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348results about How to "Solve the small density" patented technology

Cathode active material powder for lithium secondary battery

It is to provide a cathode active material powder for a positive electrode for a lithium secondary battery, which has a large volume capacity density, high safety and excellent durability for charge and discharge cycles.
A cathode active material powder for a lithium secondary battery characterized by comprising a first composite oxide powder represented by the formula (1) LipQxMyOzFa (wherein Q is Co or Mn, M is aluminum or an alkaline earth metal element or a transition metal element other than Q, provided that when Q is Co, 0.9≦p≦1.1, 0.980≦x≦1.000, 0≦y≦0.02, 1.9≦z≦2.1, x+y=1, and 0≦a≦0.02, and when Q is Mn, 1≦p≦1.3, x=2−y, 0≦y≦0.05, z=4, and a=0), having an average particle size D50 of from 5 to 30 μm, and having a compression breaking strength of at least 40 MPa; and a second composite oxide powder represented by the formula (2) LipNixCoyMnzNqOrFa (wherein N is aluminum or an alkaline earth metal element or a transition metal element other than Ni, Co and Mn, 0.9≦p≦1.1, 0.2≦x≦0.8, 0≦y≦0.4, 0≦z≦0.5, 0≦q≦0.05, 1.9≦r≦2.1, x+y+z+q=1, and 0≦a≦0.02), having an average particle size D50 of from 2 to 30 μm, and having a compression breaking strength less than 40 MPa; in a ratio (weight ratio) of the first composite oxide powder/the second composite oxide powder being from 95/5 to 30/70.
Owner:SUMITOMO CHEM CO LTD

Lithium-containing composite oxide and its production method

The present invention provides a lithium-containing composite oxide for a positive electrode for a lithium secondary battery, which has a large volume capacity density and high safety, and excellent durability for charge and discharge cycles and charge and discharge rate property, and its production method.
The lithium-containing composite oxide is represented by the general formula LipNxMyOzFa (where N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, Sn, alkaline earth metal elements and transition metal elements other than Co, Mn and Ni, 0.9≦p≦1.2, 0.965≦x<2.00, 0<y≦0.035, 1.9≦z≦4.2, and 0≦a≦0.05), wherein when a powder of the lithium-containing composite oxide is classified into small particles with an average particle size of 2 μm≦Ds50≦8 μm and large particles with an average particle size of 10 μm≦Dl50≦25 μm, a content of the small particles is from 15 to 40% by weight and a content of the large particles is from 60 to 85% by weight, and 0.01≦ys≦0.06, 0≦yl≦0.02 and 0≦yl/ys<1, where (ys) is a ratio of the M element in the above general formula in the small particles and (yl) is a ratio of the M element in the general formula in the Large particles.
Owner:SUMITOMO CHEM CO LTD

Process for producing lithium-containing composite oxide

To provide a process for a lithium-containing composite oxide for a positive electrode for a lithium secondary battery, which has a large volume capacity density and high safety, and is excellent in the charge and discharge cyclic durability and low temperature characteristics.
A process for producing a lithium-containing composite oxide represented by the formula LipNxMyOzFa (wherein N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, alkaline earth metal elements and transition metal elements other than N, 0.9≦p≦1.2, 0.95≦x≦2.00, 0≦y≦0.05, 1.9≦z≦4.2 and 0≦a≦0.05), which comprises firing a mixture of a lithium source, an N element source, an M element source and if necessary, a fluorine source, characterized in that an aqueous solution having an M element source dissolved therein is mixed with an N element source powder or its pulverized product to form a slurry; if necessary after being pulverized, the slurry is dried for granulation to obtain a granulated product, which is mixed with a lithium source powder and if necessary, a fluorine source powder to obtain a mixture; and the mixture is fired at from 700 to 1,100° C. in an oxygen-containing atmosphere.
Owner:SUMITOMO CHEM CO LTD

Process for producing lithium-containing composite oxide for positive electrode of lithium secondary battery

A process for producing a lithium-containing composite oxide having a large volume capacity density, high safety, excellent durability for charge/discharge cycles, and further, excellent low temperature characteristics, which is suitable for mass production, is provided.
A process for producing a lithium-containing composite oxide represented by a general formula LipNxMyOzFa (wherein N is at least one type of element selected from the group consisting of Co, Mn and Ni, M is at least one type of element selected from the group consisting of Al, an alkali earth metal element and a transition metal element other than N, 0.9≦p≦1.2, 0.97≦x≦1.00, 0<y≦0.03, 1.9≦z≦2.2, x+y=1 and 0≦a≦0.02), the process comprising a step of firing a blended product containing a lithium source, an N element source, an M element source and, as the case requires, a fluorine source in an oxygen-containing atmosphere;
wherein as the N element source and the M element source, a product produced by impregnating a solution containing the M element source into a powder containing the N element source and drying them, is employed, and as the above firing, a first-stage firing at from 250 to 700° C. is applied and a second-stage firing at from 850 to 1,100° C. is subsequently applied to the fired product of the first-stage firing.
Owner:AGC SEIMI CHEM CO LTD
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