13 results about "Acetate ion" patented technology

This invention discloses a baseball-shaped photocatalytic material, its preparation method, and its application, belonging to the field of photocatalytic ammonia synthesis technology. The baseball-shaped photocatalytic material comprises rod-shaped FeMOF and spherical MnMOF. The baseball-shaped photocatalytic material uses rod-shaped FeMOF as a substrate, with spherical MnMOF grown on top of the rod-shaped FeMOF. The spherical MnMOF contains acetate ions. The preparation method involves dissolving an iron source and a manganese source in a solvent, adding an organic ligand, and ultrasonically treating the mixture, followed by a hydrothermal reaction. The manganese source is manganese acetate tetrahydrate. This invention's baseball-shaped photocatalytic material, through the uniform growth of spherical MnMOF on rod-shaped FeMOF, forms an electron-hole conversion channel, thereby enhancing the electron-hole transport rate, improving the photocatalytic performance of the bimetallic organic framework structure, and significantly increasing the yield of photocatalytic ammonia synthesis.

The invention discloses a trigonelline metformin salt and a preparation method thereof, and the preparation method comprises the following steps: providing a resin column filled with anion exchange resin, treating the resin column with a salt solution for ion replacement activation to obtain an activated resin column, anions of the salt are chloride ions, bromide ions, acetate ions, malate ions, lactate ions, tartrate ions or citrate ions; enabling the trigonelline metformin iodized salt solution to pass through an activated resin column, and selectively collecting the exchanged solution; and carrying out concentration treatment on the collected exchanged solution to obtain the trigonelline metformin salt. In combination with a specific embodiment, compared with a trigonelline metformin iodate, the solubility of the trigonelline metformin salt prepared by the preparation method of the trigonelline metformin salt provided by the invention in water is greatly improved, so that the application range of the trigonelline metformin salt is greatly expanded.

The invention provides a system and a method for co-producing single-cell protein through electrodialysis treatment of organic wastewater and hydrogen oxidizing bacteria fermentation, the system and the method are divided into an anode chamber, a middle chamber and a cathode chamber through a cation exchange membrane and an anion exchange membrane, and the anode chamber and the cathode chamber are filled with organic wastewater; and the middle chamber is filled with a hydrogen oxidizing bacteria fermentation culture medium. Under the driving of an electric field, ammonium ions and acetate ions in the wastewater are selectively migrated to the middle chamber through the anion and cation exchange membrane respectively, and are efficiently utilized by hydrogen oxidizing bacteria as a nitrogen source and a carbon source to produce single-cell protein. According to the system, collaborative integration of an electrodialysis technology and a microbial fermentation process is successfully realized, nutrient substances in the organic wastewater are recovered and converted into single-cell protein with high additional value while the organic wastewater is purified, the treatment burden is effectively converted into protein resources, and the system has environmental benefits, economical efficiency and sustainability.

The invention discloses a method for synthesizing high-purity super-crystal formamidine bromide (FABr), which is characterized in that the FABr is synthesized by means of anti-solvent addition and staged cooling, and the method comprises the following steps: (1) feeding for reaction; (2) extracting a crude product; (3) suction filtration and washing; (4) crystallizing and purifying; and (5) vacuum drying, through combination of a neutralization reaction and a recrystallization process, impurities such as metal ions and acetate ions can be effectively removed, the purity of a final product can reach 99.9% or above through verification, the method is short in process route and mild in reaction condition, the total yield can be stabilized to be 85% or above, the whole process is carried out at low temperature and in an inert atmosphere, thermal decomposition and oxidation of FABr are reduced, and the method is suitable for industrial production. The product has excellent thermal stability and storage stability, the FABr crystal obtained through temperature-controlled crystallization is uniform in size, easy to store and used for subsequent preparation of a perovskite precursor solution, used reagents are common, the cost is low, operation steps are simple, and industrial large-scale production is easy to achieve.

The invention discloses a curable additive containing a polymer monomer I and a perfluoroalkyl ionic liquid II, a high oxidation potential electrolyte containing the curable additive and a battery, the structural formula of the polymer monomer I is shown in the specification, wherein R1-R3 are selected from C1-C4 alkyl, alkoxy, halogenated alkyl or halogenated alkoxy, and the structural formula of the perfluoroalkyl ionic liquid II is shown in the specification. R4 is selected from alkylene groups or halogenated alkyl groups of C1-C6, and R5 is selected from alkyl groups or halogenated alkyl groups of C1-C2; the structural formula of the perfluoroalkyl ionic liquid II is shown in the specification, wherein X and Y are respectively and independently selected from one or more of imidazoles, pyridines, quaternary ammonium, quaternary phosphorus, pyrrolidines or piperidines, and R is selected from perfluoro-substituted C1-C10 alkylene; z <-> and Z < '-> are respectively and independently selected from one or more of halide ions, phosphate ions, perchlorate ions, sulfimide ions, oxalato borate ions, sulfonate ions and acetate ions. The invention constructs the high oxidation potential electrolyte and the battery with high safety and conductivity.

The invention provides an impurity removal method for ammonium chloride flash water, which comprises the following steps of: removing ammonia nitrogen from the ammonium chloride flash water: adjusting the pH value of the ammonium chloride flash water to be alkaline by using alkali, adding magnesium salt and phosphate to generate magnesium ammonium phosphate precipitate, stirring, crystallizing, standing, filtering and separating to obtain magnesium ammonium phosphate and filtrate for later use; and acetate ion removal of the ammonium chloride flash water: enabling the filtrate to pass through a resin column, and removing acetate to obtain the ammonium chloride flash water after impurity removal. In order to solve the problem that the ammonium chloride flash water is difficult to effectively treat, residual chloroacetate ions in the ammonium chloride flash water are removed by adopting methods such as activated carbon adsorption and ion exchange resin adsorption, and the ammonium chloride flash water is applied to an ammonium glyphosate aqueous solution, so that the treatment cost of the ammonium chloride flash water is greatly reduced; and a new thought is provided for the treatment of the ammonium chloride flash water.

The invention relates to the technical field of catalysis, and discloses a catalyst, a preparation method and application thereof, and a preparation method of dimethyl terephthalate. The catalyst comprises a polyester terephthalate carrier and an active component loaded on the polyester terephthalate carrier, the active component contains acetate ions and metal ions, and the metal ions are selected from at least one of IA group metal ions and IIB group metal ions. The catalyst can be conveniently and quickly separated from ester exchange and / or esterification products when applied to ester exchange and / or esterification reaction, is convenient to use for multiple times, and has relatively high catalytic activity; the product prepared by the catalyst has high purity and good hue.

This invention discloses an iodonium salt photoinitiator and its application in the preparation of treatment-free CTP thermal printing plates. The general formula of the iodonium salt photoinitiator is shown in Formula 1, wherein R1 is a substituted or unsubstituted alkyl or substituted or unsubstituted alkoxy group having 2-9 carbon atoms, and R2, R3, R4, and R5 are independently hydrogen atoms, alkyl groups, halogens, hydroxyl groups, carboxyl groups, amino groups, alkoxy groups, ester groups, nitro groups, and are tetraphenylboron ions, boron tetrafluoride ions, boron hexafluoride ions, phosphorus hexafluoride ions, arsenic hexafluoride ions, tellurium hexafluoride ions, halide ions, perchlorate ions, acetate ions, or trifluorosulfonate ions. The iodonium salt photoinitiator with the structure of this application can be used to prepare treatment-free CTP thermal printing plates, and can improve digital imaging speed and reduce crystals in the precursor of the formed negative lithographic printing plate. At the same time, the prepared treatment-free CTP thermal printing plate has excellent imaging speed and printing durability.

The present invention addresses the problem of providing: a polishing composition for polishing a gallium oxide substrate at a high polishing speed; and a polishing method therefor. [Solution] A polishing composition for a gallium oxide substrate, which contains silica particles, water, and multivalent anions, and wherein the content of the multivalent anions in the polishing composition is 0.002 mol / L or less. The multivalent anion is a multivalent anion including at least one type of multivalent anion selected from the group consisting of sulfate ions, oxalate ions, citrate ions, and phosphate ions. The polishing composition further contains a monovalent anion, and the content of the monovalent anion in the polishing composition is 0.04 mol / L or less. A polishing composition in which a monovalent anion is a monovalent anion including at least one type of monovalent anion selected from the group consisting of a nitrate ion, a chloride ion, a bromide ion, a chlorate ion, a bromide ion, an acetate ion, a formate ion, a propionate ion, and a butyrate ion. And the pH is from 5.0 to 9.5 (inclusive).

The invention relates to the field of energy storage devices, in particular to a multifunctional aqueous zinc-iodine battery and an electrolyte thereof, and the multifunctional aqueous zinc-iodine battery comprises zinc ions and an electrolyte additive, the zinc ion source is zinc salt, and anions of the zinc salt are one or more of sulfate ions, acetate ions, nitrate ions, trifluoromethanesulfonate ions, perchlorate ions and the like; during working, the zinc-iodine battery is subjected to an I- / I2 / I + reversible oxidation-reduction reaction on the positive electrode side, and is subjected to Zn / Zn < 2 + > reversible dissolution / deposition on the negative electrode side. When Zn / Zn < 2 + > reversible dissolution / deposition occurs in the zinc negative electrode, through interaction of the electrolyte additive and Zn < 2 + >, crystal face growth of Zn metal (002) is promoted, hydrogen evolution reaction is inhibited, uniform deposition of zinc in the negative electrode is finally induced, and the cycle life of the negative electrode is prolonged. On one side of the positive electrode, the electrolyte additive interacts with other functional groups through a halogenated group to form a negative potential accumulation region, so that stable existence of I < + > ions is realized.

The present application relates to the field of gas purification, discloses a kind of activated potassium base solution for removing carbon dioxide in oxygen-containing gas and application and carbon dioxide removal method.Activated potassium base solution for removing carbon dioxide in oxygen-containing gas includes potassium carbonate, amino acid activator, ionic liquid and water;Wherein, the anion in the ionic liquid is selected from at least one of acetate ion, lactate ion, amino acid salt ion.The activated potassium base solution described in the present application has high decarburization efficiency, is resistant to oxidative degradation, resistant to thermal degradation, has low toxicity, has little corrosivity to equipment, and is not prone to cause decarburization system blockage.

This invention discloses the application of lithium triacetate as a coating additive for cathode materials and its application in cathode materials. In this invention, lithium triacetate is used as a coating additive for cathode materials. On the one hand, triacetate ions can complex with metal ions on the surface of the cathode material, which is beneficial to the formation of the subsequent lithium-ion conductive layer. At the same time, it can also improve the stability of the coating layer and inhibit the peeling off of the coating layer. On the other hand, the use of lithium salt can prevent the direct use of triacetate from corroding the cathode material and damaging the material structure. It can also act as a lithium supplement agent to provide lithium ions to the cathode material, while avoiding the introduction of other metal ions and eliminating the adverse effects of other metal ions on the performance of the cathode material.

The invention discloses a high-voltage cross-linked perfluoroalkyl ionic liquid and application thereof in a battery. The high-voltage cross-linked perfluoroalkyl ionic liquid has a structure shown in a formula (1), wherein X and Y are independently selected from one or more of imidazoles, pyridines, quaternary ammonium, quaternary phosphorus, pyrrolidines or piperidines, and R is selected from perfluoro-substituted C1-C10 alkylene; z <-> and Z < '-> are respectively and independently selected from one or more of halide ions, phosphate ions, perchlorate ions, sulfimide ions, oxalato borate ions, sulfonate ions and acetate ions. The fluorine element is introduced into the ionic liquid structure through molecular design, so that the ion transmission, oxidation resistance and safety performance of the ionic liquid are improved, and the high-safety and high-energy-density solid-state battery is further prepared.