The invention discloses a
polyurethane resin modified acetic acid-propionic acid
emulsion as well as a preparation method and application thereof, and belongs to the technical field of emulsions for glass fibers. The
emulsion is prepared from the following raw materials in parts by weight: 200 to 300 parts of
butyl acrylate, l70 to 210 parts of
vinyl acetate, 10 to 15 parts of
methacrylic acid, 8 to 15 parts of
dimethyl ester, 5 to 10 parts of
polyurethane resin, 5.0 to 6.0 parts of nonionic emulsifier, 4.0 to 5.0 parts of anionic emulsifier, 0.5 to 1.5 parts of initiator, 0.4 to 0.9 part of
sodium bicarbonate and 350 to 400 parts of water. The preparation method comprises the following steps: (1) weighing the raw materials; (2) heating, stirring and dispersing the nonionic emulsifier, the anionic emulsifier and part of water to obtain a pre-
emulsion; and (3) firstly stirring
butyl acrylate,
vinyl acetate,
methacrylic acid,
dimethyl ester and
polyurethane resin, then adding the rest water and
sodium bicarbonate, continuously stirring, heating, adding an initiator for reaction, finally dropwise adding the pre-emulsion, keeping the temperature and cooling to obtain the water-based
adhesive. And polyurethane is used for modification, so that the
water resistance and the
heat resistance of the modified
glass fiber are improved, and the modified
glass fiber has excellent performance when being used on the
glass fiber.