Fluorosilicate self-cleaning glass nanophase material and producing method thereof
A technology of nanomaterials and production methods, applied in the field of silicon fluoride self-cleaning glass nanomaterials, can solve the problems of complex production process, high cost, and relatively high temperature requirements for curing and film formation, and achieves simple construction, stable product performance, and good resistance. The effect of UV aging properties
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Embodiment 1
[0031] The production method of silicon fluoride self-cleaning glass nanomaterials in this embodiment includes the following two steps:
[0032] 1) Synthesis of silica nanoparticles
[0033] 500 parts of ethanol was placed in the reactor as a solvent and stirred, and 15 parts of water was added. Then add concentrated ammonia water to adjust the pH value of the system to 10. At a reaction temperature of 40°C, 15 parts of ethyl orthosilicate was added into the reactor, and the hydrolysis reaction was carried out for 1.0 h.
[0034] 2) Surface modification of silica nanoparticles
[0035] The pH value of the above reaction system was adjusted to 6.0 with dilute hydrochloric acid, 1.5 parts of tridecafluorooctyltrimethoxysilane was added, and the reaction was continued at 35° C. for 6 h to obtain a light blue solution. The pH value of the reaction system is adjusted to 7.0 with ammonia water, and the reaction product is filtered to obtain the fluorinated modified silicone nano ...
Embodiment 2
[0038] The production method of silicon fluoride self-cleaning glass nanomaterials in this embodiment includes the following two steps:
[0039] 1) Synthesis of silica nanoparticles
[0040] 500 parts of ethanol was placed in the reactor as a solvent and stirred, and 15 parts of water was added. Then add concentrated ammonia water to adjust the pH value of the system to 10. At a reaction temperature of 50° C., 15 parts of ethyl orthosilicate was added into the reactor, and the hydrolysis reaction was carried out for 0.8 h.
[0041] 2) Surface modification of silica nanoparticles
[0042] Adjust the pH of the above reaction system to 5.0 with dilute hydrochloric acid, add 1.5 parts of tridecafluorooctyltrimethoxysilane, and continue the reaction at 40°C for 4 hours to obtain a light blue solution, adjust the pH of the reaction system with sodium hydroxide The value is 5.0, and the reaction product is filtered to obtain the fluorinated modified silicone nano coating.
[0043] ...
Embodiment 3
[0045] The production method of silicon fluoride self-cleaning glass nanomaterials in this embodiment includes the following two steps:
[0046] 1) Synthesis of silica nanoparticles
[0047] Put 500 parts of ethanol as a solvent in the reactor and stir, add 8 parts of water, and then add sodium hydroxide to adjust the pH value of the system to 12.5. At the reaction temperature of 38°C, 8 parts of ethyl orthosilicate was added into the reactor, and the reaction was stirred for 0.5h.
[0048] 2) Surface modification of silica nanoparticles
[0049] Adjust the pH value of the above silica reaction system to 5.0 with acetic acid, add 2.5 parts of heptadecafluorodecyltriethoxysilane, and continue stirring at a reaction temperature of 40° C. for 3.5 hours to obtain a light blue solution. The pH value of the reaction system is adjusted to 7.0 with ammonia water, and the reaction product is filtered to obtain the fluorinated modified silicone nano coating.
[0050] The coating prep...
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