Photo-curable resin composition

a technology of photocurable resins and compositions, applied in the field of selected stereolithographic resins, can solve problems such as excessive color development and part distortion

Inactive Publication Date: 2008-05-01
DSM IP ASSETS BV
View PDF28 Cites 26 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Typical temperatures have risen to values between 50° C. and 90° C

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Photo-curable resin composition
  • Photo-curable resin composition
  • Photo-curable resin composition

Examples

Experimental program
Comparison scheme
Effect test

examples

[0107]The present invention is further illustrated with a number of examples, which should not be regarded as limiting the scope of the present invention.

[0108]Radiation curable liquid compositions were prepared by weighing all the ingredients into a container under mechanical stirring either at room temperature or up to 50° C. until homogeneous resin mixtures were obtained. Each liquid mixture was then filtered off into a vat of stereolithography apparatus using a medium paint filter before fabrication of parts.

[0109]Compositions were prepared by mixing the components listed in Table 2 (Examples) and Table 3 (Comparative Examples, which are not Examples of the invention) for epoxy and acrylate dual cure or hybrid resins, with amounts of the components being listed in parts by weight. The thus prepared compositions were subsequently analyzed in accordance with the Test Methods described below. The test results are also listed in Tables 2-3.

Test Methods

[0110](a) Energy E10, Depth of ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Timeaaaaaaaaaa
Timeaaaaaaaaaa
Forceaaaaaaaaaa
Login to view more

Abstract

The invention relates to a radiation curable composition comprising from about 50 wt % to about 70 wt % of a cycloaliphatic diepoxide, from about 5 wt % to about 15 wt % of a polyol, from about 5 wt % to about 15 wt % of an oxetane, from about 10 wt % to about 20 wt % of an aromatic diacrylate, a radical photoinitiator and a cationic photoinitiator. The invention further relates to a process for making a three dimensional article from the resin composition of the invention, to the three-dimensional article itself and to the use of the composition of the invention.

Description

FIELD OF THE INVENTION[0001]The present invention relates to selected stereolithographic resins containing cationically curable and radically curable compounds.BACKGROUND OF THE INVENTION[0002]The production of three-dimensional articles of complex shape by means of stereolithography has been known for a number of years. In this technique the desired shaped article is built up from a radiation-curable composition with the aid of a recurring, alternating sequence of two steps (a) and (b). In step (a), a layer of the radiation-curable composition, one boundary of which is the surface of the composition, is cured with the aid of appropriate imaging radiation, preferably imaging radiation from a computer-controlled scanning laser beam, within a surface region which corresponds to the desired cross-sectional area of the shaped article to be formed, and in step (b) the cured layer is covered with a new layer of the radiation-curable composition, and the sequence of steps (a) and (b) is re...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08J3/28
CPCC08G59/22C08G59/24C08G65/18C08L63/00C08L71/02G03F7/0037Y10T428/24612G03F7/038G03F7/0755G03F7/027B29C67/0066C08L2666/02B29C64/135B33Y70/00B33Y70/10
Inventor XU, JIGENG
Owner DSM IP ASSETS BV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap