30results about "Silver organic compounds" patented technology

Provided are powder of a pure disilver hydrogen citrate-containing composition in powder form, having excellent solubility, and a method for easily obtaining the disilver hydrogen citrate-containing composition with high efficiency. In addition, provided are an antibacterial agent or antiviral agent, containing the disilver hydrogen citrate-containing composition, and a method for producing the same.The method for producing a disilver hydrogen citrate-containing composition of the present invention includes the following processes (1) to (3):(1) preparing a reaction mixture containing a silver compound and citric acid, the reaction mixture having a pH of 2.0 to 5.5;(2) precipitating the disilver hydrogen citrate-containing composition from the reaction mixture; and(3) collecting the precipitated disilver hydrogen citrate-containing composition.

The invention relates to organic electroluminescent materials and devices. The present disclosure provides carbene emitters of formula (I) wherein the ligand LigA has one or more electron withdrawing substituents; an organic light emitting device (OLED) comprising an anode, a cathode, and an organic layer disposed between the anode and the cathode, the organic layer comprising a compound of formula (I); and a consumer product comprising an OLED comprising a compound of formula (I): Formula (I).

A compound including a first ligand LA of Formula I,is provided. In Formula I, moiety A is a monocyclic ring or a polycyclic fused ring system; moiety B is a polycyclic fused ring system having at least three rings; each of Z1 to Z4 is C or N; K is a direct bond or a linking group; each R substituent is hydrogen or a General Substituent defined herein; at least one RA includes a non-aromatic polycyclic group; LA is coordinated to a metal M; Z1 forms a dative bond with M; and Z2 forms an anionic bond to K. Formulations, OLEDs, and consumer products containing the compound are also provided.

The present invention relates to Ag-based organic coordination nanoparticles, a method for producing the same, a photoresist composition and use thereof. m (R) n (Q) x ] y The production method involves placing a silver salt and a primary organic ligand in a sample bottle, dissolving them in an organic solvent, stirring for a certain period of time under specific temperature conditions, filtering, concentrating, crystallizing by cooling or evaporating, and finally recrystallizing in an organic solvent to obtain Ag-based organic coordination nanoparticles. This nanoparticle composition can be used as an electron beam, mid-UV, deep UV, and EUV photoresist.

An organometallic compound represented by Formula 1wherein, M1 to M4 are each independently a first-row transition metal, a second-row transition metal, or a third-row transition metal; X1 and X2 are each independently C(R5)(R6), Si(R5)(R6), N(R5), O, S, Se, or Te; W1 to W4 are each independently N(R7)(R8), P(R7)(R8), S(R7), a C5-C60 carbocyclic group unsubstituted or substituted with at least one R10a, or a C1-C60 heterocyclic group unsubstituted or substituted with at least one R10a; L1 to L6 are each independently a C1-C30 alkylene group unsubstituted or substituted with at least one R10a, a C5-C60 carbocyclic group unsubstituted or substituted with at least one R10a, or a C1-C60 heterocyclic group unsubstituted or substituted with at least one R10a, a3 to a6 are each independently an integer from 0 to 3, and R1 to R8 and R10a in Formula 1 are as described herein.

To provide an extractant for selectively extracting at least one of cuprous salt and silver salt.SOLUTION: The present invention provides a metal salt extractant for extracting at least one of cuprous salt and silver salt. The extractant is a compound represented by general formula (1). In the general formula (1), R1 and R2 each independently represent a hydrogen atom, an alkyl group, an aryl group, a heteroaryl group, an alkoxy group, a hydroxy group, or a group represented by -NHR', and R' represents a hydrogen atom, an alkyl group, an aryl group, a heteroaryl group, an alkoxy group, or a hydroxy group.SELECTED DRAWING: Figure 1

Provided are compounds of Formula (I) wherein P is a phosphorescent emitter, F is a fluorescent emitter, and L is a covalent linker. Also provided are formulations comprising these compounds. Further provided are OLEDs and related consumer products that utilize these compounds

The application discloses a thiacalix[4]arene-protected copper-silver nanocluster material for electro-reducing CO2 and a preparation method thereof, and belongs to the technical field of organic-inorganic hybrid catalysts. O h Symmetry, the molecular structure is composed of a truncated cubic inorganic silver core and a peripheral ligand, large ligands cover, i.e. passivate the larger face of the cubic core, small size ligands cover, i.e. passivate the smaller face of the cubic core, forming a double hydrophobic protective shell. The silver atoms on the truncated face are exposed, realizing the symmetrical construction of the cluster structure and the ordered exposure of the sites, and effectively ensuring the synthesis of the copper-silver nanocluster material with stability and activity. The faradic efficiency of the copper-silver nanocluster material for electro-catalytically reducing CO2 to CO reaches 97.76% under the condition of self-stability.

A kind of super-large mercaptan silver cluster material with silver triangle as core and its preparation method belong to the technical field of inorganic nanomaterials, the chemical formula of the silver cluster material is: C 114 Ag 104 S 34 O2, belongs to triclinic system, space group is P-1, cell parameter is α=108.5020 (10) °, β=119.4730 (10) °, γ=96.1580 (10) °, the silver cluster material has luminescent property.

A compound having a first ligand LA wherein the first ligand LA comprises a structure of Formula Iis provided. In Formula I, if R2 and R3 are not joined to form a ring, then at least two of R1 to R6 are not H. Also in Formula I, if R1 and R2 are not H, then R1 and R2 are also not bonded to the first ligand LA. Formulations, OLEDs and consumer products containing the compound are also provided.

The invention discloses a chiral metal halide optical waveguide material and a preparation method thereof, and relates to the technical field of optical waveguide materials, and the preparation method of the chiral metal halide optical waveguide material comprises the steps that chiral amine, metal halide, a reducing agent and acid are mixed and heated till solid is dissolved; and cooling and crystallizing to obtain the chiral metal halide optical waveguide material. The optical waveguide material with CPL emission and optical waveguide transmission functions is prepared, the material can efficiently generate circular polarization luminescence, and low-loss and directional optical waveguide transmission of CPL is achieved.

Disclosed herein are metal complexes that exhibit multiple radiative decay mechanisms, together with methods for the preparation and use thereof.

The present application belongs to the technical field of oil field chemistry, and particularly relates to a slow-release gel breaker, an intelligent controllable temperature-resistant temporary plugging agent and a preparation method thereof. The raw materials of the slow-release gel breaker include the following components in parts by weight: silver salt and a complexing agent, wherein the complexing agent is ammonia or 1,4-dicyanobenzene; the raw materials of the intelligent controllable temperature-resistant temporary plugging agent include the following components in parts by weight: the slow-release gel breaker, a thickening agent, an initiator and a crosslinking agent. The preparation method includes mixing and reacting the silver salt and the complexing agent to obtain the gel breaker, dissolving the thickening agent in water, adding the initiator, the crosslinking agent and the gel breaker, mixing and reacting to obtain the product. Compared with the existing temporary plugging agent technology, the present application has the advantages of low viscosity before injection, one-time injection into the formation, arbitrary control of gel breaking time, plugging rate greater than 90%, good plugging property, reduced cost and time of secondary injection of the gel breaker, and important significance for oil field measures such as profile control, water plugging and acidizing fracturing.

The present invention relates to poly(melamine-silicate) derivatives as biocidal disinfection and decontamination agents, and to methods for their production and use. More specifically, the invention relates to halogenated adducts of poly(melamine- silicate) with metal oxides.

The application discloses an organic semiconductor material based on a hexamer capto benzene silver organic metal sulfide and application thereof. The heterogeneous synthesis method of the hexamer capto benzene silver comprises the following steps: under the condition of heating, the hexamer capto benzene silver is reacted with silver chloride in an organic solvent under an inert atmosphere, and the reaction temperature is 45-65 DEG C, and the reaction time is 24-72 h. The hexamer capto benzene silver is prepared through a P-type organic semiconductor device, and the migration rate can be up to 50 cm 2 / (V.s)~200 cm 2 / (V.s). The raw material is cheap and easy to obtain, is low-toxicity and harmless, is an environment-friendly and sustainable development new method for preparing materials. The reaction process of the method is convenient and controllable, the utilization rate is high, and the method is more suitable for laboratory and commercial production, and has a good application prospect for the development of the organic metal sulfide material in the field of organic semiconductor materials.

The application discloses a monovalent currency metal complex and preparation and application thereof, and belongs to the technical field of electroluminescent materials. The monovalent currency metal complex has a carbene-metal-arylamines structure, has a thermal activation delayed fluorescence property, and has the advantages of high photo-induced quantum yield, short exciton lifetime and high level of directional transition dipole orientation distribution, so that the external quantum efficiency of a device can be improved and the efficiency roll-off of the device can be inhibited, and a new scheme for constructing an organic electroluminescent device with high efficiency and long service life is provided.

The present disclosure provides coinage metal carbene emitters of Formula I; organic light emitting device (OLED) comprising an anode, a cathode, and an organic layer, disposed between the anode and the cathode, comprising a compound of Formula I; and consumer products comprising an OLED comprising a compound of Formula I:

The invention relates to organic electroluminescent materials and devices. A compound comprising a first ligand LA of Formula I is provided. In Formula I, Part A is a monocyclic or polycyclic fused ring system; part B is a polycyclic fused ring system having at least three rings; each of Z1 to Z4 is C or N; k is a direct bond or a linking group; each R substituent is hydrogen or a universal substituent as defined herein; at least one RA comprises a non-aromatic polycyclic group; lA is coordinated with metal M; z1 and M form a coordinate bond; and Z2 and K form an anionic bond. Formulations, OLEDs, and consumer products containing the compounds are also provided.

The present disclosure relates to functionalized gold carbene naphthoquinone compounds and salts thereof. In some aspects, these compounds can be used to treat cancer including cancers which are resistant to one or more other chemotherapeutic agents such as cisplatin or platinum chemotherapeutic agents. Also provided herein are pharmaceutical compositions comprising the gold carbene naphthoquinone compounds. The present disclosure also provides methods of preparing a cancer vaccine.

To provide an aggregate of Ag nanoclusters that features the structured and periodic arrangement of the Ag nanoclusters, demonstrating outstanding thermal stability.SOLUTION: An aggregate of Ag nanoclusters comprises Ag nanoclusters, comprising two or more Ag atoms, connected and aggregated through an organic compound as a linker. The linker comprises C-C triple bonds, with pyridine ligands at every terminus.SELECTED DRAWING: Figure 5

The invention relates to a metal complex acceptor material, an exciplex thereof and application. The invention relates to a metal complex acceptor material, which is a compound with a structure as shown in a formula (I), the metal complex acceptor material is matched with an organic donor material to form an exciplex luminescent material, the exciplex luminescent material is applied to an organic light-emitting diode, the driving voltage is lower, the luminous efficiency is higher, and the service life of a device can be prolonged. The compound has potential to be applied to the field of organic electroluminescent devices.

Described herein are two-coordinate d10 metal carbene complexes comprising (i) Cu(I), Ag(I), or Au(I), (ii) a pyrazine-fused NHC ligand or a pyridine-fused NHC ligand, and (iii) a carbazole ligand, a pyrido[2,3-b]indole ligand, or a pyrido[3,4-b]indole ligand. The radiative properties of the compounds can be controlled through thermally activated delayed fluorescence. The emission color of the complexes can be tuned through the use of carbazoles with different donor strengths. Methods of using the complexes are also described herein.

The present application belongs to the cross field of coordination chemistry and nanomaterials, discloses a tert-butyl acetylene ligand protected silver cluster and a preparation method thereof and application thereof in X-ray detection. 72 H 109 Ag 14 ClO (abbreviation: Ag 14 ), belongs to the trigonal system, and the space group is R-3. Under X-ray irradiation, it changes from white or colorless to purple, and the fluorescence color also changes from blue to orange red. The sample after color change is dissolved in a methanol solution for recrystallization, and can be restored to the initial state. In a relatively wide temperature range (77K-330K), the Ag 14 sample can be induced to change color by X-ray, which opens up a new way for developing a new type of cluster-based X-ray detection material which is cheap, simple and recyclable.

The invention relates to organic electroluminescent materials and devices. A compound having a first ligand LA is provided, wherein the first ligand LA comprises a structure of Formula I. In formula I, if R2 and R3 are not joined to form a ring, then at least two of R1 to R6 are not H. Likewise in Formula I, if R1 and R2 are not H, then R1 and R2 are neither bonded to the first ligand LA. Formulations, OLEDs, and consumer products containing the compounds are also provided.

Provided is a compound having Formula Iwhere rings A and B are independently a five-membered or six-membered, carbocyclic or heterocyclic ring, each of which is optionally aromatic; together with nitrogen atoms bonded to ring A and ring B, ring W is a 5-membered N-heterocyclic carbene; and the remaining variables are as defined herein.

Provided are powder of a pure disilver hydrogen citrate-containing composition in powder form, having excellent solubility, and a method for easily obtaining the disilver hydrogen citrate-containing composition with high efficiency. In addition, provided are an antibacterial agent or antiviral agent, containing the disilver hydrogen citrate-containing composition, and a method for producing the same. The method for producing a disilver hydrogen citrate-containing composition of the present invention includes the following processes (1) to (3): (1) preparing a reaction mixture containing a silver compound and citric acid, the reaction mixture having a pH of 2.0 to 5.5; (2) precipitating the disilver hydrogen citrate-containing composition from the reaction mixture; and (3) collecting the precipitated disilver hydrogen citrate-containing composition.

The present application relates to metal complex acceptor material, its excited complex and application. A kind of metal complex acceptor material, it is the compound with the structure of formula (I), combined with organic donor material by the metal complex acceptor material to form excited complex luminescent material application in organic light emitting diode, with lower driving voltage and higher luminous efficiency, and can improve the service life of device, has potential application in the field of organic electroluminescence device.

The present invention relates to a method for preparing a p-type semiconductor layer, a p-type semiconductor layer obtainable by said method, an organic electronic device comprising said p-type semiconductor layer, a display device comprising said organic electronic device, a metal compound, and the use of said metal compound in a p-type semiconductor layer.