A method of depositing a fluorinated
borophosphosilicate glass (FBPSG) on a
semiconductor device as either a final or interlayer
dielectric film. Gaps having aspect ratios greater than 6:1 are filled with a substantially void-free FBPSG film at a temperature of about 480 DEG C. at sub-atmospheric pressures of about 200
Torr. Preferably, gaseous reactants used in the method comprise TEOS, FTES, TEPO and TEB with an
ozone /
oxygen mixture.
Dopant concentrations of
boron and
phosphorus are sufficiently low such that surface
crystallite defects and hygroscopicity are avoided. The as-deposited films at lower
aspect ratio gaps are substantially void-free such that subsequent anneal of the film is not required. Films deposited into higher
aspect ratio gaps are annealed at or below about 750 DEG C., well within the thermal budget for most
DRAM, logic and merged logic-
DRAM chips. The
resultant FBPSG layer contains less than or equal to about 5.0 wt %
boron, less than about 4.0 wt %
phosphorus, and about 0.1 to 2.0 wt %
fluorine.