A high-temperature resistant lithium ion electrolyte belongs to the technical field of a lithium battery electrolyte and comprises a lithium salt and an organic solvent and also comprises 1,2-bi(trimethylsilyl) ethylene, 1,3-dimethyl-1,1,3,3-tetraethylene disiloxane, 2,4,6-triethylene-2,4,6-trimethylcyclotrisiloxane or 1,3-divinyl-1,1,3,3-tetramethyl-disilazane. In the battery electrolyte, the charge-discharge performance of a lithium battery can be effectively improved due to addition of the substance into the electrolyte, side reaction is reduced, so that the battery bubbling is reduced, andthe cycle lifetime of the battery is prolonged.