56results about "Silver organic compounds" patented technology

Provided are powder of a pure disilver hydrogen citrate-containing composition in powder form, having excellent solubility, and a method for easily obtaining the disilver hydrogen citrate-containing composition with high efficiency. In addition, provided are an antibacterial agent or antiviral agent, containing the disilver hydrogen citrate-containing composition, and a method for producing the same.The method for producing a disilver hydrogen citrate-containing composition of the present invention includes the following processes (1) to (3):(1) preparing a reaction mixture containing a silver compound and citric acid, the reaction mixture having a pH of 2.0 to 5.5;(2) precipitating the disilver hydrogen citrate-containing composition from the reaction mixture; and(3) collecting the precipitated disilver hydrogen citrate-containing composition.

Provided is a light-emitting element having a low driving voltage and high reliability. The light-emitting element includes a light-emitting layer between an anode and a cathode, and a first layer between the light-emitting layer and the cathode, the first layer containing an organic compound and a metal. The metal belongs to any one of group 3 to group 13 in the periodic table. The organic compound and the metal are a SOMO-forming combination.

The invention relates to organic electroluminescent materials and devices. The present disclosure provides carbene emitters of formula (I) wherein the ligand LigA has one or more electron withdrawing substituents; an organic light emitting device (OLED) comprising an anode, a cathode, and an organic layer disposed between the anode and the cathode, the organic layer comprising a compound of formula (I); and a consumer product comprising an OLED comprising a compound of formula (I): Formula (I).

An antimicrobial agent with synergistic antimicrobial effects, comprising iodide ions encapsulated within silver cages, as well as its preparation method and application, relates to the technical field of antimicrobial materials. The antimicrobial agent utilizes a 16-core silver cage as its basic structural unit, encapsulating iodide ions within the cages and assembling them into a one-dimensional chain structure using thiols as connectors. This antimicrobial agent, by encapsulating iodide ions within the silver cages, achieves diversified antimicrobial material performance and structure through the synergistic action of multiple antimicrobial mechanisms.

A compound including a first ligand LA of Formula I,is provided. In Formula I, moiety A is a monocyclic ring or a polycyclic fused ring system; moiety B is a polycyclic fused ring system having at least three rings; each of Z1 to Z4 is C or N; K is a direct bond or a linking group; each R substituent is hydrogen or a General Substituent defined herein; at least one RA includes a non-aromatic polycyclic group; LA is coordinated to a metal M; Z1 forms a dative bond with M; and Z2 forms an anionic bond to K. Formulations, OLEDs, and consumer products containing the compound are also provided.

The invention discloses a Salen ligand, a carbene compound and a preparation method of the Salen ligand and the carbene compound, and belongs to the technical field of chemical synthesis. The chemical structural formula of the Salen ligand is shown as a formula I, and the formula I is # imgabs0 #; in the formula I, M comprises any one of Pd, Ni, Cu and Zn; r comprises any one of methyl, ethyl and n-butyl; r'comprises any one of C1-C5 alkyl, phenyl and biphenyl; and X comprises PF6. Salen and carbene are combined to realize concerted catalysis, stability enhancement and multifunctional integration, the structure adjustability and metal coordination capability of the Salen ligand are retained, high reaction activity and stability of carbene are introduced, a multifunctional composite system is formed, the catalytic activity of the single Salen ligand is remarkably improved, and the Salen ligand has a wide application prospect. The application field of the Salen ligand is widened, and the technical problem that Salen is rarely researched in the carbene field is solved.

The invention relates to the technical field of developing materials, and discloses a preparation method and application of a luminescent nanocluster, the preparation method comprises the following steps: step 1, dissolving a metal precursor in methanol to prepare a metal precursor solution, the metal precursor being selected from silver nitrate, copper nitrate or a combination thereof; step 2, adding 4, 6-dimethyl-2-mercaptopyrimidine into the metal precursor solution, and carrying out a stirring reaction to form a complex; 3, adding sodium hydroxide into the reaction mixture, and continuously stirring until a luminescence phenomenon occurs; step 4, carrying out centrifugal treatment on the reacted solution, and separating to obtain an upper solution and a lower precipitate; step 5, respectively collecting the upper solution and the lower precipitate redissolved by methanol, and standing; step 6, obtaining a high-luminescence nanocluster crystal in a natural volatilization or standing and airing mode; the absolute luminous quantum efficiency of the material prepared by the invention is 60% or above, and some absolute luminous quantum efficiencies are even close to 100%; the light-emitting wavelength can be adjusted from yellow-green to red, the latent fingerprint showing precision is extremely high, the third-level characteristics of fingerprints can be clearly shown, the advantages of being simple in synthesis process, low in cost, small in pollution and the like are achieved, and wide application prospects are achieved in the technical field of new-generation fingerprint detection.

The present invention relates to Ag-based organic coordination nanoparticles, a method for producing the same, a photoresist composition and use thereof. m (R) n (Q) x ] y The production method involves placing a silver salt and a primary organic ligand in a sample bottle, dissolving them in an organic solvent, stirring for a certain period of time under specific temperature conditions, filtering, concentrating, crystallizing by cooling or evaporating, and finally recrystallizing in an organic solvent to obtain Ag-based organic coordination nanoparticles. This nanoparticle composition can be used as an electron beam, mid-UV, deep UV, and EUV photoresist.

An organometallic compound represented by Formula 1wherein, M1 to M4 are each independently a first-row transition metal, a second-row transition metal, or a third-row transition metal; X1 and X2 are each independently C(R5)(R6), Si(R5)(R6), N(R5), O, S, Se, or Te; W1 to W4 are each independently N(R7)(R8), P(R7)(R8), S(R7), a C5-C60 carbocyclic group unsubstituted or substituted with at least one R10a, or a C1-C60 heterocyclic group unsubstituted or substituted with at least one R10a; L1 to L6 are each independently a C1-C30 alkylene group unsubstituted or substituted with at least one R10a, a C5-C60 carbocyclic group unsubstituted or substituted with at least one R10a, or a C1-C60 heterocyclic group unsubstituted or substituted with at least one R10a, a3 to a6 are each independently an integer from 0 to 3, and R1 to R8 and R10a in Formula 1 are as described herein.

To provide an extractant for selectively extracting at least one of cuprous salt and silver salt.SOLUTION: The present invention provides a metal salt extractant for extracting at least one of cuprous salt and silver salt. The extractant is a compound represented by general formula (1). In the general formula (1), R1 and R2 each independently represent a hydrogen atom, an alkyl group, an aryl group, a heteroaryl group, an alkoxy group, a hydroxy group, or a group represented by -NHR', and R' represents a hydrogen atom, an alkyl group, an aryl group, a heteroaryl group, an alkoxy group, or a hydroxy group.SELECTED DRAWING: Figure 1

Provided is a light-emitting element having a low driving voltage and high reliability. The light-emitting element includes a first light-emitting layer and a second light-emitting layer between an anode and a cathode, and a first layer between the first light-emitting layer and the second light-emitting layer. The first layer includes a metal and a first organic compound including an electron-deficient heteroaromatic ring. The metal belongs to any one of group 3 to group 13 in the periodic table.

Provided are compounds of Formula (I) wherein P is a phosphorescent emitter, F is a fluorescent emitter, and L is a covalent linker. Also provided are formulations comprising these compounds. Further provided are OLEDs and related consumer products that utilize these compounds

The application discloses a thiacalix[4]arene-protected copper-silver nanocluster material for electro-reducing CO2 and a preparation method thereof, and belongs to the technical field of organic-inorganic hybrid catalysts. O h Symmetry, the molecular structure is composed of a truncated cubic inorganic silver core and a peripheral ligand, large ligands cover, i.e. passivate the larger face of the cubic core, small size ligands cover, i.e. passivate the smaller face of the cubic core, forming a double hydrophobic protective shell. The silver atoms on the truncated face are exposed, realizing the symmetrical construction of the cluster structure and the ordered exposure of the sites, and effectively ensuring the synthesis of the copper-silver nanocluster material with stability and activity. The faradic efficiency of the copper-silver nanocluster material for electro-catalytically reducing CO2 to CO reaches 97.76% under the condition of self-stability.

A kind of super-large mercaptan silver cluster material with silver triangle as core and its preparation method belong to the technical field of inorganic nanomaterials, the chemical formula of the silver cluster material is: C 114 Ag 104 S 34 O2, belongs to triclinic system, space group is P-1, cell parameter is α=108.5020 (10) °, β=119.4730 (10) °, γ=96.1580 (10) °, the silver cluster material has luminescent property.

A compound having a first ligand LA wherein the first ligand LA comprises a structure of Formula Iis provided. In Formula I, if R2 and R3 are not joined to form a ring, then at least two of R1 to R6 are not H. Also in Formula I, if R1 and R2 are not H, then R1 and R2 are also not bonded to the first ligand LA. Formulations, OLEDs and consumer products containing the compound are also provided.

Methods of depositing a passivation layer on a semiconductor substrate are described. The methods may include exposing a semiconductor substrate having a metal layer thereon to a precursor to form a passivation layer on the metal layer, the precursor having a general formula (I), where exposing the semiconductor substrate to the precursor may include a transmetallation process. The method may further include purging the semiconductor substrate.

The application discloses a metal nanomaterial, in particular discloses a thermoluminescence color-changing metal nanomaterial, a preparation method and application thereof. The thermoluminescence color-changing metal nanomaterial exhibits a significant temperature-dependent characteristic in emission intensity under ultraviolet excitation. The thermoluminescence color-changing metal nanomaterial can be used as a nanometer fluorescence thermometer and has wide application in the technical fields of biological medicine, environmental monitoring and nanoelectronics.

To provide an organometallic compound and an organic light-emitting device including the organometallic compound.SOLUTION: An organometallic compound herein is represented by chemical formula 1 shown below. For explanations of the chemical formula 1, the corresponding descriptions of the specifications are referred to.SELECTED DRAWING: Figure 1

The invention discloses a chiral metal halide optical waveguide material and a preparation method thereof, and relates to the technical field of optical waveguide materials, and the preparation method of the chiral metal halide optical waveguide material comprises the steps that chiral amine, metal halide, a reducing agent and acid are mixed and heated till solid is dissolved; and cooling and crystallizing to obtain the chiral metal halide optical waveguide material. The optical waveguide material with CPL emission and optical waveguide transmission functions is prepared, the material can efficiently generate circular polarization luminescence, and low-loss and directional optical waveguide transmission of CPL is achieved.

Copper, silver and gold fluorinated alkoxide complexes such as complexes having a structure represented by the general formula (I) are described:, and multimers thereof and / or crystalline forms thereof as well as uses thereof, such as in processes to prepare materials, films and / or structures comprising copper, silver or gold using, processes including atomic layer deposition and chemical vapor deposition processes.

The present invention relates to an organic electronic device comprising a semiconductor layer, said semiconductor layer comprising a compound of formula (1).

Copper, silver and gold fluorinated alkoxide complexes such as complexes having a structure represented by the general formula (I) are described:, and multimers thereof and / or crystalline forms thereof as well as uses thereof, such as in processes to prepare materials, films and / or structures comprising copper, silver or gold using, processes including atomic layer deposition and chemical vapor deposition processes.

The present invention discloses a solvent-induced complex material, a preparation method and an application thereof, wherein the chemical formula of the complex material is [(1,2-bis(3-pyridyl)ethylene)(1,2,4,5-benzenetracarboxylate) 0.5 silver] n . The complex material of the present invention has a homogeneous polycrystalline structure, which is α-type and β-type respectively. α-type and β-type can be converted into each other in different solvents. Silver nitrate, 1,2-bis(3-pyridyl)ethylene and 1,2,4,5-benzenetetracarboxylic acid form an α-type complex through coordination self-assembly in a methanol solvent. The α-type complex is a one-dimensional chain structure. The α-type complex is dissolved in acetonitrile and recrystallized to form a β-type complex; the β-type complex is dissolved in methanol and recrystallized to reform the α-type complex. Compared with the α-type structure, the conductivity of the material with the β-type structure is increased by 58%. The synthesis method of the solvent-induced complex material of the present invention is simple, the synthesis conditions are mild, and the yield is high.

Disclosed herein are metal complexes that exhibit multiple radiative decay mechanisms, together with methods for the preparation and use thereof.

The present application belongs to the technical field of oil field chemistry, and particularly relates to a slow-release gel breaker, an intelligent controllable temperature-resistant temporary plugging agent and a preparation method thereof. The raw materials of the slow-release gel breaker include the following components in parts by weight: silver salt and a complexing agent, wherein the complexing agent is ammonia or 1,4-dicyanobenzene; the raw materials of the intelligent controllable temperature-resistant temporary plugging agent include the following components in parts by weight: the slow-release gel breaker, a thickening agent, an initiator and a crosslinking agent. The preparation method includes mixing and reacting the silver salt and the complexing agent to obtain the gel breaker, dissolving the thickening agent in water, adding the initiator, the crosslinking agent and the gel breaker, mixing and reacting to obtain the product. Compared with the existing temporary plugging agent technology, the present application has the advantages of low viscosity before injection, one-time injection into the formation, arbitrary control of gel breaking time, plugging rate greater than 90%, good plugging property, reduced cost and time of secondary injection of the gel breaker, and important significance for oil field measures such as profile control, water plugging and acidizing fracturing.

The present invention relates to poly(melamine-silicate) derivatives as biocidal disinfection and decontamination agents, and to methods for their production and use. More specifically, the invention relates to halogenated adducts of poly(melamine- silicate) with metal oxides.

The application discloses an organic semiconductor material based on a hexamer capto benzene silver organic metal sulfide and application thereof. The heterogeneous synthesis method of the hexamer capto benzene silver comprises the following steps: under the condition of heating, the hexamer capto benzene silver is reacted with silver chloride in an organic solvent under an inert atmosphere, and the reaction temperature is 45-65 DEG C, and the reaction time is 24-72 h. The hexamer capto benzene silver is prepared through a P-type organic semiconductor device, and the migration rate can be up to 50 cm 2 / (V.s)~200 cm 2 / (V.s). The raw material is cheap and easy to obtain, is low-toxicity and harmless, is an environment-friendly and sustainable development new method for preparing materials. The reaction process of the method is convenient and controllable, the utilization rate is high, and the method is more suitable for laboratory and commercial production, and has a good application prospect for the development of the organic metal sulfide material in the field of organic semiconductor materials.

The application discloses a monovalent currency metal complex and preparation and application thereof, and belongs to the technical field of electroluminescent materials. The monovalent currency metal complex has a carbene-metal-arylamines structure, has a thermal activation delayed fluorescence property, and has the advantages of high photo-induced quantum yield, short exciton lifetime and high level of directional transition dipole orientation distribution, so that the external quantum efficiency of a device can be improved and the efficiency roll-off of the device can be inhibited, and a new scheme for constructing an organic electroluminescent device with high efficiency and long service life is provided.