The invention discloses a benzo pentacyclic compound and application thereof, and belongs to the technical field of display. The chemical
structural formula of the compound is shown in the specification, wherein Ar, R1 to R6 are respectively and independently
hydrogen,
deuterium,
halogen, cyano, nitro,
alkyl of C1-C18, alkoxy of C1-C12, substituted or unsubstituted
aryl of C6-C30 or substituted or unsubstituted heteroaryl of C3-C30, and R1 to R6 are respectively and independently selected from
hydrogen,
deuterium,
halogen, cyano, nitro,
alkyl of C1-C18, alkoxy of C1-C12, substituted or unsubstituted
aryl of C6-C30 or substituted or unsubstituted heteroaryl of C3-C30; ar1 and Ar2 are respectively and independently a substituted or unsubstituted C6-C30
aryl group or a substituted or unsubstituted C3-C30 heteroaryl group; each of L1 to L3 independently represents a
single bond, a substituted or unsubstituted C6-C60
arylene group, or a substituted or unsubstituted C3-C30 heteroarylene group; at least one of Z1 to Z3 is N, and the balance is CH; a is O, S, Se or CR7R8. The compound has excellent
electron transmission performance, and is beneficial to improving the
voltage, efficiency and service life of a device.