The invention relates to an aluminum-based
lead alloy /
cobalt-doped coated carbon
fiber powder-alpha-PbO2 composite positive grid and a preparation method thereof, and belongs to the technical field of battery grids. The aluminum-based
lead alloy /
cobalt-doped coated carbon
fiber powder-alpha-PbO2 composite positive plate grid sequentially comprises an aluminum
alloy matrix, a
zinc immersion
antimony layer, a nanometer La2O3-doped
nickel bottom layer, a Pb-Sn-Bi-
Ag alloy middle layer and a porous
cobalt-doped coated carbon
fiber powder-alpha-PbO2 composite
active layer from inside to outside. The catalytic activity of the
electrode plate is improved by utilizing
high conductivity and large bearing current intensity of aluminum, and the outer layer is doped with cobalt-coated carbon fiber powder-alpha-PbO2, so that the
corrosion resistance of the positive grid can be improved, and the service life of the positive grid can be prolonged. Compared with a traditional
lead alloy, the aluminum-based lead
alloy composite positive plate grid has the advantages that the weight is reduced by more than 50%, the tensile strength is improved by 34%, and the
conductivity is improved by more than 28%. Under the condition of 100%
depth of discharge (DOD), the cycle period of a lead storage battery using the aluminum-based lead
alloy anode grid is prolonged by 25%, and the long-term frequent
charge and discharge requirements of a lead-acid
energy storage battery can be met.