The application belongs to the field of industrial
wastewater, and particularly relates to a double-layer filler
calcium fluorophosphate
crystallization deep
fluorine removal
system and a method thereof. The mixing distribution area of the
fluidized bed system is provided with a water inlet
pipe, the water inlet
pipe is respectively provided with a first dosing
pipe and a second dosing pipe, and the dosing pipes are connected with the water inlet pipe through a pipeline mixer. The first dosing pipe adds phosphates and inorganic acid, and the second dosing pipe adds
calcium salt. Industrial
fluorine-containing
wastewater enters the mixing distribution area, the
reagent in the first dosing pipe makes the pH value of the
wastewater acidic, avoiding pipeline blockage; then the wastewater enters the pH adjusting area and contacts with the first layer of filler, the pH value of the wastewater changes to neutral to alkaline; then the wastewater enters the induced
crystallization area, the
fluorine ions in the wastewater generate
calcium fluorophosphate crystals with the phosphates and the calcium salt on the surface of the filler, realizing efficient fluorine removal. Through the principle of acidic pH in the mixing distribution area and neutral to alkaline pH in the induced
crystallization area, the application guarantees smooth water inlet and deep fluorine removal of the wastewater.