The invention belongs to the technical field of
composite electrode materials, and relates to a preparation method of a NiCoCu
selenide composite MXene / carbon sphere
thin film electrode material, which comprises the following steps: firstly, dissolving ZIF-67
powder in a carbon sphere solution, then adding an MXene
aqueous solution, stirring for 1-10 hours, and carrying out suction
filtration and
drying to obtain ZIF-67 MXene / CS; secondly, a solution is prepared from
urea, a
copper source, a
nickel source and ethyl
alcohol according to the proportion, ZIF-67 (at) MXene / CS is immersed in the solution, and a NiCoCu-LDH (at) MXene / CS thin film is obtained after a
hydrothermal reaction; and thirdly, mixing the NiCoCu-LDH-coated MXene / CS film,
selenium powder and
sodium borohydride according to a
mass ratio of (0.5-1): (1-2): (1-2), reacting at 150-180 DEG C for 12-24 hours, washing the obtained product with deionized water, and
drying to obtain the NiCoCu-LDH-coated MXene / CS
composite material. The MXene and the carbon spheres jointly provide a flexible substrate for the self-supporting material, the
conductivity and the specific surface area of the material are increased, meanwhile, NiCoCu-Se is intercalated into the MXene, an intermediate buffering effect is achieved, self-stacking of the MXene is prevented, and the structure of the self-supporting material is more stable. When the self-supporting material is applied to a positive
electrode material of a
supercapacitor, the self-supporting material avoids using an
adhesive, so that the impedance of the material is reduced, and the electrochemical performance is improved.