594 results about "Mesophase" patented technology

The invention discloses a preparation method of mesophase carbon microspheres from coal liquefaction residues serving as raw materials, which comprises the following steps of: firstly carrying out solvent extraction on the coal liquefaction residues, then carrying out a series of processing to obtain refined asphalt with different contents of quinoline insoluble substances, and carrying out thermal polycondensation reaction on the refined asphalt in the presence of a chemical auxiliary agent and a nucleating accelerator at the temperature of 380-450 DEG C, the pressure of 0-5 MPa and the stirring rotation speed of 40-500 r/min for 1-20 hours to obtain the mesophase microspheres. According to the invention, the chemical auxiliary agent and the nucleating accelerator can be added during theheat treatment process to improve the yield and narrow the particle size distribution of the mesophase carbon microbeads, and the mesophase carbon microspheres are prepared from the coal liquefactionresidues serving as the raw materials and have the advantages of low cost, simple preparation process, high yield (up to 35%), narrow particle size distribution, good sphericity, etc.

The invention relates to a high-energy silicon-carbon composite negative electrode material for a lithium ion battery and a manufacturing process thereof. The negative electrode material takes silicon powder or a mixture of the silicon powder and graphite powder as a core material, takes pyrolytic carbon as a shell material, and uses the shell material to coat the core material. The process for manufacturing the negative electrode material provided by the invention is characterized by performing nanoscale processing on mesophase pitch, ensuring that the nanoscale mesophase pitch is in a semi-liquid state, spraying the semi-liquid nanoscale mesophase pitch to the surface of a substrate of the silicon powder or the surface of a substrate of the mixture of the silicon powder and the graphite powder through a nanometer spraying device to realize the uniform coating, and finally obtaining a negative electrode material for a secondary battery through conventional drying, carbonization and graphitization processes (a high-strength magnetic field is applied during the carbonization and the graphitization). The specific capacity of high-energy silicon-carbon battery powder manufactured by the process can reach more than 1,050mAh/g, and over 80 percent of capacity can still be maintained after the circulation for 500 times.

The invention provides a high-rate charge-discharge lithium-ion battery and a preparation method thereof. The anode active material of the lithium-ion battery is lithium manganate; the cathode active material is selected from one or more of mesocarbon microbeads, artificial graphite or natural graphite coated by mesophase pitch; a conductive agent is selected from one or more of conductive graphite, conductive carbon black, nano Ag, nano SiO2 or nano Al2O3. The preparation method of the lithium-ion battery comprises the preparation of the anode plate, the parathion of the cathode plate and the assembly of the battery. The lithium-ion battery has the advantages of high-rate charge-discharge performance, long cycle life, high capacity, safe use, environmental protection, low cost and the like. The preparation method has the advantage of simple and easy process operation, and is applicable to the mass production.

The invention relates to an extraction method of direct coal liquefaction residues and application of extracts. The extraction method comprises the following steps: a) adding coal liquefaction residue powder and a first extraction solvent to a stirred tank to undergo primary extraction; b) carrying out solid-liquid separation on the extracted mixture obtained in the step a) and recovering the first extraction solvent from the obtained liquid in a solvent recovery unit and recycling the first extraction solvent; c) obtaining extracts after recovering the first solvent and mixing the extracts with a second extraction solvent to undergo secondary extraction; d) carrying out solid-liquid separation on the extracted mixture obtained in the step c), obtaining heavy liquefied oil after recovering the second extraction solvent from the obtained liquid in the solvent recovery unit and then carrying out moderate hydrogenation on the heavy liquefied oil and other recycled solvents in a coal liquefaction solvent hydrogenation unit and using the product as the recycled solvent in the coal liquefaction process; and e) carrying out heat treatment on the asphaltic substances obtained in the step d) by heating and carbonizing to obtain mesophase asphalt and oils.

The invention belongs to the technical field of a preparation method of spinning raw materials of high-performance pitch-based carbon fibers, and particularly relates to a preparation method of soluble mesophase pitch, which mainly solves the problems of the existing mesophase pitch preparation method that the process is complicated, requirements on the equipment are high, the cost is high, the industrialization process is difficult and the like. The invention adopts the technical scheme that the preparation method of the soluble mesophase pitch comprises the following steps of (1) thermally treating raw material pitch or ethylene bottom oil with a low softening point in an inert atmosphere, then distilling the material in a short distance or flashing the material, removing light ends, and collecting heavy fraction, i.e. heavy end pitch; (2) preparing the heavy enbd pitch into mesophase pitch; and (3) cooling the mesophase pitch to 320DEG C to 400DEG C, removing internal light ends, and collecting the heavy fraction, i.e. the mesophase pitch. The preparation method has the advantages of simplicity in process, moderate in reaction condition, low equipment requirement, low cost and adaptability to industrialized production.

A block copolymer, preferably a block copolymer such as poly(isoprene-block-ethylene oxide), PI-b-PEO, is used as a structure directing agent for a polymer derived ceramic (PDC) precursor, preferably a silazane, most preferably a silazane commercially known as Ceraset. The PDC precursor is preferably polymerized after mixing with the block copolymer to form a nanostructured composite material. Through further heating steps, the nanostructured composite material can be transformed into a nanostructured non-oxide ceramic material, preferably a high temperature SiCN or SiC material.

A self-assembly process for preparing luminescent organic-inorganic nanocomposite thin films is disclosed. A homogeneous solution in water and an organic solvent is obtained containing a soluble silicate, a silica coupling agent, a surfactant, and an organic material having a hole transport, electron transport, and/or emissive material moiety. The silica coupling agent is selected to chemically react with the organic material. A film of the homogeneous solution is deposited onto a substrate. Preferentially evaporating the organic solvent enriches the concentration of water and non-volatile solution components to promote micelle formation. Organic materials migrate into the hydrophobic portion of the forming micelles. Continued evaporation promotes self-assembly of the micelles into interfacially organized liquid crystalline mesophases. Reacting the organic material and silica coupling forms a nanostructure self-assembly. Luminescent ordered nanocomposite structures prepared by the process, and organic-inorganic HLED devices fabricated from the luminescent organic-inorganic nanocomposite structures are disclosed.

A method of preparing a mesoporous carbon includes mixing a mesophase pitch, a carbon precursor, an acid, and a solvent to obtain a carbon precursor mixture; impregnating an ordered mesoporous silica (OMS) with the carbon precursor mixture; heat-treating and carbonizing the impregnated OMS to form an OMS-carbon composite; and removing the OMS from the OMS-carbon composite. The mesoporous carbon uses the mesophase pitch and the carbon precursor to reduce sheet resistance, and thus can efficiently transfer electric energy. Such mesoporous carbon can be used as a conductive material of electrodes for fuel cells. When the mesoporous carbon is used as a support for catalysts of electrodes, a supported catalyst containing the support can be used to manufacture a fuel cell having high efficiency.

The invention discloses a method for preparing spherical active carbon employing water soluble bitumen. The method comprises the following processes: washing commercial sulfonated asphalt to obtain a complete water-soluble material; preparing a bituminous solution from the obtained water-soluble material or water-soluble mesophase pitch and deionized water; carrying out spray granulation on the bituminous solution, so as to obtain a bituminous ball; carbonizing and activating the bituminous ball, so as to obtain the spherical active carbon. The method has the advantages that the commercial sulfonated asphalt and the water-soluble mesophase pitch are adopted, so that the spherical active carbon is low in price and wide in source, no organic solvent is added in the balling process, the bituminous ball is controllable in particle size distribution, the prepared spherical active carbon is large in specific surface area, and industrial production is easy to achieve.

Provided are a solder bump, a method of manufacturing the same, and a method of bonding a light emitting device using the method of manufacturing the solder bump. In particular, the solder bump is formed of a compound including a first element through a third element, in which the first and third elements together form a compound having a plurality of intermediate phases and solidus lines.

The invention discloses a mesophase-pitch-based carbon fiber and a preparation method thereof. The preparation method comprises the steps of conducting mesophase pitch polymerization, modification and visbreaking, conducting centrifugal spinning, conducting hot jetting drafting, conducting oxidation, carbonization and graphitization, and obtaining the mesophase-pitch-based carbon fiber. The diameter of the mesophase-pitch-based carbon fiber ranges from 120 nm to 2000 nm, the draw ratio is 500-20000: 1, the tensile strength is 1.5-4.0 GPa, the tensile modulus is 300-600 GPa, the electrical resistivity is less than 0.2 * 10 <-4> omega.cm, the thermal conductivity is 500-800 W/m.k, and the mesophase-pitch-based carbon fiber is low in fabrication cost and can be applied to fields such as static electricity resistance, heat dissipation, electromagnetic shielding and heat shielding.

The method of the present invention provides a Method of preparing a spinnable mesophase and carbon fiber by using coal to directly liquefy residue-based asphalt vinyl material. According to the invention, the residue-based asphalt vinyl material which is subjected to direct coal liquefaction as a raw material, and the method comprises the following steps: grinding the asphalt vinyl material, and then placing in a high temperature tube type furnace or a high pressure reaction kettle under the inert gas protection, and preparing under the temperature of 200-500 DEG C and the pressure of 0.1-10 MPa to obtain the spinnable mesophase, performing processes of melt spinning, preoxidation and carbonization treatment on the mesophase to prepare the carbon fiber. The invention has the advantages of simple preparation method, conventional equipment, cheap raw material, good product quality and environmental protection, and is a method for high-value utilization of coal resource. The prepared carbon fiber can be used for high performance aerospace materials, adsorbents with high efficiency, separating agents, catalysts and catalyst carriers and the like.

Disclosed is a solid activated carbon and a process for manufacturing the solid activated carbon which is particularly suitable for electrode materials used in an electric double layer capacitor and various batteries. The use of the solid activated carbon makes it possible to prepare an activated carbon substrate having high mechanical strength and practical capacitance while the content of activated carbon is high. The solid activated carbon comprises an activated carbon powder and/or an activated carbon fiber, a carburized substance of a PVA or a resin derived from PVA, and a PVA or a resin derived from PVA. The process for manufacturing the solid activated carbon comprises, molding a molding material consisting of an activated carbon powder and/or an activated carbon fiber, a PVA or a resin derived from PVA or a mixture of a PVA or a resin derived from PVA and a mesophase using a known molding method, aging the molded compact in air and heat-treating the aged compact in a non-oxidizing atmosphere.

A process for producing mesophase pitch from high-temperature coal tar comprises: removing salts and quinoline insoluble fraction from a high-temperature coal tar to obtain a decant oil; using the decant oil as a hydrogenation feedstock, or pre-distilling the decant oil to obtain a residue with a boiling point higher than 230 and formulating the residue into a hydrogenation feedstock; catalytic hydrorefining the hydrogenation feedstock to obtain a hydrofined oil; distilling the hydrofined oil to obtain hydrogenated pitch; and subjecting the hydrogenated pitch to the thermal polymerization to obtain the mesophase pitch. The process has features such as an easily controllable degree of hydrogenation, complete removal of impurities, good raw material flowability, not tending to form the carbon deposition and the coking during the process, and not tending to jam the reactor. The product has a high content of mesophase pitch, a low softening point and a low impurity content.

The invention provides a method for preparing mesophase pitch through catalytic cracking oil slurry hydroisomerization and thermal condensation. The method comprises the steps that FCC oil slurry of naphthenic crude oil or intermediate base crude oil and distillate oil which is obtained at the temperature higher than 400 DEG C through vacuum distillation serve as the raw materials, on the condition that a hydroisomerization catalyst exists, the temperature ranges from 250 DEG C to 320 DEG C, the pressure is 5 MPa, reaction is conducted for 4-8 h, and the modified raw materials are obtained. Continuous reaction is conducted on the modified raw materials for 2-10 h at the temperature ranging from 330 DEG C to 460 DEG C and at the pressure of 12 MPa, and the mesophase pitch with the high quality is obtained. According to the method for preparing the mesophase pitch through catalytic cracking oil slurry hydroisomerization and thermal condensation, the preparation technology is simple, the production cost is low, the prepared mesophase content is high and greater than 97 percent, the softening point is low, the temperature ranges from 230 DEG C to 250 DGE C, the large-wide-area linear flow optical anisotropic structure is achieved, and the spinnability is good.

A process is disclosed for producing needle coke from heavy atmospheric distillation residues having sulfur no more than 0.7 wt %, which process involves the steps of heating the feedstock to a temperature in the range of 460 to 540° C. for thermal cracking in a soaking column under pressure in the range of 1 to 10 kg/cm² to separate the easily cokable material, separating the cracked products in a quench column and a distillation column and then subjecting the hydrocarbon fraction from the bottom of the quench column and a heavy gas oil fraction having 10% true boiling point more than 370° C. and 90% true boiling point not less than 480° C. from the distillation column and/or any other suitable heavier hydrocarbon streams in a definite ratio depending on certain characteristic parameters to thermal cracking in a second soaking column at a temperature of 440 to 520° C., pressure in the range of 2 to 20 kg/cm² in presence of added quantity of steam for formation of a mesophase carbonaceous structure which on steam stripping and cooling forms a solid crystalline coke suitable for manufacturing of graphite electrode of large diameter having co-efficient of thermal expansion lower than 1.1×10⁻⁶/° C. measured on graphite artifact in the temperature range of 25 to 525° C.

The invention provides a method for preparing a binder-free graphite product, which is characterized in that the graphite product is composed of crude petroleum coke and coal pitch mesophase pellet powder, and is characterized by comprising the following steps: drying, dewatering and smashing the crude petroleum coke; grinding the smashed crude petroleum coke to obtain crude petroleum coke powder by using a ball mill and an airflow pulverizer in sequence; heating the coal pitch mesophase pellet powder to carry out pre-oxidation treatment; cooling to room temperature; fully mixing by a blender; charging under vibration and preforming; placing blended power into a hydraulic cylinder, and obtaining isostatic pressing graphite green bodies through the steps of boosting pressure, maintaining pressure, reducing pressure and demoulding in an isostatic pressing forming process; placing the isostatic pressing graphite green bodies into an iron crucible; taking river sand and metallurgical coke powder as fillers in the roasting process, wherein the fillers are used for preventing the products from oxidization and deformation and fixing green body shapes; putting the iron crucible filled with the isostatic pressing graphite green bodies into a roasting furnace for roasting treatment to obtain isostatic pressing graphite roasting products after roasting; carrying out graphitization treatment on the isostatic pressing graphite roasting products by using a graphitized furnace to obtain the binder-free graphite products.

The invention discloses a preparation method of a carbon/carbon composite material with high heat conduction. The method comprises the following steps: a mesophase asphalt based carbon fiber which is treated by low temperature carbonization at 350-500 DEG C is prepared into an X-Y directional orthogonal paving layer whose thickness is 5-50mm by a winding method; a piece of PAN based carbon fiber carbon cloth is used for clamping the upper and lower surfaces of the asphalt based carbon fiber paving layer, bundles of the PAN based carbon fiber are used for carrying out puncture at a Z direction of the layer, and a three dimensional orthogonal fiber prefabricated body is obtained. High temperature carbonization and graphitization heat treatment are carried out, and a prefabricated body of the carbon/carbon composite material with high heat conduction is prepared. The carbon fiber prefabricated body is primarily densified to 1.30-1.60g/cm<3>, and the PAN based carbon fiber carbon cloth layers on the surface are removed; liquid phase infiltration pyrolysis is carried out, the material is densified to 1.70-2.10g/cm<3>, and finally the heat conductivity coefficient of the carbon/carbon composite material at X or Y direction is 200-350W/(m.K), and bending strength is 100-250MPa.

The invention relates to a mesophase pitch raw material as well as a preparation method and an application of the mesophase pitch raw material in preparing a high-performance carbon fiber. By virtue of measurement based on an elemental analysis method for the mesophase pitch raw material, the molar ratio H/C of hydrogen atoms to carbon atoms in the molecular structure of the mesophase pitch raw material is 0.55-1.0; the molar ratio of the naphthenic carbon content to the total carbon content in the molecular structure measured by virtue of a nuclear magnetic resonance method is greater than 9%; the softening point temperature, measured by an insertion method, of the mesophase pitch raw material is 200-240 DEG C; the content, measured by a polarizing microscope method, of the mesophase is 100%. The preparation method comprises the following step: polymerizing naphthalene-based compounds such as methylnaphthalene used as raw materials in the presence of a mixture of hydrogen fluoride and boron trifluoride as a catalyst by virtue of controlling the polymerization conditions. Compared with the prior art, the mesophase pitch raw material has the advantages of good spinning stability and high pre-oxidation activity, and is conductive to the control and operation of the carbon fiber spinning and pre-oxidation processes, the operation process is simple and the mesophase pitch raw material is conducive to preparing a high-performance pitch-based carbon fiber.