The invention discloses a preparation method for a supercapacitor material MoO2/graphene/g-C3N4, and belongs to the technical field of composite material preparation. The method comprises the following steps: 1), scattering oxidized graphene into deionized water, employing a cell pulverizer for smashing, adding mixed solution composed of a molybdenum salt precursor and an end-capping reagent, carrying out the stirring of the mixed solution, enabling the mixed solution to be uniform, and obtaining an oxidized graphene-molybdenum salt-sodium salt mixed solution system; 2), adjusting pH value andthen carrying out the hydro-thermal reaction in a reaction still; 3), employing water and ethyl alcohol for cleaning, carrying out the low-temperature vacuum drying, and obtaining an MoO2 composite oxidized graphene material; 4), mechanically mixing the MoO2 composite oxidized graphene material with a carbon and nitrogen precursor, carrying out the high-temperature calcination of the mixture under the protective atmosphere of high temperature argon gas, cooling the mixture to the room temperature, and then obtaining the MoO2/graphene/g-C3N4 composite material. The method is simple and feasible, and is low in cost. The specific capacity of an obtained composite material supercapacitor is remarkably enlarged, and the composite material supercapacitor is good in cyclic charging and discharging stability.