The invention discloses a halogenated phosphorosilicate glass
solid electrolyte and application, the raw materials comprise a halogenated
metal source and a
lithium salt, and the structural general formula is (Lia (AxDyOz)) bMXc, wherein M is Al, Zr, Ta, Hf, Nb, Ga, W or Mo; x is a
halogen anion; a is P, Si or B; d is H, Al or Na; axDyOz is an
oxygen-containing anion of P, Si or B; a, b, c, x, y and z are stoichiometric ratios, and a is greater than or equal to 1 and less than or equal to 4, 0.1 lt; blt; 1 < = c < = 4, 1 < = x < = 9, 0 < = y < = 2, and 2 < = z < = 18. According to the invention,
halogen anions are introduced to regulate and control a covalent
network structure, so that the
ion migration capability and the forming performance of the material are remarkably improved, meanwhile, the excellent stability and cost advantages of the material are maintained, and the halogenated phosphorosilicate glass
solid electrolyte with high
ionic conductivity, good forming performance and high stability is obtained.