The invention belongs to the technical field of
supramolecular chemistry macrocyclic main body design and anion recognition, and particularly relates to an anion
acceptor material based on bicyclic condensed
aromatic hydrocarbon as well as a preparation method and application of the anion
acceptor material. The anion
acceptor material is shown as a formula I and has a D-A structure, the existence of an
electron acceptor ensures low
electron density of a large-ring inner cavity of the anion acceptor material, and the anion acceptor material shows strong affinity to anions. Meanwhile, the anion acceptor material has two
anion binding sites, and has potential application in the field of supramolecular
polymer construction. The anion acceptor material based on the bicyclic condensed
aromatic hydrocarbon is simple in synthesis
route, low in cost and modifiable, has good recognition capability on anions, and can be widely applied to the fields of anion recognition sensing,
supramolecular assembly, supramolecular
polymer construction and the like.