gasifying furnace is exhausted through an ash residue discharge hole in the form of solid or liquid. The double-cyclone coal pyrolysis gasification step converting device and the double-cyclone coal pyrolysis gasification step converting method are used for gasifying clean coal gas.
Owner:HARBIN INST OF TECH

Coal thermal decomposition grate firing apparatus and its combustion method

The invention relates to a coal pyrolysis layer combustion device and the combustion method thereof, including that the furnace body interior of the first layer combustion furnace is divided into an upper oxidation pyrolysis chamber and a lower fire grate layer combustion chamber which is communicated with each other; the coal and desulfurizer are mixed to be fed into the middle part of the oxidation pyrolysis for oxidation pyrolysis through a hopper; the generated combustible gas and the smaller semi-coke particles are overflowed through the upper-connected through port or are carried in the airflow to be fed into the mechanical fire grate layer combustion chamber; the bigger semi-coke particles fall on the mechanical fire grate and are fed into the layer combustion layer for combustion; the mechanical fire grate layer combustion chamber is provided with a front arch and a back arch for organizing the airflow field inside the furnace; the coal pyrolysis layer combustion device and the combustion method thereof adopt the fluidization characteristics of the coal particles with different particle diameters and the high thermal capacity characteristic inside the oxidation pyrolysis chamber to realize the natural separation of the coal particles with different particle diameters and the rapid oxidation pyrolysis of coal, reduce the fire grate coal leakage loss and the incomplete combustion loss caused by the front segment low temperature of the fire grate and reduce the emission of the SOx and NOx pollutant through the combination of the pyrolysis desulfurization and the combustion desulfurization, and the reburning denitration formed by the coal pyrolysis product.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Coal pyrolysis gasification poly-generation device and process based on circulating fluidized bed

InactiveCN103881761ARealize hierarchical optimization utilizationTo solve the purpose of efficient purificationFluidized bed combustionCombustible gas productionElectricityCombustion
The invention discloses a coal pyrolysis gasification poly-generation device and process based on a circulating fluidized bed. A circulating fluidized bed boiler is organically coupled with a moving bed coal pyrolysis reactor and a moving bed gasification furnace, the high temperature circulation ash of the circulating fluidized bed boiler is used as a carrier for pyrolyzing high volatile coal steam coal from a coal funnel in the moving bed coal pyrolysis reactor, the semicoke generated in pyrolysis is separated out from the pyrolysis reactor and is fed into the moving bed gasification furnace for gasification, and at the same time the moving bed gasification furnace is used as a device for purifying a pyrolysis coal gas, thereby achieving the function of on-line dust collection of the pyrolysis coal gas. The gasified activated coke as a byproduct is discharged outside the reaction system. Therefore, through organic combination of three procedures, including pyrolysis, gasification and combustion, graded optimized utilization of the coal resource is achieved, joint production of heat, electricity, tar, coal gas and activated coke is achieved, and meanwhile the purposes of gasifying the coal gas and efficiently purifying the pyrolysis coal gas are achieved.
Owner:SHANXI LUAN MINING GRP +1

Device for preparing coal tar and coal gas by coupling semi-coke powder gasification and reformed gas pyrolysis and method using same

The invention discloses a device for preparing coal tar and coal gas by coupling semi-coke powder gasification and reformed gas pyrolysis. In the device, a semi-coke heating furnace is communicated with the lower part of a gasification and pyrolysis reactor, the top of the semi-coke heating furnace is communicated with an afterheat boiler, and the lower part of the semi-coke heating furnace is communicated with the upper part and a high-temperature semi-coke heat exchanger through valves; the high-temperature semi-coke heat exchanger is communicated with a crusher which is communicated with the lower end and the upper part of the gasification and pyrolysis reactor; the upper end of the gasification and pyrolysis reactor is communicated with a raw coke oven gas filter; the raw coke oven gas filter is communicated with the afterheat boiler, a semi-coke outlet and the upper part of the gasification and pyrolysis reactor; one outlet of the afterheat boiler is communicated with lower end of the gasification and pyrolysis reactor; an oil and gas outlet is communicated with an oil and gas separator; and the oil and gas separator is communicated with the middle part of the gasification and pyrolysis reactor through a circulating fan. A method preparing coal tar and coal gas by using the device comprises the steps of pulverized coal preparation and drying, semi-coke gasification, methane reforming, coal pyrolysis, gas and solid separation and oil and gas separation. The device and the method, which are disclosed by the invention, can be used for preparing coal tar and coal gas.
Owner:王树宽

Pyrolysis gasification coupling integrated poly-generation system and process for coal chemical industry

The invention provides a pyrolysis gasification coupling integrated poly-generation system and process for the coal chemical industry. The system comprises a coal preparation unit, a pyrolysis-gasification coupling system A and a poly-generation system B, wherein the poly-generation system B comprises a purified gas separation unit connected with the purified gas outlet of the pyrolysis unit, a purified tar separation unit connected with the purified tar outlet of the pyrolysis unit, and a chemical product synthesis unit and an IGCC (Integrated Gasification Combined Cycle) unit which are respectively connected with purified gasification gas outlet of the gasification unit; and the purified tar separation unit is sequentially connected with a coal tar hydrofining unit and an oil product separation unit. The pyrolysis gasification coupling integrated poly-generation system and process can be used for organically combining coal pyrolysis gasification and the production process of oil, gas, chemicals, electricity and heat to realize integration of material conversion and energy conversion, maximize classified utilization, value promotion, utilization efficiency and economical benefit of coal resources, and improve the energy utilization efficiency.
Owner:SHAANXI COAL & CHEM TECH INST

Coal-gas-circulation coal whole-size-grading pyrolytic coupling hot-pressing formed coke preparation technique and system

The invention provides a coal-gas-circulation coal whole-size-grading pyrolytic coupling hot-pressing formed coke preparation technique and system. Raw coal is divided into slack coal and pea coal by a raw coal preheating grading system; the coal gas generated by the method is used as a heat source for slack coal pyrolysis in a slack coal pyrolyzing furnace, and pyrolytic coal gas generated by slack coal pyrolysis is used as a heat source for pea coal pyrolysis; hot semicoke obtained after the slack coal and pea coal pyrolysis is used as a raw material for preparing the hot-pressing formed coke; and tar slag collected at the coal pyrolysis section is used instead of part of the adhesive for preparing the hot-pressing formed coke. The coal pyrolysis technique and hot-pressing formed coke preparation technique are coupled to produce the formed coke, thereby implementing graded utilization of coal and coke making of mill coal, saving the rare coke resources for the nation, and implementing high added value utilization of the product semicoke. The tar slag generated at the coal pyrolysis section is used as part of the adhesive instead of part of high-price coal pitch, thereby achieving the goal of waste reutilization. By using the hot semicoke as the raw material, the formed coke is formed under hot conditions, so that the heat utilization efficiency is high.
Owner:新疆乾海环保科技有限公司

Internally rotary dedusting type solid heat carrier and moving bed pulverized coal pyrolysis method and device

The invention discloses an internally rotary dedusting type solid heat carrier and moving bed pulverized coal pyrolysis method and device. The internally rotary dedusting type solid heat carrier and moving bed pulverized coal pyrolysis device comprises a cylinder body, wherein an upper sealing head is arranged at the top of the cylinder body; a pyrolysis gas outlet is formed in the middle of the upper sealing head; a collecting pipe box is defined between the upper sealing head and a collecting pipe box sealing head connected with the upper sealing head; a plurality of cyclone separator sets communicated with the collecting pipe box are arranged at the lower part of the collecting pipe box sealing head; a plurality of mixing pipes are symmetrically arranged on the two sides of the cylinder body; a coal gas inlet, a pulverized coal inlet and a heat carrier inlet are formed in each mixing pipe; a tapered lower sealing head is arranged at the lower part of the cylinder body; a discharge pipe is arranged at the bottom of the lower sealing head; a circulating semicoke blanking pipe and a product semicoke blanking pipe are symmetrically connected to the discharge pipe, and the discharge pipe and the blanking pipes form an inverted Y-shaped pipe branch; a valve is arranged on each of the circulating semicoke blanking pipe and the product semicoke blanking pipe. The pulverized coal used as the raw material is adequate in source, cheap, and easy to obtain; the device and the method have the characteristics of being wide in application range, simple in technological process, relatively low in investment, easy to operate, safe, stable and the like.
Owner:神木市锦丰源洁净煤科技有限公司

Dust removal device and method for oil gas during pulverized coal pyrolysis/retorting

The invention provides a dust removal device and method for oil gas during pulverized coal pyrolysis/retorting. The device comprises a dust removal pretreatment unit, an oil gas filter and a sand-blasting tank which are sequentially connected, wherein the dust removal pretreatment unit comprises at least two stages of cyclone separators connected in series; the oil gas filter adopts a closed tank, and nozzles, venture tubes, an oil gas purification chamber, a gas collecting chamber and dust hoppers are arranged in the oil gas filer from top to bottom sequentially; the nozzles are arranged at the top of the tank and communicated with the outside; the venture tubes are correspondingly and perpendicularly arranged below the nozzles; the oil gas purification chamber is perpendicular to the venture tubes and provided with hollow filter element groups inside, and the hollow filter element groups are in sealing connection with an upper tube plate and a lower tube plate of the oil gas purification chamber; the gas collecting chamber is coaxially communicated with filter elements; dust valves are arranged at the lower ends of the dust hoppers; the sand-blasting tank is a closed tank, a sand inlet is formed in the top and communicated with a sand pipeline inlet through a sand preheater, gas inlets are formed in the top and in the lower side part respectively and are communicated with a reverse blowing gas pipeline inlet through a reverse blowing gas preheater, and a sand outlet is formed in the bottom and communicated with the oil gas filter. The problems of poor oil gas dust removal effect, low efficiency, instable operation and the like of an existing device are solved.
Owner:SHAANXI COAL & CHEM IND GRP SHENMU TIANYUAN CHEM IND +1
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