The invention discloses a
fluorescence detection method of
tin ions Sn < 4 + >, which is characterized in that on the basis of a dual-emission ratio sensing mechanism of a
europium metal organic framework, Eu < 3 + >, 2-hydroxyterephthalic acid (HTPA) and 1, 10-
phenanthroline are coordinated and self-assembled to synthesize cubic EuMOF, and the cubic EuMOF simultaneously generates dual-emission
fluorescence of HTPA and Eu < 3 + > at 430 nm and 614 nm respectively. When Sn < 4 + > exists, the EuMOF structure collapses, so that the
antenna effect between the ligand and Eu < 3 + > is destroyed, the I614 / I430
fluorescence intensity ratio change is initiated, the Sn < 4 + > quantitative detection is realized, the
detection limit is as low as 54.37 nM, and the
linear range is 0.1-100 [mu] M. Aiming at
field detection requirements, EuMOF test paper is further combined with RGB analysis application assisted by a
smart phone to construct a portable visual sensing platform. The fluorescent sensor constructed by the invention can realize quantitative analysis and
rapid detection of Sn < 4 + >, has high sensitivity,
high selectivity and good anti-interference capability, and can be used for detecting Sn < 4 + > in an actual sample.