4373results about "Special form destructive distillation" patented technology

A process for producing a blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from a first renewable feedstock comprising at least one component selected from the group consisting of glycerides, free fatty acids, biomass, lignocellulose, free sugars, and combinations thereof. The cyclic rich component is generated from a second renewable feedstock comprising at least one component selected from the group consisting of glycerides, free fatty acids, free fatty alkyl esters, biomass, lignocellulose, free sugars, and combinations thereof. The blended fuel may a gasoline boiling point range blended fuel, a diesel boiling point range blended fuel, an aviation boiling point range blended fuel, any combination thereof, or any mixture thereof.

A coal compaction system and method for a non-recovery coke oven having refractory roof, floor, side walls and end doors for coal charging and coke discharge provides an improved coal charging machine carrying a coal conveyor supported intermediate the ends of the conveyor to avoid conveyor sagging and non-uniform depth of a deposited coal bed, a number of pressurized fluid-driven vibratory compactors mounted on an end of the charging machine and spaced-apart across the width of the coal bed and serving to compact the coal bed on a retraction stroke of the charging machine, a pivoted lifting frame mounted on the charging machine above the compactors and from which the compactors individually are suspended and are provided with individual supply of pressurized fluid, and a coke pusher head mounted on the charging machine behind the compactors and serving, when the lifting frame and associated compactors are raised, to push finished coke from the coke oven.

The invention provides an industrial treatment method for oil field waste. The industrial treatment method for oil field waste comprises the following steps: carrying out sampling analysis on the oil field waste, preheating to 80-300 DEG C by using high-temperature steam or conduction oil, then carrying out microwave pyrolysis treatment, controlling pressure at minus 5000 to minus 100 Pa, thus obtaining solid treatment substances and gas, condensing, separating and purifying the gas, and finally recycling so as to obtain water, oil and non-condensable gas. An industrial treatment device for oil field waste comprises a feed hopper, a dryer, a microwave heating cavity, a microwave generator, a heating device and a condensation separation purification device, wherein the feed hopper is connected to the dryer which is connected to the microwave heating cavity, a steam or conduction oil outlet of the heating device is connected to a steam or conduction oil outlet of the dryer; gas outlets of the dryer and the microwave heating cavity are connected to the condensation separation purification device; the microwave generator is connected to the microwave heating cavity. The industrial treatment method and the industrial treatment device have good treatment effects, high utilization rate of energy sources and good economical efficiency.

Methods for fractional catalytic pyrolysis which allow for conversion of biomass into a slate of desired products without the need for post-pyrolysis separation are described. The methods involve use of a fluid catalytic bed which is maintained at a suitable pyrolysis temperature. Biomass is added to the catalytic bed, preferably while entrained in a non-reactive gas such as nitrogen, causing the biomass to become pyrolyzed and forming the desired products in vapor and gas forms, allowing the desired products to be easily separated.

Methods, process, apparatus, equipment, and systems are disclosed for converting biomass into bio-oil fractions for chemicals, materials, feedstocks and fuels using a low-cost, integrated fast pyrolysis system. The system improves upon prior art by creating stable, bio-oil fractions which have unique properties that make them individually superior to conventional bio-oil. The invention enables water and low-molecular weight compounds to be separated into a final value-added fraction suitable for upgrading or extracting into value-added chemicals, fuels and water. Initial bio-oil fractions from the process are chemically distinct, have low-water content and acidity which reduces processing costs normally associated with conventional bio-oil post-production upgrading since fewer separation steps, milder processing conditions and lower auxiliary inputs are required. Biochar is stabilized so that it can be handled safely. The integrated fast pyrolysis process includes biomass storage, preparation, pretreatment, and conversion, product recovery and processing to create and store stable biochar and bio-oil fractions.

The embodiment of the invention discloses a method and a system for processing oil field wastes. The method for processing the oil field wastes comprises the following steps: conveying initial materials to a heating cavity, and heating the heating cavity by using high-temperature flue gas, so as to obtain mixed steam and solid residues; carrying out condensation and separation on the mixed steam, so as to obtain oil, water and a noncondensable gas, wherein the oil and the noncondensable gas are used for combusting to obtain the high-temperature flue gas, and the solid residues are discharged out of the heating cavity. According to the method, the heating cavity is indirectly heated by using the high-temperature flue gas, so that the initial materials inside the heating cavity are subjected to thermal decomposition, solid residues free of oil, the noncondensable gas and oil are obtained from the mixed steam generated by thermal decomposition after a series of treatments, and then the noncondensable gas and oil are used for combusting to generate the high-temperature flue gas. Compared with the prior art, the method disclosed by the invention has the advantages that decomposition is carried out without adding a cracking agent, and thermal decomposition can be directly carried out on the oil field wastes in different regions, therefore, the method and the system are better in universality.

The present invention provides methods for the thermolysis of lignocellulosic materials, such as wood, cellulose, lignin, and lignocellulose. In specific embodiments, the methods comprise combining the lignocellulosic material with an ionic liquid and subjecting the mixture of the lignocellulosic material and the ionic media to pyrolytic conditions to form a recoverable product, such as a commodity chemical.

In at least one embodiment of the present invention, a method for producing liquid hydrocarbons from biomass is provided. The method comprises pyrolizing the biomass with hydrogen (H₂) to form bio-oil. The bio-oil comprises alkanes, alkenes, alcohols, aldehydes, ketones, aromatics, hydrocarbons or mixtures thereof. The H₂ is formed from a carbon-free energy source.

This invention relates to systems and methods for converting biomass into highly inert carbon. Specifically, some embodiments densify the carbon into anthracite-style carbon aggregations and store it in geologically stable underground deposits. The use of certain embodiments yield a net effect of removing atmospheric carbon via the process of photosynthesis and converting it into hard coal, which can be stored in underground beds that mimic existing coal deposits which are known to be stable for thousands of years.

The invention discloses a continuous biomass low-temperature pyrolytic charring method and a charring furnace thereof, belonging to the fields of biomass charring and biomass energy source utilization. The furnace body of the charring furnace adopts a screw propelling feed mode, and the power is derived from the drive of a motor; an external heating cylinder is sheathed outside an internal heating cylinder of the furnace body, the internal cylinder and the external cylinder are spaced, and the internal flue inside the sleeve has a labyrinth path to ensure heat supply from hot flue gas to pyrolytic reaction to uniformly heat a biomass raw material; and during charring, the generated flue gas supplies heat to a reaction cylinder after combustion in a combustion chamber, and the hot flue gas enters a heat exchanger device to dry the raw material after flowing through the sleeve. Through screw propelling, the method disclosed by the invention realizes continuous low-temperature pyrolytic charring reaction, and realizes accuracy control of the retention time of the biomass inside the charring furnace; and the furnace body adopts a sleeve structure, which fully utilizes the afterheat of the charring flue gas, and the reaction cylinder adopts interior heating and outer wall heating together, which enhances the uniformity characteristic of the temperature inside the reaction cylinder and prolongs the service life of an auger shaft.

Disclosed is a scaleable pyrolysis system for batch processing of waste vehicle tires and other waste to provide pyrolysis products. The core pyrolysis system includes one or more batch reactors, heating units, solids processing units, gas/liquid processing units and control units. In operation, the temperature gradients internal to the reactor are controlled by preferential channeling of heat to provide pyrolysis products that are of high quality, and hence commercially advantageous, while facilitating high throughput.

The invention described herein generally pertains to utilization of high power density microwave energy to reduce organic compounds to carbon and their constituents, primarily in a gaseous state. The process includes, but is not limited to, scrap tires, plastics, asphalt roofing shingles, computer waste, medical waste, municipal solid waste, construction waste, shale oil, and PCB/PAH/HCB-laden materials. The process includes the steps of feeding organic material into a microwave applicator and exposing the material to microwave energy fed from at least two linear polarized sources in non-parallel alignment to each other, and collecting the material. The at least two sources of microwave energy are from a bifurcated waveguide assembly, whose outputs are perpendicular to each other and fed through waveguide of proper impedance, such that the microwave sources are physically and electrically 90° out of phase to each other. The microwave frequency is between 894 and 1000 MHz, preferably approximately 915 MHz.

A process for the pyrolysis of carbonaceous material is carried out in a cyclone reactor which is fitted with enhanced filtering equipment. In addition the invention relates to the use of a cyclone fitted with a rotating filter as a pyrolysis reactor. By using a cyclone of the rotating separator type as a pyrolysis reactor, carbonaceous material, such as biomass, can effectively be converted in a product having excellent chemical properties and which product is free from particulate matter.

This invention is directed to a method of preparing a natural resin by liquefying wood, bark, forest residues, wood industry residues, or other biomass using rapid destructive distillation (fast pyrolysis). Fast pyrolysis produces both vapors and char from biomass, and following removal of the char from the product vapors, a liquid pitch product is recovered and processed by distillation, evaporation, or a combination thereof, in order to obtain a natural resin which may be in either liquid or solid form. The natural resin comprises a total phenolic content from about 30% to about 80% (w/w), and is a highly-reactive ligninic compound that has been found to be suitable for use within resin formulations without requiring any further extraction or fractionation procedures. Resins comprising up to 60% natural resin have been prepared and tested in board production and found to exhibit similar properties associated with commercially available resins. The natural resin may substitute for phenol, or for both phenol and formaldehyde within phenol-containing resins. Similarly, the natural resin can replace a substantial part of the components within urea-containing resins.

The invention relates to a biochar-containing composition comprising biochar having organic matter therein and/or thereon, clay associated, optionally intercalated, with the organic matter, a non-clay mineral and optionally also a plant growth promoter.

A system and method for biomass pyrolysis utilizing chemical looping combustion of a produced char to capture carbon dioxide is disclosed. The system includes a biomass pyrolysis reactor, a char combustor, and oxidation reactor and a separator for separating carbon dioxide from flue gas produced by the char combustion. The pyrolysis reactor pyrolyzes biomass in the presence of reduced metal oxide sorbents producing char and pyrolysis oil vapor. The char is separated and combusted in the char combustor, in the presence of oxidized metal oxide sorbents, into a gaseous stream of carbon dioxide and water vapor. The carbon dioxide and water are separated so that a stream of carbon dioxide may be captured. The oxidation reactor oxidizes, in the presence of air, a portion of reduced metal oxide sorbents into oxidized metal oxide sorbents that are looped back to the char combustor to provide oxygen for combustion. A second portion of the reduced metal oxide sorbents is recycled from the char combustor to the pyrolysis reactor to provide heat to drive the pyrolysis. Pyrolysis oil upgrading catalyst particles may be used in addition to the metal oxide sorbents as heat energy carrier particles to improve the quality of the pyrolysis oil vapors produced in the pyrolysis reactor. Also, the metal oxide sorbents may have metals incorporated therein which serve to upgrade the pyrolysis vapors produced during pyrolysis. Non-limiting examples of such metals include Ni, Mo, Co, Cr, W, Rh, Ir, Re, and Ru.

Apparatus for biomass torrefaction which includes a serpentine elongated housing, the housing having three generally U-shaped axial portions having first and second axial extremities and an intermediate section, the first and second axial extremities are disposed in normal use at a higher elevation than the first and second axial extremities, the intermediate section being configured for holding a liquid. Other forms of the invention include the method for biomass torrefaction which includes providing a quantity of biomass, providing a liquid heat transfer fluid, providing at least a first housing for holding the heat transfer liquid, elevating the temperature of the liquid heat transfer liquid, heat treating the biomass by passing it through the heat transfer liquid in the first housing at a temperature and duration sufficient to accomplish torrefaction of the wood. In some forms of the method, the process further includes the step of pelletizing the biomass prior to performing the treating step.

A process and plant for the thermocatalytic conversion of waste materials into reusable fuels and a fuel produced by the process, involving the steps of delivering melted waste material (11) to one or more pyrolysis chambers (26) via heated and valved manifolds (22) and effecting pyrolysis of the waste material into a gascous state in an oxygen purged and pressure controlled environment. Pyrolytic gases are, then transferred to a catalytic converter (29) where the molecular structure of the gaseous material is altered in structure and form, with gases then transferred to one or more condensers (30a) to distil and cool gases in to their respective fractions. After post pyrolysis treatment, fuel fractions thon form a useable fuel. Includes the melting of waste (plastic) material (11) before delivery into any of the pyrolysis chambers (26), making the movement of material into the catalytic tower (29) a semi-continuous operation, directing melted waste material into one or more, but preferably four, pyrolysis chambers (26a, b, c, d), making each chamber capable of independent operation, optionally mechanically removing waste char from the pyrolysis chamber (107) by use of an internet auger (112) or other suitable means.

The present invention provides a vertically oriented gasifier comprising vertically successive processing regions for conversion of carbonaceous feedstock into gas. The gasifier comprises of: one or more processing chambers with two or more vertically successive processing regions being distributed within said one or more processing chambers, within each one of which a respective process selected from the group consisting of drying, volatilization and carbon conversion is at least partially favoured, The processing regions are identified by temperature ranges respectively enabling each said respective process. One or more additive input elements are associated with the processing regions for inputting additives to promote each said at least partially favoured process therein. In addition, the gasifier comprises one or more material displacement control modules adapted to control a vertical movement of the feedstock through said processing regions to enhance each said at least partially favoured process, one or more feedstock inputs located near a first of said processing regions and one or more gas outputs and one or more residue outputs.

There is described a processor for use in the microwave torrefaction of biomass material which comprises, a micronised biomass char material and a method of producing a biomass char material, and a method of producing L-glucosan.

A method of recovering hydrocarbons from hydrocarbonaceous materials can include forming a constructed permeability control infrastructure. This constructed infrastructure defines a substantially encapsulated volume. A comminuted hydrocarbonaceous material can be introduced into the control infrastructure to form a permeable body of hydrocarbonaceous material. The permeable body can be heated sufficient to remove hydrocarbons therefrom. During heating the hydrocarbonaceous material is substantially stationary as the constructed infrastructure is a fixed structure. Removed hydrocarbons can be collected for further processing, use in the process, and/or use as recovered.

Described herein are methods and mechanisms for laterally dispensing fluid to a coke drum in a predictable and maintainable manner that alleviates thermal stress. In one embodiment, the methods and mechanisms utilize a split piping system to dispense fluid through two or more inlets into a spool that is connected to a coke drum and a coke drum bottom deheader valve. A combination of block valves and clean out ports provides a more effective means to clean the lines and allows fluid to be laterally dispensed in a controllable and predictable manner. The fluid is preferably introduced to the spool in opposing directions toward a central vertical axis of the spool at equal but opposing angles ranging from minus thirty (−30) to thirty (30) degrees relative to a horizontal line laterally bisecting the spool. Alternatively, however, fluid can be introduced to the spool tangentially.

An apparatus of produced water treatment, to be adopted in an in-situ recovery method of producing bitumen from oil sand, the apparatus capable of removing the oil from produced water, the produced water of being left by separating the bitumen from bitumen-mixed fluid having been recovered from the oil sand, the apparatus having: a vessel for receiving the produced water; a submerge type filtration membrane module, installed in the vessel, for filtering the produced water in the condition of the membrane being submerged in the produced water; and a bubble generator for generating bubbles to be forwarded toward the submerged filtration membrane in the produced water.

Embodiments presented herein describe an apparatus and method to convert carbonaceous materials, particularly biomass and those biomass resources which are remotely located, into a high performance solid fuel. This method, and the apparatus described as the means to accomplish this method, provides a continuous process which can be completely powered by the energy contained in the biomass. The heat, mechanical power and electrical power are provided from the energy in the biomass, through the methods described. In this way, the apparatus is free to operate in remote locations, where no power or auxiliary fuel sources are available.

The present invention provides an autothermal torrefaction device, which can be either stationary of mobile. Embodiments of the present invention include a torrefaction chamber having a chamber inlet for receiving biomass and at least one chamber outlet. The torrefaction chamber can be substantially surrounded by an exterior housing defining an outer jacket and having a jacket inlet and a jacket outlet. The outer jacket and torrefaction chamber define a space therebetween such that a burner unit including an inlet operatively connected to the chamber outlet and an outlet operatively connected to the jacket inlet allows vapors produced or released from within the torrefaction chamber to travel into the burner unit for combustion of at least a portion of the vapors and subsequently travel through the space between the jacket and the torrefaction chamber to provide heat necessary for autothermal torrefaction of biomass.

A method of forming a pyrolysed biocarbon from a pyrolyzable organic material is delineated. The method involves the conversion of pyrolyzable organic materials to biocarbon for subsequent use. A carbonization circuit is employed with individual feedstock segments being advanced through the circuit. The method facilitates user manipulation of rate of advancement of the feedstock through the circuit, selective collation of volatiles from pyrolyzing feedstock, selective exposure of predetermined feedstock segments to collated volatiles as well as thermal recovery and redistribution as desired by the user. This results in the capacity for a customizable biocarbon product, the latter being an auxiliary feature of the methodology.

The present invention is to provide a method for carbonification of crop straws and a device thereof. Pyrolysis process is controlled by regulating the feeding of oxygen during said pyrolysis process, and pyrolysis and carbonification are respectively conducted in separate pyrolysis and carbonification pools, wherein the straws are pyrolyzed in said pyrolysis pool and entered into said carbonification pool to be carbonified. The present invention can quickly raise the temperature of the pyrolysis process, shorten the time of the pyrolysis process, and improve the pyrolysis carbonification efficiency.

Production of biomass hydrogen-enriching fuel gas is carried out by thermal cracking for biomass raw materials at 550-650 deg. C under isolated air, converting it into gas-phase product and residual carbon, separating residual carbon from gas-phase product, transferring out of reacting system, burning to obtain heat energy, cracking at 800-950 deg. C and reforming into hydrogen, methane and other light hydrocarbons. It combines bitter spar catalyst and steam; it can eliminate tar, decrease methane content and increase hydrogen content. Hydrogen content reaches to 30%-55 wt%.

The invention discloses a process for integrally heated continuous preparing biomass pyrolysis gasification gas and a rotary furnace utilized by the same. At a furnace tail cooling section, red charcoal at a temperature of 600-800 DEG C after pyrolyzing and destructive distilling reacts with steam generated by cooling spray water on the lower portion in the furnace so as to absorb large quantities of heat and simultaneously generate water gas and semi-water gas. Heat generated by burning recycled gas and air is used for maintaining pyrolysis temperature of biomass material layers and providesenough heat for further, pyrolysis, destructive distillation and steam decomposition reaction. By aid of the heat, biomass inside the furnace is pyrolyzed and destructively distilled to generate large quantities of volatile matters, and the biomass is gradually heated to decompose destructive gas with high heat value. The rotary furnace utilizes a three-section design: a first section is a furnace head preheating section, which is mainly used for preheating and drying raw materials, a second section is a rotary furnace body pyrolysis section, which is mainly used for pyrolysis and destructivedistillation and is a core operation portion of the furnace, and a third section is a furnace tail cooling section, which is mainly used for cooling charcoal. Prepared gas is high in heat value, and devices occupy small space.

The invention discloses a method for performing microwave pyrolysis on garbage. The method comprises the following steps of: 1) pretreating the garbage to obtain structured garbage which is suitable for microwave pyrolysis; 2) performing microwave pyrolysis on the garbage, namely introducing pyrolysis gas out of a pyrolysis gas outlet of a microwave pyrolysis device, continuously outputting pyrolysis solid products from a pyrolysis solid residue discharge port on the microwave pyrolysis device, sealing the rest parts of the microwave pyrolysis device except a garbage inlet, the pyrolysis solid residue discharge port and a pyrolysis gas outlet to prevent the pyrolysis gas from being leaked and preventing external air from entering the microwave pyrolysis device to ensure that the pyrolysis gas is used as protective gas for pyrolysis reaction; and 3) recovering pyrolysis products, namely treating according to the pyrolysis products. The method has the characteristics of rapidness and high efficiency, low energy consumption, low cost, high resource utilization rate, simplicity in operation, high garbage volume reduction rate, capacity of obviously reducing damage of garbage to environment and the like; and by the method, innocent treatment of the garbage can be realized really.