226 results about "Phosphate ion" patented technology

The invention relates to the technical field of bone tissue materials, and discloses a metal-doped biomimetic mineralized dECM cryogel and a preparation method and application thereof.The preparation method of the cryogel comprises the steps that firstly, hyaluronic acid and methacrylic anhydride are mixed in a solvent, the pH value is adjusted, a reaction is conducted, and methacrylic acid hyaluronic acid is obtained; then under the condition of a photoinitiator, mixing the methacrylic acid hyaluronic acid with an acellular extracellular matrix, and performing freezing and crosslinking treatment to obtain the cryogel, and finally, soaking the cryogel in a mineralization solution containing Ca < 2 + > and / or Mg < 2 + >, adding a buffer solution containing phosphite ions, incubating, and washing to obtain the crystal gel. The biomimetic mineralized dECM cryogel prepared by the method disclosed by the invention is good in ion release stability, can significantly improve the migration ability of HUVECs, contributes to promoting proliferation of rMSCs and improving the osteogenic differentiation potential of the rMSCs, and can be used for regeneration and repair of bone defects.

The invention belongs to the technical field of preparation of phosphorus removal agents, and particularly relates to a composite phosphorus removal agent and a preparation method and application thereof. The composite phosphorus removal agent comprises a honeycomb carrier and microspheres, the microspheres are loaded on the honeycomb carrier; the microspheres are prepared from the following raw materials: polyvinylidene fluoride particles, graphene oxide, ZrOCl2 and phosphorus-accumulating bacteria. The composite phosphorus removal agent comprises a honeycomb carrier, microspheres and microcapsules, wherein the microspheres and the microcapsules are loaded on the honeycomb carrier; capturing phosphate radicals in a water body by the microspheres and carrying out biological phosphorus removal and adsorption phosphorus removal; the honeycomb carrier also has the effect of adsorbing phosphate; and the two synergistically remove phosphate in the water body, so that the phosphorus removal effect of the phosphorus removal agent is improved, and the burden of the water body is not increased.

The invention belongs to the technical field of fluorescent sensing materials, and particularly relates to a ratio metering type fluorescent probe based on a metal organic framework (MOF) material as well as a preparation method and application of the ratio metering type fluorescent probe. The probe material emits blue light, after 2, 6-dipicolinic acid (DPA) is added, the DPA enhances fluorescence emission of Tb < 3 + > and inhibits emission of coumarin through an antenna effect, the fluorescence intensity ratio (I548 / I429) between two emission bands is changed, a good linear response relation is shown in the concentration range of 0-90.0 mu M, the detection limit is 0.13 mu M, and high-sensitivity ratio type detection of the DPA is achieved. After detection is finished, phosphate radical (PO4 < 3->) ions are added, so that the antenna effect can be effectively quenched, the initial fluorescence state is recovered, and meanwhile, the method can be used for detecting the concentration of phosphate radicals. After DPA is added again, reactivation can be realized, so that recycling can be realized, and the limitation of disposable use of a traditional fluorescent probe is broken through.

The present solution provides a preparation method for a three-dimensional structured ferrous phosphate pigment with corrosion early warning capability, including following steps: preparing a ferrous ion-containing solution for providing ferrous ions, where the ferrous ion-containing solution includes a soluble ferrous salt and a surfactant but no oxidizing ions, and the ferrous ion-containing solution is maintained in an acidic environment; preparing an initial mixed solution for providing phosphate ions and ammonium ions; and performing ultrasonic refinement, heating, and holding on the intermediate mixed solution using an auxiliary device with ultrasonic oscillation and microwave heating functions to obtain a final mixed solution; and filtering out precipitates from the final mixed solution, and then transferring the precipitates to a vacuum environment for high-temperature heating treatment to obtain a three-dimensional structured ferrous phosphate pigment with corrosion early warning capability.

The invention relates to the technical field of non-ferrous metal hydrometallurgy, in particular to a method for separating molybdenum and rhenium from molybdenum smelting waste acid by using resin, which comprises the following steps: adding a phosphorus source into the molybdenum smelting waste acid, and then adjusting the acidity to an acid environment in which the hydrogen ion concentration is greater than or equal to 1mol / L; molybdenum and rhenium in the molybdenum smelting waste acid with the acidity adjusted are separated through weak-base anion exchange resin, and a rhenium product with the lower molybdenum impurity content is obtained. According to the method, the phosphorus source is added into the molybdenum smelting waste acid, so that phosphate ions are hydrolyzed from the phosphorus source, molybdenum can be effectively prevented from being adsorbed by the alkalescent anion exchange resin, the selectivity of the anion exchange resin to rhenium is greatly improved, and the rhenium recovery rate and the molybdenum-rhenium separation effect are improved; the problems that in the prior art, ion exchange resin is difficult to adapt to molybdenum-rhenium separation under the high molybdenum concentration, the rhenium recovery rate is low, the rhenium-molybdenum separation effect is poor, and a high-molybdenum-concentration solution cannot be treated are solved.

The invention relates to a preparation method of iron phosphate, and discloses low-sulfur porous iron phosphate and a preparation method thereof. The preparation method of the low-sulfur porous iron phosphate comprises the following steps: providing a mixed solution which contains iron ions, phosphate ions and sulfuric acid; controlling the temperature of the mixed solution to be 60-80 DEG C, and preserving heat and aging for 10-20 hours to obtain slurry containing iron phosphate; extracting a solid from the slurry and washing for multiple times; the washed solid is subjected to microwave drying, the drying temperature is set to be 350-400 DEG C, and the frequency is set to be 2400-2500MHz. The preparation method is short in technological process and low in energy consumption, and the prepared iron phosphate is low in sulfur content, is of a porous structure, is applied to a battery, facilitates permeation of an electrolyte and intercalation and deintercalation of lithium ions, and can enable the battery to have high circularity.

The utility model relates to the technical field of organic wastewater treatment, and discloses a magnesium-carbon primary battery reaction tank which comprises a reaction tank, a water inlet pipe is arranged inside the left side of the reaction tank, a water outlet pipe is arranged inside the right side of the reaction tank, and a first slag discharge tank and a second slag discharge tank are arranged inside the upper side of the reaction tank. A negative plate magnesium plate and a positive plate carbon plate are arranged in the reaction tank, a sludge scraper is arranged in the reaction tank, and the bottom end of the water inlet pipe is fixedly connected with a sludge accumulation hopper. According to the utility model, magnesium ions react with ammonia nitrogen and phosphate in the wastewater to generate magnesium ammonium phosphate precipitates, so that multiple purposes are realized, the content of hydrogen ions in the wastewater is reduced, the acidity of the wastewater is relieved, the content of ammonia nitrogen and phosphate ions is directly reduced, and the production cost is reduced. The burden of nitrification, denitrification and biochemical phosphorus removal of a subsequent biochemical system is relieved, and meanwhile, the dosage of phosphorus removal in deep treatment is reduced.

The invention provides a method for preparing a MnCo2O4 catalyst from a phosphate radical modified precursor and application of the MnCo2O4 catalyst, uniform doping of phosphate radical ions in a MnCo2O4 crystal is realized through a synergistic effect of molecular modification and subsequent calcination of a phosphate radical functional group on a cobalt-manganese hydroxide precursor, so that the defects of surface modification are fundamentally overcome, and the application range of the MnCo2O4 catalyst is widened. The method has the advantages of simple preparation process, short reaction time, mild conditions, strong controllability and good repeatability, and is suitable for the fields of efficient water treatment and environmental restoration. Phosphate radical impregnation is carried out at the cobalt manganese hydroxide precursor stage, so that phosphate radicals enter an MnCo2O4 spinel bulk phase structure in the subsequent calcination process, stable bulk phase modification is realized, and the thermal stability and structural integrity of the material are remarkably improved; phosphate radicals have an adjusting effect on a metal cation coordination environment, valence optimization of Mn and Co can be induced in the calcination process, the proportion of Mn < 3 + > / Mn < 4 + > and balance of Co < 2 + > / Co < 3 + > are improved, and the material has more high-activity sites capable of participating in persulfate activation reaction.

The application discloses a vaccine and a preparation method thereof, and the preparation method comprises the following steps: mixing an acidic protein antigen solution containing a phosphate buffer solution with an aluminum adjuvant to make the molar ratio of phosphorus and aluminum below 0.9, so as to obtain an acidic protein vaccine; or mixing the aluminum adjuvant with a solution containing phosphate ions to make the molar ratio of phosphorus and aluminum above 0.2, and then mixing the aluminum adjuvant with an alkaline protein antigen solution containing a phosphate buffer solution, so as to obtain an alkaline protein vaccine; wherein the acidic protein antigen is any kind of protein antigen with a net negative charge; and the alkaline protein antigen is any kind of protein antigen with a net positive charge. According to the preparation method, the molar ratio of phosphorus and aluminum is adjusted to a specific range according to the net charge of the protein antigen, so that the isoelectric point of the aluminum adjuvant can be effectively changed, the charge carried by the aluminum adjuvant is opposite to the charge carried by the protein antigen, and then the aluminum adjuvant and the protein antigen are attracted to each other through electrostatic interaction. The vaccine antigen prepared by the method has high antigen adsorption rate and good stability, the preparation method is simple, and the method is suitable for industrial application.

The application discloses a PO4 3‑ and a preparation method of a flame-retardant epoxy acrylate coating layer of 8-OQ intercalated zinc-aluminum hydrotalcite, and the coating layer. Phosphate ions are intercalated between layers by using the ion-exchangeability between layers, and other intercalation agents are used to increase the intercalation rate of phosphate ions before the phosphate ions are embedded into the layers. 8-hydroxyquinoline as an intercalation agent can effectively expand the interlayer spacing of hydrotalcite, and provide more space for anion exchange. The Zn / Al-PO4 3‑ -LDHs intercalated with 8-hydroxyquinoline has the optimal flame-retardant and mechanical properties of the coating layer of the EA compound system. The hydrotalcite can make the carbon layer more uniform, more dense and more solid, and increase the carbon content of the coating layer, so as to improve the flame retardancy and thermal stability of the composite coating, and provide a new method for the research on the hydrotalcite modified EA fireproof coating.

The invention relates to a vertical flow biological induction dephosphorization system and a dephosphorization process. The system comprises a reactor body, an inner barrel and an outer barrel, wherein the inner barrel and the outer barrel form an inner reaction cavity and an outer reaction cavity; the flow guide device is communicated to the axial bottom end of the inner cylinder; the aeration device is arranged in the flow guide device and is used for aerating upwards; and the dephosphorization agent adding device is used for adding a dephosphorization agent while crushing particles below the flow guide device. By additionally arranging a dephosphorization agent adding device, large-particle-size anaerobic ammonia oxidation particles are crushed, a dephosphorization agent is added at the same time, an alkaline environment created by hydroxyl radicals generated by anaerobic ammonia oxidation reaction and microorganisms are used for synergistically promoting a dephosphorization path, a biological induced crystallization reaction is enhanced, and the dephosphorization effect is improved. According to the invention, calcium and magnesium ions are added into the phosphorus removal agent, the excessive calcium and magnesium ions and phosphate ions in the sewage are promoted to be subjected to a crystallization reaction, the free phosphate ions are converted into phosphorus-containing precipitates, the purposes of phosphorus removal and phosphorus resource recovery can be achieved, the dosage of alkaline agents in the phosphorus removal agent can be reduced, and considerable economic benefits are achieved.

The invention discloses a sustained and controlled release value-added fertilizer containing a bioactive carrier and a preparation method of the sustained and controlled release value-added fertilizer, and belongs to the technical field of sustained and controlled release fertilizers. The slow / controlled-release value-added fertilizer is prepared by compounding a bioactive carrier and an NPK compound fertilizer, wherein the bioactive carrier is prepared from three parts, namely a charcoal-layered double-metal hydroxide composite base material, interlayer intercalation phosphate radicals and surface-loaded humic acid. High-amount uniform loading of layered double hydroxides on the surface of biochar is achieved through a hydrothermal in-situ growth technology, phosphate radicals are stably embedded between layers in a subject-object composite mode, and a humic acid active component is combined to form a novel value-added fertilizer with multiple functions of nutrient slow release, soil improvement and growth stimulation. The fertilizer utilization rate is effectively improved, and the nutrient loss risk is reduced.

The application discloses a gold leaching method for pyrite-containing gold ore, and comprises the following steps: after the pyrite-containing gold ore is finely ground, water is added to obtain a slurry; a gold leaching reagent solution is added into the slurry to obtain a mixed leaching solution; the pH value of the mixed leaching solution is adjusted to alkaline, and leaching treatment is performed; and after filtration, a gold-containing leaching solution is obtained; the gold leaching reagent solution comprises polyphosphate, copper salt and thiosulfate; in the gold leaching reagent, polyphosphate is added; under alkaline conditions, polyphosphate ions can be selectively adsorbed or complexed on the surface active sites of pyrite to form a physical or chemical masking layer, thereby effectively blocking the direct contact of pyrite with dissolved oxygen and thiosulfate in the solution, inhibiting the catalytic decomposition of pyrite, significantly reducing the invalid consumption of thiosulfate, stabilizing the pH value and potential of the leaching system, and guaranteeing the efficient leaching of gold.

The invention relates to the technical field of hyaluronic acid solution detection, and particularly discloses a method for detecting a buffer solution in a sodium hyaluronate solution, and the method is reliable in content detection, low in detection difficulty and easy to operate. A cationic standard series solution is obtained; preparing a plurality of anion standard solutions with different concentrations and containing chloride ions and phosphate ions to obtain a series of anion standard solutions; pretreating the sodium hyaluronate solution to be detected to obtain a sample to be detected; carrying out ion chromatography detection on the cation standard series solution, the anion standard series solution and the sample through an anion and cation exchange chromatographic column by adopting an ion chromatography method, drawing a standard curve according to a chromatogram, and calculating a linear regression equation of the standard curve; and according to the chromatographic peak area of each ion in the sample and the corresponding linear regression equation, calculating the concentration of the corresponding ion and the content of the corresponding buffer solution.

The invention provides a phosphorus-fixing lanthanum-based nano composite material as well as a preparation method and application thereof, and relates to the field of novel nano composite materials. According to the material, lysozyme protein fibers are taken as a structural template, a confinement space is constructed by utilizing the ultrahigh length-diameter ratio of the lysozyme protein fibers, and controllable synthesis of the sub-5nm high-dispersion lanthanum oxide nanoparticles is realized. Functional groups in a protein chain can be enriched and nucleation sites can be provided through electrostatic attraction and key coordination synergistic effect, so that the lanthanum-based protein fiber nano composite material is formed. When the material is used for treating phosphorus wastewater, efficient phosphorus removal and long-term phosphorus fixation are realized through an enrichment-conversion synergistic mechanism: phosphate ions are enriched through electrostatic adsorption, and thermodynamically stable lanthanum phosphate is generated in situ at lanthanum active sites. According to the method, gt is still kept in the presence of high-concentration equal competitive ions; the phosphorus removal rate is 90%, the generated lanthanum phosphate can be used as a slow-release phosphate fertilizer or an industrial phosphorus chemical raw material, and closed-loop conversion from pollution purification to resource utilization is realized.

The invention discloses a magnetic limited phosphorus-doped photocatalyst as well as a preparation method and application thereof, and belongs to the field of functional materials for pretreatment of environmental chemical pollutants. The preparation method comprises the following steps: preparing magnetic Fe3O4.TiO2 by adopting a microwave method, and introducing a C18 modified carbon framework material and phosphate ions by taking the magnetic Fe3O4.TiO2 as a matrix to prepare the magnetic limited-access phosphorus-doped photocatalyst. The magnetic limited phosphorus-doped photocatalyst disclosed by the invention has the ultrahigh saturated adsorption capacity of a C18 modified carbon framework material, the instantaneous solid-liquid separation capacity and the efficient photocatalytic degradation capacity of nano titanium dioxide modified magnetic ferroferric oxide and the synergistic photocatalytic performance of phosphate; the problem that a traditional photocatalyst is poor in adsorption capacity is fundamentally solved, and the photocatalyst has more advantages in the aspects of adsorption removal and photocatalytic degradation of bisphenol organic pollutants in an environmental water sample.

The disclosure relates to a continuous process for obtaining phosphoric acid and calcium sulphate dihydrate from apatite, and sulphuric acid using hydrochloric acid as an intermediate attacking agent, comprising the steps: Leaching (101) apatite (11) with an aqueous solution of hydrochloric acid (12,13) to solubilize phosphorus compounds contained in the apatite, thereby obtaining a solution (15) containing phosphate (H3PO4) and calcium chloride (CaCl2); extracting (103) said solution (15) with organic solvent (16), yielding an organic extract (17) loaded with phosphate ions, and an aqueous raffinate (21) containing calcium chloride and residual impurities; re-extracting the phosphate ions from the organic extract (17) with water (18), thus yielding an aqueous extract (19) of phosphoric acid, and an unloaded organic phase substantially free of phosphoric acid, reacting (107) the raffinate (21) containing calcium chloride with sulphuric acid (26) to cause precipitation of calcium ions in the raffinate as calcium sulphate dihydrate and to recover chloride ions in the raffinate in the form of hydrochloric acid (12), wherein the reaction of the raffinate (21) containing calcium chloride with sulphuric acid (26) involves intermittent agitation of the raffinate, filtering off (108) precipitated calcium sulphate dihydrate (27) from the previous step (107) and washing it with water, recycling (112) the recovered hydrochloric acid (12) to the step (101) of the leaching apatite.

The application discloses an aluminum phosphate powder material with radiation refrigeration performance and a preparation method thereof. The method comprises the following steps: step 1, according to the molar ratio of aluminum ions, phosphate ions and ethylene glycol 2:(1-4):(10-20), aluminum hydroxide, ammonium phosphate and ethylene glycol are weighed, the aluminum hydroxide and the ammonium phosphate are mixed and then put into a mortar, the ethylene glycol is added into the mortar, and after being fully ground, the mixture A is obtained through filtration and washing; step 2, the mixture A is put into a crucible and placed in a muffle furnace, the temperature is first raised from room temperature to 200-280 DEG C at a temperature rising rate of 3-5 DEG C / min, and then raised to 1000-1200 DEG C at a temperature rising rate of 5-8 DEG C / min, and the temperature is kept for 2-4 h to obtain the product B; and step 3, the product B is ground in a mortar, sieved and the aluminum phosphate powder material is obtained. The aluminum phosphate powder material prepared by the method has excellent radiation refrigeration performance.

The invention belongs to the technical field of oral implant materials, and relates to a magnesium metal-guided bone regeneration membrane, a preparation method thereof and a product for preparing the magnesium metal-guided bone regeneration membrane. The magnesium metal-guided bone regeneration membrane comprises a bone repair combination product of the magnesium metal-guided bone regeneration membrane. The preparation method comprises the following steps: respectively providing an electrochemical deposition solution and a polysaccharide-containing solution; the electrochemical deposition liquid comprises a calcium ion donor, a phosphate ion donor and mussel mucin; the method comprises the following steps: placing a magnesium metal matrix in an electrochemical deposition solution, and carrying out first-stage electrochemical deposition under a first electrochemical deposition condition to prepare an intermediate 1; placing the intermediate 1 in an electrochemical deposition solution, performing second-stage electrochemical deposition under a second electrochemical deposition condition, cleaning, and drying to prepare an intermediate 2; placing the intermediate 2 in a solution containing polysaccharide, dip-coating the polysaccharide, and drying; the first electrochemical deposition condition and the second electrochemical deposition condition are respectively as follows: the voltage is 1-5V and 10-60V; the membrane has the biological functions of low corrosion rate, high bonding strength, inflammation resistance, bacteria resistance, osteogenesis promotion and the like.

The application provides a sewage treatment biochemical reaction tank, and relates to the technical field of sewage treatment, which comprises a biochemical tank, wherein the biochemical tank is communicated with a water distribution tank, a plurality of filter material oxidation units are arranged in the biochemical tank, adjacent filter material oxidation units are communicated, sewage enters from one end of the biochemical tank, sequentially passes through a plurality of adjacent filter material oxidation units, and finally enters a sedimentation tank, the filter material oxidation unit comprises a filter material bin and an oxidation tank, the filter material bin is filled with granular calcium carbonate dephosphorization filter material so as to remove phosphate ions in sewage, an aeration pipe is arranged below the oxidation tank, a plurality of aeration holes are formed in the aeration pipe, a curtain type filler is arranged above the aeration pipe, and the curtain type filler is attached with an aerobic microbial membrane; the filter material bin is arranged adjacent to the oxidation tank, and the oxidation tank is communicated with the filter material bin. The application has the advantages of high dephosphorization and denitrification efficiency and good sewage treatment effect.

An electrolyte for a lithium-ion cyclizing battery comprises a glycerol-based ionic liquid and an ammonium-based cyclic ionic liquid. The glycerol-based ionic liquid essentially comprises equimolar amounts of a cation component, consisting of a lithium (Li+)-glycerol complex, and an anion component, consisting of an arsenate ion, a phosphate ion, a sulfonylimide ion, a borate ion, and / or a chlorate ion. The ammonium-based cyclic ionic liquid comprises a cation component, consisting of a piperidinium ion and / or a pyrrolidinium ion, and an anion component, consisting of an arsenate ion, a phosphate ion, a sulfonylimide ion, a borate ion, and / or a chlorate ion. The electrolyte has a lithium concentration greater than or equal to 0.2 mol per liter and less than or equal to 1.6 mol per liter.The electrolyte can be used in batteries that cycle lithium ions and include silicon-containing electroactive materials of the negative electrode.

A method for synthesizing a material, comprising the steps of: providing a starting mixture containing lithium, a metal, a phosphate ion, and an additive which improves the transport of lithium ions into a material provided by this method compared to a material provided in the absence of these additives; heating this mixture in a reduction atmosphere to produce a material, wherein the material comprises a first phase which is LixMPO4, where M is the metal and x is less than or equal to 1.05, e.g.LiFePO4 in olivine structure, and includes a second phase, wherein the second phase has an ionic conductivity greater than the ionic conductivity of the first phase, wherein the additive replaces at least some of the phosphorus or the metal in the LixMPO4, where M is the metal and x is less than or equal to 1.05, wherein the first phase comprises 80-95 mol percent of the material and the second phase comprises 5-20 mol percent of the material, wherein the metal and the phosphate are provided as FePO4×2H2O in the starting mixture, wherein the process further comprises: introducing the carbon-containing compound polyvinyl alcohol (PVA) into the mixture prior to the reaction.

Provided is a method for removing impurities including aluminum from a metal-containing solution which is obtained from lithium battery waste and which contains aluminum ions, iron ions, cobalt ions, and / or nickel ions, said method comprising a dealumination step for removing aluminum by raising the pH of the metal-containing solution under the presence of phosphate ions and precipitating aluminum, wherein the iron ions in the metal-containing solution provided for the dealumination step include divalent iron ions.

The application provides a kind of anion and cation double-doped nickel cobalt manganese positive electrode precursor material and its preparation method and application.The nickel cobalt manganese positive electrode precursor material includes precursor matrix material and doping element doped in the precursor matrix material;The doping element includes phosphorus and lanthanum, and the phosphorus doping is phosphate doping.The nickel cobalt manganese positive electrode precursor material provided by the application realizes homogeneous doping of anion and cation through the synergistic doping of phosphate ions and lanthanum, effectively stabilizes lanthanum and phosphorus elements in nickel cobalt manganese, and improves the structural stability of the positive electrode material, thereby improving the electrochemical performance of the positive electrode material.

According to the preparation method, iron ions and phosphate ions are in a high-temperature and high-pressure environment, seed crystal generation and growth are controlled by presetting a specific crystal form, a large number of microcrystals are prevented from being instantly formed, the crystal size is controllable, the crystallinity is high, the consistency is good, and the conversion rate and the crystallization quality of the anhydrous iron phosphate are improved. Anhydrous iron phosphate is directly synthesized, sintering, dehydration and crystallization are not needed, washing water is greatly reduced, energy consumption and waste discharge are reduced, the influence of sintering on product quality fluctuation and poor consistency is avoided, and the production cost is reduced; the crystallinity and the particle size of the final iron phosphate crystal are adjusted by regulating and controlling the seed crystal type, the particle size and the dosage of the seed crystal, the dropwise adding speed and the stirring rotating speed of the iron source and the phosphorus source and the temperature and pressure during reaction, and on the premise that the high crystallinity and the stable and high iron-phosphorus ratio are kept, the specific surface area is adjustable within the range of 5-15 m < 2 > / g, the D50 is adjustable within the range of 0.8-12 microns, and the tap density is adjustable within the range of 0.6-1.55 g / cm < 3 >. And different application requirements are met.

[Problem] To provide a water electrolysis method and a water electrolysis system with which water electrolysis can be highly efficiently performed under non-extreme pH conditions. [Solution] Provided is a water electrolysis method in a buffer solution having a pH of 7 to 12, wherein the buffer solution is composed of an electrolyte solution containing at least one cation species selected from the group consisting of alkali metal cations and at least one anion species selected from the group consisting of borates and carbonates, and the electrolyte solution contains 0.1 to 6.0 mol / kg of phosphate ions.

This invention provides a method for efficiently recovering phosphorus using a Mg-Al layered double hydroxide. [Solution] According to one aspect of the present invention, a method for recovering phosphorus contained in wastewater is provided, comprising: a preparation step of preparing a Mg-Al layered double hydroxide having carbonate ions or hydroxide ions as interlayer anions; an exchange step of contacting the Mg-Al layered double hydroxide prepared in the preparation step with a gas containing hydrogen chloride to obtain a Mg-Al layered double hydroxide in which the interlayer anions have been replaced with chloride ions; and a recovery step of contacting the Mg-Al layered double hydroxide obtained in the exchange step with wastewater to replace the interlayer anions with phosphate ions contained in the wastewater and recover the phosphorus contained in the wastewater.

The present application relates to the technical field of biomedical materials, in particular to a composite gel containing core-shell structure calcium hydroxyapatite microspheres, a preparation method and application thereof. The composite gel comprises a gel carrier and microspheres dispersed in the gel carrier, the microspheres comprise a core and a shell layer coated on the outside of the core, the core is a biodegradable polymer, and the shell layer is calcium hydroxyapatite. After the core-shell structure calcium hydroxyapatite microsphere composite gel of the present application is implanted, calcium hydroxyapatite first contacts human tissues and is degraded into calcium ions and phosphate ions, stimulates collagen production and carries out tissue remodeling; then the biodegradable polymer is also metabolically degraded; and the degradation rate of calcium hydroxyapatite can control the exposure rate of the polymer microspheres, so that a long-term plumping filling effect is achieved; the gel has suitable viscoelasticity, can uniformly suspend the composite microspheres, and after injection into the human body, the microspheres are also uniformly dispersed in the gel.

A whitlockite preparation method includes: determining a size of the whitlockite crystal to be prepared; determining a first amount of a first cation other than calcium ion on the basis of the determined size of the crystal, wherein when the determined size of the whitlockite crystal is a first size, the first amount is determined to be a first value, wherein when the determined size is a second size larger than the first size, the first amount is determined to be a second value; mixing calcium ion and phosphate ion in order to prepare a first phosphate crystal, wherein the determined first amount of the cation other than calcium ion is also mixed therewith; mixing a second amount of cation other than calcium ion with phosphate ion to prepare a second phosphate crystal; and aging a solution containing the first phosphate crystal and the second phosphate crystal.