The present application relates to the field of functional materials, energy conversion and
environmental protection technology, and more particularly to a
biomass baking-gasification chemical chain
water circulation hydrogen production method, which is used for
biomass resource
cascade utilization and
hydrogen-rich
syngas production. In the baking stage, the catalyst is mixed with
biomass to absorb the
moisture therein and release and utilize the
moisture in the gasification process. The present application provides a new type of
metal-support catalyst, the
metal active phase of which mainly includes Ce-Mn, Ce-Zr, Mn-Zr and other bimetallic and multimetallic materials, and the support is CaO. The catalyst includes a CaO support and active
metal particles dispersed on the support, the active metal particles are dispersed on the surface of the CaO support by embedding, the
doping of the metal is conducive to the formation of
oxygen vacancies, increases the
electron cloud density, reduces the
valence electron energy level, and makes the catalyst have excellent
hydrogen production performance and stability in the cyclic adsorption of H2O and CO2. The abundant
oxygen vacancies provide active sites for the adsorption and dissociation of H2O in biomass, and promote the
hydrogen production from
biomass gasification.