The invention belongs to the technical field of
solar cell manufacturing, and provides a step temperature cycle propulsion
boron diffusion process and application thereof. The
boron diffusion technology comprises the steps that a
silicon wafer is placed in
boron diffusion equipment, pre-oxidation, pre-deposition and stepped temperature circulation
boron diffusion propelling are sequentially carried out on the
silicon wafer, and the stepped temperature circulation
boron diffusion propelling procedure comprises an initial stage, a middle stage and a final stage which are sequentially carried out. A circulation mode of heating
oxygen-free boron expansion and pushing junction and then cooling
oxygen-filled boron expansion and pushing junction is adopted in each stage for multiple times of circulation, and the
heating temperature and the
cooling temperature of each stage are optimized, so that a boron expansion
doping layer is formed on the surface of the
silicon wafer. According to the
boron diffusion process, the oxidation temperature can be reduced, the concentric circle defect can be eliminated, the
junction depth and the surface
doping concentration of boron diffusion
doping can be increased, the uniformity of boron diffusion doping can be improved, the FF, Jsc, Uoc and Eta of the battery can be further improved, the thermal budget can be reduced, and the service life of equipment can be prolonged.