4802results about "Special form destructive distillation" patented technology

A pyrolysis method and system are provided that enhances the production of C3 and C4 alkanes in the resulting pyrolysis effluent. More particularly, the disclosed pyrolysis method and system may be configured to enhance the production of C3 and C4 alkanes due to the use of certain pyrolysis catalysts and more intense pyrolysis conditions.

A process for upgrading plastic derived oil includes contacting the plastic derived oil with a mixed catalyst in a first reactor, where the mixed catalyst includes a decontamination catalyst and a cracking catalyst different from the decontamination catalyst. The first reactor reduces concentrations of halogen-containing compounds in the plastic derived oil. The process includes passing the first reactor effluent to a second reactor and contacting the first reactor effluent with the cracking catalyst to produce a second effluent comprising light olefins and naphtha range hydrocarbons. The process includes separating used mixed catalyst from the first reactor to produce a used decontamination catalyst and a second used cracking catalyst, and regenerating the decontamination catalyst and cracking catalyst in separate regenerators to reduce exposure of the cracking catalyst to halogen-containing compounds produced during regeneration of the used decontamination catalyst.

A stirring device is provided. The stirring device includes a stirring device body (10), a rotating shaft (11) arranged at the center of the stirring device body, a plurality of connecting rods (12) fixedly connected to the rotating shaft, and a regulating assembly (141,143,144,145,146,147). A tail end of each connecting rod is hinged with a scraper (13). The rotating shaft is rotatable around an axis of the rotating shaft under the driving of a driving component. The connecting rods are uniformly distributed along the length of the rotating shaft. The rotating direction of the scraper is located in a plane vertical to the axis of the rotating shaft. The regulating assembly is used for regulating a rotation angle of the scraper. Wherein, the scraper can be in flexible contact with an inner wall of the stirring device body under the regulation of the regulating assembly.

A method for pyrolysis of a mass of waste material, includes: providing a screw arrangement adapted to supply heat to the mass by mechanical shear; providing a reactor after the screw arrangement, adapted to supply heat to the mass in the absence of oxygen by heating the reactor wall; heating the mass to an exit temperature and increasing the pressure to an exit pressure in the screw arrangement; thermally degrading the mass in the reactor. The mass is brought into an extreme condition at the exit temperature and exit pressure by the screw arrangement, such that during the pressure drop pyrolysis occurs, thereby forming gaseous hydrocarbons within the connecting element.

A process for upgrading plastic derived oil includes contacting a plastic derived oil stream with a decontamination catalyst in a first reactor, separating a first reactor effluent from a used decontamination catalyst, passing the first reactor effluent to a second reactor downstream of the first reactor, contacting the first reactor effluent with a cracking catalyst in the second reactor, and separating a second reactor effluent from a used cracking catalyst. The cracking catalyst is different from the decontamination catalyst. The process further includes regenerating the used decontamination catalyst in a decontamination catalyst regenerator to produce regenerated decontamination catalyst, and regenerating the used cracking catalyst in a cracking catalyst regenerator separate from the decontamination catalyst regenerator to produce regenerated cracking catalyst. Regenerating the used cracking catalyst separately reduces deactivation of the cracking catalyst by halogen-containing compounds produced during regeneration of the decontamination catalyst.

The invention provides a bio-oil yield prediction method based on interpretable machine learning, and relates to the field of biomass pyrolysis technology and machine learning, and the method comprises the following steps: 1, obtaining a biomass pyrolysis original data set, and carrying out the preprocessing; 2, enhancing the preprocessed data by applying a condition table generative adversarial network CTGAN; 3, dividing the enhanced data set into a training set and a test set, performing training by adopting an extreme gradient enhanced XGB model, optimizing hyper-parameters of a BO model through Bayesian, and constructing a CTGAN-XGB-BO prediction model; and 4, performing model interpretation on the trained and optimized bio-oil yield prediction model. Compared with the prior art, the machine learning algorithm based on the CTGAN-XGB-BO model provided by the invention has the advantages that the prediction precision of the bio-oil yield is improved, the time and the cost of experimental research are reduced, and researchers can better understand and optimize the production process and improve the process control level due to explanation and analysis of the model.

Production systems and methods for producing pellets or pellet products, which can be used, e.g., in an electric arc furnace (EAF) to produce metal alloys, are disclosed herein. In some embodiments, a method for forming coke pellets includes (i) blending biomass with a set of materials to form an input blend, (ii) preconditioning the input blend by hydrating the input blend to generate a first plurality of particles, (iii) charging the first plurality of particles into an oven to produce a second plurality of particles via pyrolysis, (iv) post-conditioning the second plurality of particles to produce a third plurality of particles by exposing the second plurality of particles to at least one of an amphipathic binder, a hydrophobic binder, or a hydrophilic binder, and (v) physically altering the third plurality of particles to form coke pellets. The biomass can have a first volatility and the set of materials can have a second volatility lower than the first volatility.

Methods and systems for coking coal blends to produce foundry coke products are disclosed herein. Methods for producing coke products can include charging a coal blend into a coke oven; and heating the charged coal blend such that a crown temperature of the coke oven is greater than a lower bound coking temperature. The pyrolysis duration begins when the crown temperature of the oven is greater than the lower bound coking temperature, and ends when the crown temperature of the oven is less than the lower bound coking temperature.

Integrated processes and facilities for providing recycled content hydrocarbon products (r-products) from mixed waste plastic are provided. Carbon dioxide capture and energy recovery from one or more process streams described herein increase energy efficiency and help reduce overall environmental impact while producing valuable final products from chemically recycled waste plastic.

The invention discloses a large-scale pig breeding wastewater purification treatment system, and relates to the technical field of wastewater treatment.The large-scale pig breeding wastewater purification treatment system is characterized in that the ion concentration of anaerobic liquid is monitored through a multi-ion sensing array, and a multi-channel feeding system is controlled to synthesize customized struvite compound fertilizer; the AI prediction control unit predicts the optimal medicament dosage and realizes millisecond-level closed-loop regulation; the multi-dimensional synergistic biochemical treatment module comprises an A / O biochemical treatment unit and an electric field enhanced anaerobic ammonia oxidation reactor, the electric field enhanced anaerobic ammonia oxidation reactor applies a direct-current electric field through an electrode pair, and engineering conductive biochar is used as a carrier to accelerate microbial metabolism; the sludge low-temperature pyrolysis self-consistent circulation module is used for pyrolyzing and converting residual sludge into biochar, biofuel and wood vinegar, and the biochar activation treatment unit is used for preparing engineering conductive biochar and forming a substance closed loop through a self-consistent circulation conveying system; and the digital twinning intelligent management and control platform realizes intelligent management and control of the system.

According to the invention, biomass rice hull ash and a sodium hydroxide solution are reacted to obtain water glass and carbon mud. And reacting the water glass with CO2 generated by calcining the limestone to produce a white carbon black product and a mixed waste liquid of sodium carbonate and sodium bicarbonate. Meanwhile, quick lime obtained by calcining limestone is digested and then reacts with sodium carbonate and sodium bicarbonate mixed waste liquid to generate a light calcium carbonate product and dilute sodium hydroxide waste liquid. And finally, the dilute sodium hydroxide waste liquid is concentrated and reused for water glass production, so that the waste liquid is recycled, and a complete process closed loop is formed. According to the process method disclosed by the invention, two leading-edge innovative processes, namely production of white carbon black by renewable resource biomass rice hull ash and production of white carbon black by a carbonization method, are organically combined and are coupled with production of light calcium carbonate by a limestone calcination process, so that the problem that a large amount of sodium sulfate-containing wastewater is discharged in a traditional process is solved; meanwhile, the carbon footprint of white carbon black and calcium carbonate products is greatly reduced.

The invention discloses an optimal control method for a straw pyrolysis carbonization process. The method comprises: performing multipoint temperature real-time acquisition and data processing on a carbonization zone of a carbonization furnace, obtaining temperature information and calculating a deviation from a preset ideal temperature curve (S01); dynamically adjusting an operating parameter of the combustion zone using a control algorithm based on the temperature deviation (S02); performing on-line monitoring on the flue gas components (S03); and regulating and controlling the return air flow and the secondary air supply amount of the combustion area in a linkage manner according to the flue gas monitoring result so as to optimize combustion and energy recovery (S04). Through accurate and intelligent process control, efficient, environment-friendly and high-valued utilization of the straw carbonization process is realized.

Disclosed herein are methods for pyrolysis of plastic feedstock comprising post-consumer and / or post-industrial plastics. In various implementations, the methods include directing the plastic feedstock into an internal volume of a reactor vessel, and pyrolyzing the plastic feedstock in the internal volume of the reactor vessel.

It has been discovered that heat energy may be captured from the flue gas from a pyrolysis reactor, which was previously lost due to exhausting. More particularly, it has been discovered that residual heat energy from pyrolysis flue gas in a chemical recycling facility may be used to preheat waste plastic streams and provide heat for waste plastic pyrolysis. Consequently, the pyrolysis processes and systems described herein may obtain a lower carbon footprint.

Chemical recycling facilities for processing mixed plastic waste are provided herein. Such facilities have the capability of processing mixed plastic waste streams and utilize a variety of recycling facilities, such as, for example, solvolysis facility, a pyrolysis facility, a cracker facility, a partial oxidation gasification facility, an energy generation / energy production facility, and a solidification facility. Streams from one or more of these individual facilities may be used as feed to one or more of the other facilities, thereby maximizing recovery of valuable chemical components and minimizing unusable waste streams.

The invention provides a rapid waste plastic pyrolysis-catalysis device and a test method, and belongs to the field of waste plastic utilization. The problems that a traditional waste plastic pyrolysis-catalytic reaction device is uneven in heating and low in pyrolysis rate in the pyrolysis process are solved. A rapid pyrolysis-catalytic reaction device for waste plastics comprises a pyrolysis device, a catalytic reaction device and a catalytic reaction device, the pyrolysis device comprises a pyrolysis container, a heat-carrying medium and a heating device, the heat-carrying medium is filled in the pyrolysis container and is in a liquid state at a high temperature, and the heating device is arranged on the wall of the pyrolysis container; the catalytic cracking device comprises a reducer pipe, an electromagnetic induction heating device and a catalytic reaction core, the catalytic reaction core is arranged on the upper half section of the reducer pipe, and a coil of the electromagnetic induction heating device is arranged outside the catalytic reaction core. The device is mainly used for pyrolyzing plastics.

Disclosed herein are reactors for pyrolysis of plastic feedstock comprising post-consumer and / or post-industrial plastics. In various implementations, the reactors include a reactor vessel, and one or more heaters configured for heating the feedstock in the reactor vessel's internal volume.

Disclosed herein are reactors for pyrolysis of plastic feedstock comprising post-consumer and / or post-industrial plastics. In various implementations, the reactors include a reactor vessel, and one or more heaters configured for heating the feedstock in the reactor vessel's internal volume.

The invention belongs to the technical field of energy conversion equipment and solid resource pyrolysis conversion utilization, and discloses continuous replacement type pyrolysis equipment and a pyrolysis method thereof. The continuous replacement type pyrolysis equipment comprises a feeding system, a microwave generating system is arranged on one side of the feeding system, a carbon residue collecting system is arranged at the bottom of the feeding system, a continuous replacement system is installed in the microwave generating system, and a reaction system is installed in the continuous replacement system. One side, far away from the feeding system, of the reaction system is connected with a product collecting system; through the synergistic effect of microwave pyrolysis and dynamic replacement design, pyrolysis of crushed materials and tar cracking are integrated into a continuous process, efficient energy conversion is achieved, high-added-value products such as liquid fuel / chemicals and pyrolysis carbon residues are finally produced, and reduction, harmlessness and resourceful treatment of solid resources is promoted.

Disclosed herein are reactors for pyrolysis of plastic feedstock comprising post-consumer and / or post-industrial plastics. In various implementations, the reactors include a reactor vessel for receiving and pyrolyzing the plastic feedstock, and one or more heaters for heating the feedstock in the reactor vessel's internal volume.

The invention provides a pyrolysis recovery method of a plastic packaging bag, and belongs to the technical field of plastic packaging bag recovery, the pyrolysis recovery method of the plastic packaging bag comprises the following steps: removing impurities from the waste plastic packaging bag, cleaning and drying, and controlling the moisture to be below 5%; the packaging bag is crushed into small blocks with the diameter smaller than 20 mm, so that the pyrolysis efficiency is improved; feeding the crushed plastic into a pyrolyzing furnace through a spiral feeder, adding an auxiliary pyrolyzing component, heating to 300-600 DEG C under an oxygen-free or oxygen-deficient condition, and carrying out thermal cracking; oil gas obtained after pyrolysis is condensed through a cooling system and classified, and solid residues are subjected to tempering treatment; flue gas generated after combustion is subjected to high-temperature degradation through a secondary combustion chamber and then subjected to multistage treatment through a quench tower, dust removal, alkali spraying and activated carbon adsorption, and it is ensured that the flue gas reaches the standard and is discharged; the problems that in the existing pyrolysis recycling process of the plastic packaging bags, the treatment efficiency is low, and the environment is still polluted can be solved.

Disclosed herein are methods for pyrolysis of plastic feedstock comprising post-consumer and / or post-industrial plastics. In various implementations, the methods include directing the plastic feedstock into an internal volume of a reactor vessel, and pyrolyzing the plastic feedstock in the internal volume of the reactor vessel.

The invention provides a biomass and coal complementary gasification decarburization and hydrogen production method and system.The method comprises the steps that biomass is dried to generate dry biomass, one part of the dry biomass enters a combustor, the other part of the dry biomass and pretreated coal form pyrolysis fuel, and the pyrolysis fuel enters a pyrolysis furnace; the dry biomass and the hot air are combusted in the combustor to generate heat and first flue gas; the heat and the first flue gas are adopted to supply heat to a gasification furnace, coke from a pyrolyzing furnace is gasified, and synthesis gas is generated; second flue gas is discharged after the first flue gas supplies heat to the gasification furnace, the second flue gas supplies heat to the pyrolysis furnace, pyrolysis fuel is pyrolyzed, coke is generated, pyrolysis gas is fed back to the gasification furnace, and the coke is fed back to the pyrolysis furnace; the synthesis gas and the pyrolysis gas form a first mixed gas, tar is removed through tar separation, and a pure mixed gas is generated; and after the pure mixed gas is subjected to water vapor shift reaction and carbon capture, hydrogen with relatively high purity is obtained. According to the invention, carbon-hydrogen component complementation of coal and biomass is realized, the yield of gaseous products is increased, and the overall carbon emission is effectively reduced.

It has been discovered that use of a single reactor for melting waste plastics and pyrolyzing the melted waste plastics can lower the carbon footprint of a chemical recycling facility. More particularly, by melting and pyrolyzing in the same reactor vessel, one may mitigate the need for additional heat sources, thereby decreasing the potential need to combust additional fossil fuels for heating purposes. Consequently, by utilizing the plastic liquification and pyrolysis reactor described herein, one can lower the carbon footprint of the chemical recycling facility described herein.

Process for feeding plastic material, e.g. a plastic waste, to a processor such as a thermochemical reactor, e.g. a pyrolysis reactor. The process comprises an optional shredder or disintegrator (1), a conveying system (2), a feed hopper (3) with a lock hopper or rotary valve, a melting tank (6) with an agitator (5) followed by a melt pump (7) for the delivery of molten plastic to the processor. The advantage of the current process includes the ability to supply a consistent, metered flow to the processor, independent of the recycled plastic's melt properties, or the form or particle size and distribution of the plastic material.

The present invention relates to the treatment of plastic materials to be used for chemical recycling processes for the enhancement of substantially plastic materials otherwise destined for disposal.Specifically, the invention relates to a process for the pyrolysis of substantially plastic material to obtain at least hydrocarbons that are liquid at 25° C., comprising the following steps:a) feeding a substantially plastic material to a pyrolysis reactor;b) bringing said material in said pyrolysis reactor to a temperature of between 330° C. and 580° C. in the substantial absence of oxygen and at a pressure of between atmospheric pressure and 13 bara;c) maintaining said material in said pyrolysis reactor for a sufficient amount of time to produce an effluent in the gaseous state;d) partially or fully condensing said effluent in the gaseous state, so as to form at least one fluid comprising hydrocarbons that are liquid at 25° C. and which quantitatively is at least 10% by mass with respect to the mass of substantially plastic material fed;e) carrying out an assessment of at least one property “Px” of the liquid condensed from said effluent in the gaseous state by means of at least one measurement “Ax” of the spectrum in transmission, reflection or transflexion on said condensed liquid;f) adjusting at least one process parameter “Ox” according to said assessment of at least one property “Px”;g) repeating steps e) and f) iteratively so as to keep the said at least one property “Px” substantially constant over time.

The invention discloses an operation method and system for distributed organic solid waste centralized treatment and quality improvement and application, and relates to the field of chemical engineering, the operation method comprises the following steps: respectively carrying out pyrolysis treatment on organic solid waste distributed in different areas to obtain combustible gas and solid combustible materials and / or pyrolysis oil, using the combustible gas as fuel for pyrolysis treatment, and using the solid combustible materials and / or pyrolysis oil for pyrolysis treatment; the solid combustible comprises carbon powder and / or pyrolysis residues; concentrating and gasifying the solid combustibles and / or pyrolytic oil obtained in different areas to obtain mixed gas, dedusting the mixed gas, and converting the dedusted mixed gas by using water vapor to obtain a hydrogen crude product; purifying the hydrogen crude product to obtain a hydrogen product; packaging, storing or conveying the hydrogen product; the method solves the problem that large-scale industrial treatment and economic benefit improvement are difficult to realize due to the fact that the organic solid waste in a distributed area or a remote area has the characteristics of multiple types, small quantity, dispersive distribution, high transportation, recovery and treatment cost and the like.

The present invention relates to multi-layered pyrolysis reactor for the heat treatment of a rubber granulate. The multi-layered pyrolysis reactor has a pyrolysis zone and a gasification.

The invention provides phosphorus-doped hydrothermal synchronously-activated hierarchical pore green biochar, a preparation method thereof and application of the phosphorus-doped hydrothermal synchronously-activated hierarchical pore green biochar in formaldehyde adsorption, and belongs to the technical field of biomass resource high-value utilization and air pollution control. The preparation method comprises the following steps: mixing a biomass raw material with a phosphoric acid catalyst, carrying out hydrothermal carbonization reaction, carrying out solid-liquid separation on a reaction product after the reaction is finished, collecting a solid-phase material, drying, mixing with potassium hydroxide, activating, washing and drying the obtained product, and thus obtaining the phosphorus-doped hydrothermal synchronously-activated hierarchical porous green charcoal. Phosphoric acid is introduced in the hydrothermal stage to serve as a structure-directing agent and a doping source, uniform doping of phosphorus and coordinated regulation and control of a pore structure are achieved, a hierarchical pore channel system is formed in the subsequent activation process, and the physical adsorption and chemical fixation capacity of the biochar to formaldehyde molecules is greatly improved.

The invention discloses a device and method for preparing biochar from corncobs, and belongs to the technical field of biochar preparation, the device comprises a machine base, a frame is fixed outside the machine base, an outer cylinder is horizontally fixed on one side of the machine base, and the outer cylinder is fixedly connected with the frame; the crushing seat is arranged above the outer cylinder; the combustion system is arranged on one side of the outer barrel, and the combustion system is externally connected with a hot gas booster fan; the sealing end cover is fixed in the outer cylinder body; the carbonization cylinder is rotationally mounted on the machine base, and one end of the carbonization cylinder is coaxially and rotationally connected with the sealing end cover; the heat control unit is arranged in the annular cavity of the carbonization cylinder; the material guide channel is arranged on the sealing end cover; the filter material unit is fixed in the carbonization cylinder; according to the device, a scrap mixture can be graded according to the particle size, primary carbonization of the scrap mixture is achieved, then the scrap mixture is remixed and then subjected to high-temperature pyrolysis carbonization, and the purity and quality of biochar preparation are improved.