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176 results about "Carbine" patented technology

A carbine (/ˈkɑːrbiːn/ or /ˈkɑːrbaɪn/), from French carabine, is a long gun firearm but with a shorter barrel than a rifle or musket. Many carbines are shortened versions of full-length rifles, shooting the same ammunition, while others fire lower-powered ammunition, including types designed for pistols.

Aza cyclic carbine rear earth catalyst for crystallinity 3,4-polyisoprene

The present invention relates to a nitrogen heterocyclic carbene rare earth complex, a catalyst system which consists of the present invention, aluminum alkyl and an organoboron salt can catalyse the isoprene to carry out the solution polymerization, so as to prepare the polyisoprene with the crystallization property, high 3, 4-structure and high glass transition temperature (Tg). The molar ratio of aluminum alkyl and the rare earth complex is within the scope of 1 to 100, the molar ratio of the organoboron salt and the rare earth complex is within the scope of 0.5 to 2.0; the solvent which is used for polymerization can be toluene, bromobenzene, n-hexane, dichloromethane or chlorobenzene; the polymerization temperature range is -20 DEG C to 80 DEG C, the reaction time of polymerization at minus 20 DEG C is 36 hours, the reaction time of polymerization at 80 DEG C is 1 hour, and the monomer conversion rate can be up to 100 percent. The reaction is characterized by active polymerization, the molecular weight of the product can be controlled by the molar ratio of the monomer and the catalyst, the molecular weight of the polyisoprene can achieve 360,000 at most, and the glass transition temperature Tg is equal to 5 DEG C to 50 DEG C. The content of the 3, 4 structure of the polyisoprene is affected by the spatial effect and the electronic effect of the rare earth complex, the solvent type for polymerization reaction and the polymerization reaction temperature and so on, which is changed between 76 percent and 99 percent.
Owner:CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI

Wolfram carbine abrasion-proof core deposit welding rod

A tungsten carbide wear resistant drug core resurfacing welding rod comprises a drug core and a steel sheet for wrapping the drug core. A drug fur powder material is coated outside the steel sheet. The weights of the drug core, the steel sheet and the drug fur powder material separately in the total weight of the welding rod is that is the drug core is ranged from 32 percent to 36 percent, the steel sheet is ranged from 32 percent to 36 percent, the drug fur powder material is ranged from 30 percent to 34 percent, the drug core tungsten carbide is ranged from 96 percent to 98 percent and nickel is ranged from 2 percent to 4 percent. The weight of drug fur is distributed according to percent that marble is ranged from 33 percent to 35 percent, fluorite is ranged from 35 percent to 38 percent, tungsten carbide is ranged from 10 percent to 14 percent, high carbon ferromanganese is ranged from 2 percent to 6 percent, titanium iron is ranged from 8 percent to12 percent, rare earths silicon is ranged from 1 percent to 3 percent and calcined soda is ranged from 1 percent to 3 percent. The resistant alloy is equably bridged to the resurfacing welding metal through welding core. The invention has the advantages that the welding technics performance is good and the welding line ingredient is even. The connecting strength is high, thereby, avoiding gas hole and flaw and with good detachability. The invention has a higher hardness and wear resistant performance. The making technics is simple and the producing cost is lower. The welding rod structure is novel and the welding shape is good to suit in full position resurfacing welding of wearing parts in the engineering machinery in metallurgy and mine.
Owner:WUHAN TEMO WELDING CONSUMABLES CO LTD

Chiral 1,2-diamine compound and preparation method and application thereof

The invention discloses a chiral 1,2-diamine compound and a preparation method and application thereof. The molecular structure general formula of the chiral 1,2-diamine compound is shown as the general formula (I) in the specification. The preparation method of the chiral 1,2-diamine compound comprises the steps that an amine compound A and a nitroolefin compound B are added to a reaction system containing an n-heterocyclic carbine catalyst, an alkali reagent, a proton additive and a dewatering reagent for reacting and other steps. The chiral 1,2-diamine compound comprises chiral quaternary carbon atoms containing electrondrawing groups and amino groups, and can be widely used for synthesizing drug intermediates, especially heterocyclic ring structure compounds, and preparing functional materials. The preparation method is simple in process and low in requirement for reaction conditions, the reaction process is safe and controllable, the atom utilization rate and production efficiency are high, meanwhile, the enantioselectivity of products is efficiently guaranteed, and the environment pollution pressure of the methodology is low through the introduction of the small organic molecule asymmetric catalysis concept.
Owner:PEKING UNIV SHENZHEN GRADUATE SCHOOL

Dinuclear nickel cross-coupling reaction catalyst supported by nitrogen heterocycle carbine ligand and preparation method thereof

The invention discloses a dual-core nickel cross-coupling reaction catalyst supported by N-heterocyclic carbine and a preparation method. Acetonitrile is taken as a solvent, N-heterocyclic carbine ligand and silver oxide in the molar ratio of 1: 3 to 1: 6 are added and stirred, the reaction is carried out for 10 to 15 hours away from light; Ni(DME)Cl2 or Ni(PPh3)2Cl2, Ni(DME)Cl2 or Ni(PPH3)2Cl2 and the N-heterocyclic carbine ligand in the molar ratio of 2: 1 to 3: 1 are added and filtered, the filtrate is condensed, ether is added for precipitation of yellow solids, the yellow solids are sequentially washed by ethanol and ether for 2 to 3 times, the acetonitrile is then used for dissolution, the ether is slowly added, and the dual-core nickel cross-coupling reaction catalyst supported by the N-heterocyclic carbine is obtained by crystallization. The novel dual-core nickel catalyst synthesized by the invention can play the synergy due to the shorter distance between two nickel atoms, the catalytic effect thereof is higher than the common palladium catalyst, thus having very ideal catalytic effect on chlorinated aryl compounds with cheap price and wide application prospect in fine chemical and pharmaceutical industries and being environment-friendly.
Owner:ZHEJIANG UNIV

Mesoporous carbon supported N-heterocyclic carbene-palladium catalyst as well as preparation and application thereof

The invention discloses a mesoporous carbon supported N-heterocyclic carbene-palladium catalyst as well as a preparation method and application thereof. The catalyst carrier is hydroxylated mesoporous carbon; the ligand is N-heterocyclic carbine; the active ingredient is palladium chloride; the load capacity of the palladium in the active ingredient is 5.0-10.0% of the total mass of the catalyst; the surface hydroxyl group content of the hydroxylated mesoporous carbon is 1.9-2.2 mmol / g; the BET specific surface area of the hydroxylated mesoporous carbon is 700-1000m<2> / g; the BJH pore diameter is 5-7 nm; the BJH pore volume is 0.8-1.8 ml / g. According to the mesoporous carbon supported N-heterocyclic carbene-palladium catalyst, the palladium can be prevented from loss in the catalytic process; the mesoporous carbon has an ordered mesoporous structure, so that the surface dispersing performance of the palladium nano-particles can be improved to prevent the palladium from gathering in the catalytic process and improve the catalytic activity of the supported catalyst. The mesoporous carbon supported N-heterocyclic carbene-palladium catalyst has relatively high catalytic activity and relatively good reusability.
Owner:EAST CHINA UNIV OF TECH

N-heterocyclic carbine palladium compound containing pyridyl-2-formate or pyridyl-2,6-diformate ligand, preparation thereof and application thereof

The invention relates to a preparation method and an application of an N-heterocyclic carbine palladium compound containing a pyridyl-2-formate or pyridyl-2,6-diformate ligand. The N-heterocyclic carbine palladium compound containing the pyridyl-2-formate or pyridyl-2,6-diformate ligand is generated by reacting initial raw materials of a substituted imidazolium or imidazolium salt, palladium chloride and 2-picolinic acid or 2,6-dipicolinic acid, or the N-heterocyclic carbine palladium compound is generated in a high yield manner by using a corresponding N-heterocyclic carbine palladium chloride dipolymer and 2-picolinic acid or 2,6-dipicolinic acid as initial raw materials. The N-heterocyclic carbine palladium compound of the invention has a very high catalytic activity when being used in a C-N cross-coupling reaction of a halogenated arene and an organic amine as a catalyst. The chemical structural formula of the N-heterocyclic carbine palladium compound containing the pyridyl-2-formate or pyridyl-2,6-diformate ligand is shown in the specification. In the chemical structural formula, m is 0-4, and n is 0-3; and carbon numbers of R<1>, R<2>, R<3>, R<4> and R<5> are defined in the claim 1.
Owner:NANKAI UNIV
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