61 results about "Diacrylate ester" patented technology

The invention provides a solid acid catalyst and application thereof in esterification reaction of polyethoxy dihydric alcohol and acrylic acid, and relates to the technical field of preparation of polyethylene glycol diacrylate. The solid acid catalyst is a UIO-66-SO3H catalyst based on a UIO-66 framework, the catalyst is prepared from ZrCl4, formic acid, terephthalic acid and 2-sulfonic acid terephthalic acid through a reaction, the catalyst can catalyze an esterification reaction of polyethyoxyl dihydric alcohol and acrylic acid under the solvent-free condition, a subsequent desolventizing step is avoided, energy consumption is reduced, and the method is suitable for industrial production. And the prepared polyethoxy glycol diacrylate product is colorless and transparent in color, high in purity, low in polymerization degree, moderate in viscosity and wider in application space.

The invention discloses a preparation method of a self-repairing LATP composite solid electrolyte membrane, which comprises the following steps: S1, hydroxylating titanium aluminum lithium phosphate nanoparticles, and coating with an isocyanate polyurethane prepolymer to obtain porous PU-LATP particles; s2, carrying out copolymerization on adamantanediol diacrylate, acrylate and furfuryl acrylate, and then carrying out a Diels-Alder reaction with bismaleimide so as to form a reversible cross-linked precursor solution; and S3, mixing the PU-LATP particles with the precursor, a lithium salt and an auxiliary agent, carrying out vacuum defoaming, and drying to obtain the self-repairing LATP composite solid electrolyte membrane. According to the preparation method disclosed by the invention, the solid electrolyte membrane is endowed with the capability of quickly self-repairing microcracks at room temperature, and high ionic conductivity and a wide electrochemical window are considered at the same time; the mechanical strength is obviously improved, the thermal dimensional stability is excellent, and the strict requirements of the solid-state lithium battery on high safety and long cycle life can be met.

The application belongs to the technical field of ink, and discloses a UV touch ink and a preparation method thereof.The UV touch ink comprises a UV modified acrylate, an acetylacetate ethyl ester-containing acrylic resin, an active monomer, an organic wax, a photoinitiator and a solvent; the active monomer is selected from at least one of dipropylene glycol diacrylate, diethylene glycol phthalate diacrylate, neopentyl glycol diacrylate and hexanediol diacrylate. The UV modified acrylate, the acetylacetate ethyl ester-containing acrylic resin, the active monomer and the organic wax are used as main components, and the selection of the active monomer enables the prepared UV touch ink to have excellent skin feeling and velvet feeling effects, and excellent adhesion, light resistance, weather resistance, alcohol resistance and solvent resistance. Meanwhile, the UV touch ink can simplify the curing process, and only needs to be dried by UV after printing, has high curing efficiency, and does not need to be dried by hot air and UV.

A polyelectrolyte hydrogel coating with strong substrate binding performance and a method of manufacturing the same are provided. The method includes: 1) activating a substrate by applying oxygen plasma; and 2) dissolving a polycationic polymer, a polymeric monomer, a silane coupling agent and an initiator to obtain a precursor solution, vacuumizing the precursor solution to remove air bubbles, applying the vacuumized precursor solution to a surface of the substrate activated by the oxygen plasma, and performing an in-situ polymerization and curing process under nitrogen or rare gas atmosphere. The polymeric monomer includes at least one of: acrylamide, acrylic acid, hydroxyethyl methacrylamide, 2-acrylamido-2-methyl-1-propanesulfonic acid, polyethylene glycol (diol) diacrylate, 2-methacryloxyethylphosphocholine, 3-[[2-(Methacryloyloxy)ethyl]dimethylammonio]propane-1-sulfonate, and 3-[[2-(methacryloyloxy)ethyl]dimethylammonium] propionate. The silane coupling agent has a carbon-carbon double bond functional group.

Disclosed herein are processes for producing 1,3-propanediol acrylate, 1,3- propanediol diacrylate, 1,3-propanediol monoacrylate component, 1,3-propanediol monodiacrylate component, 1,3-propanediol dimethylacrylate, and 1,3-propanediol diglycidyl ether. Also disclosed herein are compositions comprising 1,3-propanediol acrylate, 1,3-propanediol diacrylate, 1,3-propanediol monoacrylate component, 1,3- propanediol monodiacrylate component, 1,3-propanediol dimethylacrylate, and / or 1,3- propanediol diglycidyl ether.

[Problem] To provide an active energy ray-curable ink composition for inkjet, which has excellent inkjet head discharge ability, forms a printed layer having excellent adhesion to various substrates, has excellent curability, does not tack on the surface after curing, has excellent flexibility when bent together with a substrate, has excellent image quality after curing, and can be used in the field of inkjet printing. The smell is very small after curing. [Solution] An active energy ray-curable inkjet ink composition satisfying the following conditions (A) to (D): (A) the content of an amine-modified oligomer accounting for 1.0% to 20.0% by mass of the total solid content, (B) the content of an alicyclic skeleton-containing monofunctional monomer forming a polymer having a Tg of 10 DEG C to 60 DEG C during polymerization accounting for 16.0% or more by mass of the total solid content, (C) 3-methyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3-trimethyl-1 the content of 1, 5-pentanediol diacrylate accounts for 8.0% to 25.0% by mass of the total solid content, and the content of acryloylmorpholine accounts for 3.0% to 15.0% by mass of the total solid content.

The invention relates to ultraviolet curing ink for a high-glossiness environment-friendly trivalent chromium surface, a product and a preparation method of the ultraviolet curing ink. The ultraviolet curing ink is prepared from the following raw materials in parts by mass: 35 to 45 parts of polyurethane acrylate resin, 15 to 30 parts of epoxy acrylate resin, 10 to 20 parts of glycol diacrylate, 5 to 10 parts of phosphate acrylate, 3 to 8 parts of polyvinyl butyral and 3 to 5 parts of a photoinitiator. The ultraviolet curing ink is applied to the surface of an environment-friendly trivalent chromium electroplating product and has good adhesive force and wear resistance.

The invention belongs to the technical field of phase change material preparation, and particularly relates to a high-stability composite phase change material and a preparation method thereof. According to the method, an organic solid-liquid phase change material is taken as a solvent, a reaction monomer octadecyl acrylate and a cross-linking agent 1, 6-hexanediol diacrylate are subjected to a cross-linking reaction through a redox initiation system (benzoyl peroxide and N, N-dimethyl-p-toluidine), and the solid-liquid phase change material is prepared. A phase-change high-molecular polymer with a phase-change function is constructed, a coating structure is formed on the organic solid-liquid phase-change material, and finally the composite phase-change material with excellent thermal stability and high latent heat characteristics is prepared. The preparation process disclosed by the invention can be carried out under a low-temperature condition, energy consumption and production cost can be effectively reduced, the process is simple, and batch production is easy; the prepared composite phase change material has wide application prospects in the fields of energy storage, temperature control and the like.

The invention discloses a vibrating diaphragm of a sound production device, the sound production device and electronic equipment. The vibrating diaphragm is prepared from a blending material, the blending material comprises first acrylate rubber and second acrylate rubber, the mass ratio of R1 to R2 in the molecular structure of the first acrylate rubber is smaller than or equal to 40%, the glass transition temperature of the first acrylate rubber ranges from-60 DEG C to-33 DEG C, and the mass ratio of R1 to R2 in the molecular structure of the second acrylate rubber is smaller than or equal to 40%. The mass ratio of the first acrylate rubber in the acrylate rubber is greater than or equal to 50wt%; the mass ratio of R1 to R2 in the molecular structure of the second acrylate rubber is greater than or equal to 60%, the glass transition temperature of the second acrylate rubber is-25 DEG C to 10 DEG C, and the mass ratio of the second acrylate rubber in the acrylate rubber is less than or equal to 50wt%; the loss factor of the vibrating diaphragm in the temperature range of-60 DEG C to 20 DEG C is greater than or equal to 0.12. According to the vibrating diaphragm disclosed by the embodiment of the invention, the vibrating diaphragm is prepared by blending the first acrylate rubber and the second acrylate rubber with different glass transition temperatures, so that the vibrating diaphragm has high damping property, high flexibility and high elastic recovery rate within a relatively wide temperature interval.

The invention belongs to the field of thick film electronic element manufacturing, and particularly relates to chip resistor MK layer UV curing slurry and a preparation method thereof. The problems that an existing UV curing protective layer is insufficient in heat resistance, and cracking and falling are caused by mismatching of thermal expansion coefficients are solved. Through an epoxy-organic silicon hybrid resin system and a composite functional filler, the resin system comprises trimethylolpropane triacrylate, hexanediol diacrylate, an epoxy acrylate oligomer, an organic silicon modified acrylate oligomer, a phosphorus-containing acrylate functional monomer and a thermal polymerization inhibitor, and the functional filler is prepared from modified spherical aluminum oxide, modified silicon dioxide, a photoinitiator, a photoinitiator, a photoinitiator, a photoinitiator, a photoinitiator and a photoinitiator. According to the invention, the thermal shock resistance and insulation reliability of the protective layer are improved while the high efficiency of the UV photocuring process is maintained.

Disclosed herein are the synthesis and characterisations of the monoacrylate-functionalised phthalonitriles (PNs). Their chemical structures are verified with 1H nuclear magnetic resonance (NMR) and Fourier transform infrared (FT-IR) spectra to confirm the successful synthesis. Subsequently, photopolymerisable resins, based on the prepared PN monomer, a commercial diacrylate and other additives can be formulated. Being post thermally treated, the PN based resins result in polymeric products with excellent thermal and mechanical performances, suggesting the high-performance nature of the PN based resins. Interestingly, the resins exhibit significant high carbon yield, indicating that they are greatly promising candidates as carbon precursors. As it is found that the resins have good three-dimensional (3D) printing capability and can be fabricated using high-resolution projection micro-stereolithography (PμSL) additive manufacturing technology, complex 3D structured objects are herein printed and performed follow-up post treatment. After being progressively pyrolysed up to 1000° C., the printed objects can be readily converted to glassy carbon (GC) structures with structural integrity and fidelity. Only ˜25% of shrinkage was found for the converted GC structure due to the significantly high char yield of the PN resins. This work not only expands the library of new class of high-performance PN resins for popular additive manufacturing but also features the precision 3D printing of GC with low shrinkage and high carbon yield for the first time.

Disclosed herein are processes for producing 1,3-propanediol acrylate, 1,3-propanediol diacrylate, 1,3-propanediol monoacrylate component, 1,3-propanediol dimethylacrylate, and 1,3-propanediol diglycidyl ether. Also disclosed herein are compositions comprising 1,3-propanediol acrylate, 1,3-propanediol diacrylate, 1,3-propanediol monoacrylate component, 1,3-propanediol dimethylacrylate, and / or 1,3-propanediol diglycidyl ether.

The application discloses a pressure-sensitive film based on force response cholesteric main chain liquid crystal oligomer, and the structure of the pressure-sensitive film based on force response cholesteric main chain liquid crystal oligomer is sequentially PDMS layer, cholesteric liquid crystal oligomer layer and substrate layer from top to bottom; the cholesteric liquid crystal oligomer layer is obtained by reacting diacrylate liquid crystal monomer and dithiol; and the polymerization degree of the cholesteric liquid crystal oligomer layer is 2-10. The pressure-sensitive film based on force response cholesteric main chain liquid crystal oligomer disclosed by the application uses the oligomer with a polymerization degree of 2-10 obtained by polymerizing diacrylate liquid crystal monomer as the cholesteric liquid crystal oligomer layer, so that the visual degree is higher, the threshold of force response is controllable, and there is no liquid component in the pressure-sensitive film, so that the pressure-sensitive film is easier to assemble and more stable.

The invention discloses an anti-permeation glue and a preparation method and application thereof, 100 parts by weight of the anti-permeation glue comprises 15-25 parts of bio-based wax microspheres, 2-5 parts of a Pickering particle stabilizer, 30-50 parts of a multistage gradient crosslinking monomer, 0.5-1.5 parts of a water-based photoinitiator, 3-8 parts of a graphene oxide-chitosan hybrid dispersion liquid, 1-3 parts of a glycosyl gemini surfactant and the balance of deionized water. Wherein the multi-section gradient cross-linking monomer is prepared from ethyl acetoacetoxymethacrylate, tripropylene glycol diacrylate and bisphenol A epoxy diacrylate according to the mass ratio of (2 to 3) to (3 to 4) to (1 to 3). The oil-proof coating is based on 100% of water and has zero VOC, the air permeability loss is smaller than or equal to 10% on the premise that the oil-proof grade is larger than or equal to 6, molten drops are avoided during combustion, and the oil-proof coating can be coated at the low temperature of 60-70 DEG C.

The application provides an ultrasonic response piezoelectric ionic hydrogel and application thereof, and the hydrogel is formed by cross-linking and solidification of a precursor solution under ultraviolet irradiation; components of the precursor solution include a photosensitive polymer, an ionic polymer, a photoinitiator and a solvent; the photosensitive polymer includes any one or a combination of at least two of polyether F127 diacrylate, polyhydroxyethyl methacrylate, polyethylene glycol dimethyl acrylate, methacrylated gelatin or methacrylated collagen; and the ionic polymer includes any one or a combination of at least two of epsilon-polylysine, polyethyleneimine hydrochloride, polyallylamine hydrochloride, polyquaternary ammonium salt-10 or cationic guar gum. The application uses ultrasonic waves as an external remote driving signal to non-invasively and painlessly activate the piezoelectric ionic effect of the hydrogel, generate detectable periodic voltage and current signals in the hydrogel, and has excellent treatment effect on acne and infected wound repair.

The application discloses a kind of radiation curing coating, the radiation curing coating is modified urethane acrylate;1,6-hexanediol diacrylate 10-20 parts, active diluent 15-20 parts, silane coupling agent KH570 1-3 parts, benzophenone photoinitiator 1-3 parts, carbon black 1-3 parts, polyethylene glycol (molecular weight less than 2500) 1-3 parts are added to urethane acrylate environmentally-friendly preparation method product, 3 (ethoxy) trimethylolpropane tri (methyl) acrylate EO-TMPTA, 2EO-TMPTA, 3EO TMPTA are stirred and uniformly mixed, finally UV ultraviolet irradiation is cured, light radiation energy 2000-3000 mJ / cm2, modified urethane acrylate can be obtained.The radiation curing coating of the application can realize UV curing and electron beam curing, the urethane acrylate prepared by the environmentally-friendly preparation method is used as the base material, cooperates with 1,6-hexanediol diacrylate raw material, and is cooperated with graphene adjusted nanosilica agent and magnesium oxide modifier, and is synergistic.

The invention relates to the technical field of biological conduction, in particular to a composite material and a rapid preparation method. The invention provides a bioelectronics-oriented novel flexible conductive composite material. The bioelectronics-oriented novel flexible conductive composite material is prepared by performing illumination molding on a mixed system. The preparation method comprises the following steps: dissolving polyether F127-diacrylate serving as an elastic network skeleton in a conductive polymer solution and uniformly doping a conductive polymer to prepare semi-interpenetrating double-network hydrogel; afterwards, excessive small molecules are removed through mild glacial acetic acid treatment, and chain segments are induced to be rearranged. The biological flexible conductive material prepared by the invention has excellent conductivity, mechanical property and biocompatibility, and a biological flexible electrode with good performance can be obtained by combining a 3D printing technology. According to the flexible electrode, the bottlenecks that an existing flexible electrode is low in conductivity, complex in packaging and limited in large-size printing are improved from a material system to a manufacturing process, and a universal and efficient new scheme is provided for implantable soft bioelectronics.

A plurality of microcapsules having a crosslinked polymer shell encapsulating an active ingredient, wherein the crosslinked polymer shell comprises or consists of at least one polymer selected from aliphatic epoxidized polyacrylates, such as soybean oil acrylate, bisphenol A-based epoxy acrylate, glyceryl propoxy triacrylate, difunctional polyester acrylate oligomers, aliphatic polyester-based urethane dimethacrylates or diacrylates, and amine-modified polyether acrylates. When a dispersion of the plurality of microcapsules in an inert medium is subjected to a shear stress of 3 kPa or more at a temperature of about 20°C, the dispersion has a mechanical resistance such that after being subjected to the shear stress for 10 minutes, the proportion of capsules broken as observed by microscope is less than 10%.

This invention relates to a high-reliability solder resist coating, its preparation method, and its application. The raw materials, by weight, include 40-50 parts of alkali-soluble resin, 10-20 parts of acrylate monomer, 1-5 parts of photoinitiator, 0.1-0.5 parts of pigment, 0.1-0.3 parts of additives, and 30-45 parts of filler. The alkali-soluble resin is bisphenol A epoxy diacrylate resin, and the filler includes at least modified barium sulfate. This invention synergistically combines bisphenol A epoxy diacrylate resin with modified barium sulfate to achieve a synergistic improvement in mechanical properties and resistance to damp heat, solving the problems of insufficient mechanical properties, poor resistance to damp heat, and difficulty in passing the stringent 85 dual-85 test of existing solder resist dry films. The solder resist dry film can meet the usage requirements of high-end printed circuit boards in harsh damp heat environments, improving the service life and reliability of printed circuit boards.

The invention discloses a diselenide bond cross-linked polyethyleneimine carrier for mRNA (messenger Ribonucleic Acid) delivery as well as a preparation method and application of the diselenide bond cross-linked polyethyleneimine carrier. The preparation of the carrier comprises the following steps: taking a synthesized diselene-1, 6-hexanediol diacrylate monomer (DSEDA) as a diselenide cross-linking agent; the diselenide cross-linked polymer material is prepared from the diselenide and branched PEI with the molecular weight of 0.6 kDa / 1.8 kDa through the Michael addition reaction of amine-acrylate, non-cross-linked primary amine is subjected to hydrophobic / hydrophilic chain modification, the hydrophilic / hydrophobic chain is a compound CH2COO-R, and the substituent R is one or more of C8-C12 linear alkyl or 6-12 oligomers of polyethylene glycol. In the carrier structure, biodegradable diacrylate bonds and diselenide bonds are introduced into the cross-linking agent, so that the transfection efficiency is maintained, and meanwhile, the toxicity is reduced to the maximum extent. As the diselenide bond can sensitively respond to oxidation and reduction environments at the same time, the diselenide bond-containing polymer molecule can become a novel mRNA carrier material, and can play a promoting role in improving intracellular mRNA release and translation.

The invention discloses a full-solid-content UV curing coating composition which comprises resin and monomers, the resin comprises phenolic aldehyde modified epoxy acrylic resin and polyurethane acrylic resin, and the monomers comprise two or more diacrylates. The invention also discloses a preparation method of the full-solid-content UV-curable coating composition, which comprises the following steps: (1) mixing the resin, a part of monomers and optional auxiliaries and pigments and fillers to obtain a premix; and (2) adding the other part of monomers and optional auxiliaries into the premix in the step (1). Further disclosed is a substrate coated with the full solid content UV curable coating composition.

The invention relates to a composite material for preparing a high-flatness temporary pavement slab as well as a preparation method and application of the composite material, belongs to the technical field of materials for non-metal additive materials, and particularly relates to the technical field of polycarbonate materials for road pavement. The composite material provided by the scheme of the invention comprises the following components in parts by weight: 100 parts of bisphenol A polycarbonate; 50 to 80 parts of polyacetal resin; 10 to 20 parts of bisphenol A ethoxylate diacrylate; 10 to 20 parts of polystyrene; 5-15 parts of nitrile rubber; 4 to 6 parts of an anti-ultraviolet agent; 2-6 parts of a flame retardant; and 1-3 parts of an antioxidant. According to the composite material provided by the invention, the bisphenol A polycarbonate is compounded with the polyacetal resin, the polystyrene and the nitrile rubber, so that the defects of polycarbonate in the aspects of fatigue resistance, solvent resistance and wear resistance are overcome, and the comprehensive performance of the obtained panel composite material is improved; and the temporary pavement slab is more suitable for being used as a high-flatness temporary pavement slab.

The invention discloses light-cured piezoelectric ceramic slurry and a preparation method and application thereof.According to the light-cured piezoelectric ceramic slurry, two-functional-group aliphatic polyurethane acrylate, hexanediol diacrylate and trimethylolpropane triacrylate are compounded, a phosphate hyperdispersant is combined, firm chemical anchoring can be formed with modified barium titanate, and the piezoelectric ceramic slurry can be applied to light-cured piezoelectric ceramics. In addition, a curing system composed of low-viscosity active monomer hexanediol diacrylate, high-crosslinking-density trimethylolpropane triacrylate and a visible light initiator is adopted, the curing system is matched with the light absorption characteristic of modified barium titanate, and therefore the light absorption property of the modified barium titanate is improved. And enough penetration depth and interlayer binding force are ensured. A DLP technology is adopted to accurately print a ceramic green body framework at one time, a barium titanate ceramic framework with a complete structure and high density is obtained after degreasing and sintering, the 3-3 type piezoelectric composite material with controllable precision is prepared, the reflection loss of sound waves is reduced, and the quality of the material is further ensured.

To solve the technical problem that the utilization rate of rainwater is reduced due to the fast evaporation of rainwater stored in the existing water cellar, the embodiment of the present application provides a preparation method of an anti-evaporation water conservation material, a soft water cellar film and an application, comprising: uniformly dissolving water, alkyl sulfate and a first fatty alcohol polyoxyethylene ether to obtain a mixed solution; adding liquid anti-evaporation agent, a second fatty alcohol polyoxyethylene ether and pre-uniformly mixed alpha-methacrylic acid, first ethylene glycol dipropylene acrylate and dibenzoyl peroxide into the mixed solution to mix and emulsify, thereby obtaining an emulsion; after the emulsion is reacted by heating, an aqueous solution of potassium persulfate is further added to continue the reaction, thereby obtaining a core layer solution; uniformly mixing vinyl acetate, butyl acrylate, hydroxyethyl acrylate and second ethylene glycol dipropylene acrylate to obtain a shell layer solution; and adding the shell layer solution into the core layer solution to react, thereby obtaining the anti-evaporation water conservation material. The embodiment of the present application has the characteristics of green, environmental protection, simple process flow and easy implementation.

The invention discloses an electron beam cured bio-based solvent-free spraying bright white finish, which is prepared from the following raw materials in parts by mass: 6 to 10 parts of epoxy acrylate oligomer, 15 to 19 parts of bio-based diacrylate, 8 to 11 parts of natural oil modified acrylate oligomer, 5 to 8 parts of epoxidized soybean oil acrylate and 10 to 15 parts of bio-based acrylate monomer, the coating is prepared from the following components in parts by weight: 15-20 parts of a bifunctional active acrylate monomer, 0.5-1 part of a dispersing agent, 0.1-0.2 part of a defoaming agent, 0.2-0.4 part of a flatting agent and 25-30 parts of titanium dioxide. The product disclosed by the invention is quick to dry, balanced in hardness and toughness and easy to cure, can cover a base material through one-time coating, and does not remain odor; and when the paint is applied to coating of white cabinets, wooden doors and panel furniture, the production efficiency can be greatly improved.

This invention discloses a polymer material technology field, specifically an impact-resistant lens resin monomer, its preparation method, and its production system. The raw materials, by weight, include: 60-80 parts epoxy acrylate, 15-25 parts polycaprolactone diacrylate, 1-3 parts dicumyl peroxide, 0.5-1.5 parts antioxidant 1010, 0.3-1.0 parts ultraviolet absorber UV-327, 0.3-0.8 parts γ-methacryloyloxypropyltrimethoxysilane, and 1-3 parts nano-silica. By using epoxy acrylate, polycaprolactone diacrylate, dicumyl peroxide, antioxidant 1010, ultraviolet absorber UV-327, γ-methacryloyloxypropyltrimethoxysilane, and nano-silica as raw materials, this invention achieves a good balance between the impact resistance and light transmittance of the lens resin monomer, solving the problem that traditional monomers cannot simultaneously achieve both properties.

The invention discloses a thermal response electrolyte, a preparation method thereof and a battery, and belongs to the field of battery electrolytes. The electrolyte comprises a component A and a component B; the component A comprises an electrolyte, an organic solvent and a thermal response compound, and the component B comprises an electrolyte, an organic solvent and a thermal triggering agent; the thermal response compound is a diacrylate compound, and a molecular chain of the diacrylate compound is composed of an alkane chain and two acrylate groups located at two ends of the alkane chain; the number of carbon atoms on an alkane chain is 1-18; the expressions of free double bonds in the two acrylate groups are respectively C (R1) = CH2 and C (R2) = CH2, and R1 and R2 are respectively and independently selected from one of hydrogen, methyl and ethyl. The thermal response electrolyte is converted into a solid state from a liquid state at a high temperature, lithium ion transmission can be blocked, a battery is disconnected, further thermal runaway is inhibited, and the problems in the background technology are effectively solved.

The application discloses a preparation method of an ultraviolet curing antistatic coating and relates to the technical field of antistatic coatings. In the application, hydrochloric acid doped polyaniline is used as a core material, 1-butyl-3-methyl imidazole bistrifluoromethanesulfonylimide ionic liquid is introduced as a dopant, and the carrier mobility of the polyaniline is significantly improved. Urea-formaldehyde resin is used as a wall material to coat the surface of the polyaniline to form microcapsules. The microcapsules release polyaniline and ionic liquid compounds after being broken to fill the crack gap. Secondly, 3,3'-dihydroxy diphenyl disulfide and acryloyl chloride are used as raw materials to generate a disulfide bond diacrylate monomer through an esterification reaction. The monomer, tetra(3-mercaptopropionic acid) pentaerythritol ester crosslinking agent and epoxy vinyl ester resin form a three-dimensional crosslinking network. The mercapto groups in the crosslinking agent and the acrylate groups of the disulfide bond diacrylate monomer undergo a click reaction to realize the topological structure reorganization of the molecular chain. The coating prepared by the application has the effect of long-acting antistatic.

Disclosed are branched poly(beta-amino ester) (PBAE) comprising a backbone having a ratio of diacrylate monomers and triacrylate monomers or diacrylate and tetraacrylate monomers, an amine sidechain, and an amine endgroup, and a nucleic acid, which are useful for the delivery of biomolecules, including the intracellular delivery of nucleic acids, which can be applied to almost any disease, ranging from cancer, to autoimmune diseases, to ocular diseases, to genetic disorders. These materials are particularly advantageous and enabled for delivery of mRNA and DNA to cells, including human cells. Compared to other PBAE nanoparticles, the disclosed NPs are smaller, more monodisperse, and more efficient at delivery and are useful and translatable as therapeutics.

The present invention provides an ultraviolet-curable ink composition for inkjet printing, which comprises a polymerization component and a photopolymerization initiator, the polymerization component comprising (A) a multifunctional amine-modified oligomer, (B) a nitrogen-containing monomer, (C) an aromatic ring-containing monomer, and (D) a multifunctional monomer, (A) comprising an acrylated amine compound having 2 photopolymerizable functional groups and 2 amino groups within the molecule, (B) comprising at least any one of acryloylmorpholine or vinylcaprolactam, (C) comprising benzyl acrylate and phenoxyethyl acrylate, (D) comprising at least any one of dipropylene glycol diacrylate, 1,6-hexanediol diacrylate, or ethoxylated trimethylolpropane triacrylate, the content of (A) being 0.8-11.0 mass%, the content of (C) being 32.0-75.0 mass%, and the content of (D) being 1.5-14.0 mass%.