The invention discloses a preparation method and application of a Ni-Eu-DPA three-dimensional coordination framework
crystal material, and relates to a preparation method and application of a three-dimensional coordination framework
crystal material. The problems that in the existing
aromatic ketone alpha-H deuteration field, the photocatalytic
light excitation state service life is short, the energy
utilization rate is low, the reaction selectivity needs to be improved, the
deuterium source is expensive, and the conditions are harsh are solved. The preparation method comprises the following steps: 1, dissolving Ni (ClO4) 2.6 H2O in water, then adding
dipicolinic acid, heating and stirring to obtain a
system A; 2, Eu (NO3) 3.6 H2O is dissolved in water, then
picolinic acid is added, heating and stirring are conducted, and a
system B is obtained; and 3, mixing the
system A and the system B, transferring the mixture into a
polytetrafluoroethylene reaction kettle for
solvothermal reaction, and naturally cooling to
room temperature to separate out light green flaky crystals. The photocatalyst is applied to the selective deuteration reaction of
aromatic ketone alpha-H.