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787results about How to "Facilitate dissociation" patented technology

Preparation method of semi-interpenetrating network polymer gel electrolyte membrane

The invention provides a preparation method of a semi-interpenetrating network polymer gel electrolyte membrane. The method comprises the following steps: (A) adding a linear polymer and a solvent to a sample bottle, stirring and dissolving the linear polymer and the solvent, adding polyethylene glycol dimethyl acrylic ester, vinylene carbonate and a photoinitiator, and mixing the polyethylene glycol dimethyl acrylic ester, the vinylene carbonate and the photoinitiator evenly to form a solution; (B) coating a glass plate with the solution, covering a layer of glass plate to form a sandwich structure, and curing the sandwich structure to obtain an ultraviolet-cured semi-interpenetrating network polymer membrane; and (C) immersing the ultraviolet-cured semi-interpenetrating network polymer membrane into liquid electrolyte. According to the gel electrolyte provided by the invention, the balance between the ionic conductivity and the mechanical property is relatively well realized; the ionic conductivity at room temperature can be up to 1.49*10<-3>S cm<-1>; the mechanical property is good; the heat stability is good; the electrolyte can be prevented from leaking; the interface stability is good; and a lithium iron phosphate / metal lithium battery assembled by the gel polymer electrolyte membrane has excellent cycle performance and rate performance.
Owner:SHANGHAI JIAO TONG UNIV

Composite polymer electrolyte for lithium ion battery and preparation method thereof

The invention relates to a composite polymer electrolyte for a lithium ion battery and a preparation method thereof. The electrolyte takes a polymer as a matrix, and an organic-inorganic composite polymer electrolyte formed by modified nano fillers is uniformly dispersed in the matrix; the modified nano fillers comprise nano oxides, ferroelectric powder or lithium-containing compounds, and the mass of the modified nano fillers accounts for 0.5%-30% of that of the polymers; and the polymers comprise polyoxyethylene, polyacrylonitrile, polymethylmethacrylate, polyvinylidene fluoride and polyvinylidene fluoride-hexafluoropropylene copolymer and a blending and copolymerization system thereof. In the invention, methoxylpolyethylene glycol acrylate is adopted to modify the nano fillers, and the surface modification improves the dispersing performance of a polymer system, therefore, the aggregation of nano particles in the polymer system is restrained, the function of the nano particles for promoting the dissociation of lithium salt in the polymer electrolyte is better exerted, a fast ion conduction channel of the fillers / polymer interface is formed and forms dispersive stress of a three-dimensional network with the polymeric matrix. Therefore, the mechanical property of the whole polymer system is improved.
Owner:SHANGHAI NAT ENG RES CENT FORNANOTECH

Method of extracting lithium salt from lepidolite

The invention discloses a method of extracting a lithium salt from lepidolite. The method comprises the following steps: roasting lepidolite mineral aggregates with CaO and Ca(CH3COO)2 in a plasma generator after ball-milling and mixing; reacting roasted materials with a dilute sulfuric acid solution and (NH4)2SO4 under a pressurized state, controlling an acid leaching temperature to 85-100 DEG C to obtain a solid-liquid mixture, cooling and freezing the solid-liquid mixture to separate potassium, rubidium, cesium and alum, filtering, adding alkali and removing impurities and depositing lithium to prepare the lithium salt. The method disclosed by the invention is capable of completely removing fluorine in the raw materials, reducing the equipment damages and environmental pollution caused by fluorine gas generation in a raw material roasting stage, improving the extraction and utilization efficiency of rare metal raw materials in the lepidolite raw material, lowering the energy consumption, shortening the reaction time and reducing the consumption of acid-base raw materials. The method disclosed by the invention is mild in condition, stable in operation process, short in production period, high in equipment efficiency, capable of realizing comprehensive utilization of resources, low in production cost and beneficial to realizing industrial production of extracting the lithium salt from the lepidolite.
Owner:李宇龙 +1

Preparation and application of single-ion conductive polymer electrolyte membrane

The invention discloses a preparation method and an application of a single-ion conductive polymer electrolyte membrane. The preparation method and the application are characterized by adopting heat initiated free radical polymerization, a polymerization system comprises lithium-containing monomers, poly(ethyleneglycol)methacrylate and a cross-linking agent, and a specific plasticizer is added toa reaction system before the reaction. The preparation method of the single-ion conductive polymer electrolyte membrane comprises steps as follows: the lithium-containing monomers, poly(ethyleneglycol)methacrylate, the cross-linking agent and a thermal initiator are dissolved in the plasticizer, and after heat initiated polymerization, the transparent self-supporting electrolyte membrane with certain mechanical strength is obtained. The preparation method and the application have the advantages as follows: a one-pot method is adopted for synthesis, the operation is convenient, and the steps are simple; the prepared electrolyte membrane has good mechanical strength, heat stability and electrochemical stability, and further has high ionic conductivity and large transport number of lithium ions; an assembled lithium metal battery shows excellent cycle performance.
Owner:NANKAI UNIV

Single slice type ambipolar ion-exchange membrane and preparation method thereof

InactiveCN101497001AFacilitates delivery and dissociationLow film resistanceSemi-permeable membranesIon-exchange membranesFunctional monomer
The invention relates to a uniwafer type bipolar ion exchange membrane and a method for preparing the same. An anion exchange layer and a cation exchange layer of a bipolar membrane are combined on two sides of the same carrier material respectively or the same side of a uniwafer type ion exchange membrane. The preparation method comprises the following steps that: a, according to certain proportion, an evocating agent, a functional monomer, a comonomer, a crosslinking agent and other additional compositions are prepared into a reaction solution of the corresponding ion exchange layer; and b, according to different carriers, the method carries out single side or double side coating treatment, that is the reaction solution is coated on the carrier material with certain thickness; the carrier material is positioned in an ultraviolet source and is radiated so that the carrier material is cured to obtain the ion exchange layer of one side; the other side of the ion exchange layer is coated with another reaction solution, positioned in the ultraviolet source and is radiated and cured, and according to requirements, cured membrane is positioned in a corresponding ionized treating solution and treated to obtain an ion exchange layer; and the bipolar membrane of the uniwafer type ion exchange layer is finally obtained. The voltage drop of two sides of the membrane is reduced; and the method has low cost and rapid reaction speed and is simple and feasible.
Owner:BEIJING TECHNOLOGY AND BUSINESS UNIVERSITY
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