2865 results about "Light cure" patented technology

The invention belongs to the technical field of aerogel materials, and particularly relates to antistatic aerogel for 3D printing as well as a preparation method and application of the antistatic aerogel. The preparation method comprises the following steps: (1) dispersing inorganic nanoparticles modified by a silane coupling agent containing epoxy groups and an aniline monomer in an acidic solvent to obtain a monomer mixed solution; (2) stirring and dissolving polyamide in the monomer mixed solution; (3) initiating a reaction to obtain a polyaniline modified polyamide solution; and (4) freeze-drying to obtain the antistatic aerogel for 3D printing. By controlling synthesis conditions, a core-shell structure of acid-doped polyaniline coated inorganic nanoparticles is formed, and a good conductive path is formed in polyamide with a small addition amount of polyaniline. The antistatic aerogel for 3D printing can be applied to technologies such as photocuring molding and fused deposition of polyurethane resin in a 3D printing technology, and the antistatic property and the mechanical property of a 3D printed product are improved.

The invention relates to a layered drug-loading microneedle patch as well as a preparation method and application thereof. The preparation method of the layered drug-loading microneedle patch comprises the following steps: S1, dissolving a drug and a soluble high-molecular polymer in a solvent according to a mass ratio of (2: 1)-(1: 12) to form a needle tip solution, then filling a needle tip cavity of a microneedle mold with the needle tip solution, drying, and removing redundant drug residues on the surface to form a drug-loading needle tip layer; and S2, filling a mold containing the drug-loading needle tip layer with a photocurable polymer, performing ultraviolet curing for 10-30 seconds under the wavelength of 365-405 nm, and then performing demolding to form a substrate layer, thereby obtaining the layered drug-loading microneedle patch. According to the method, one-time filling of the needle tip part is successfully achieved by combining needle tip auxiliary material proportion optimization, meanwhile, the curing process is rapid, the medicine utilization rate and the process stability are remarkably improved, the medicine stability is good, and the method is suitable for industrial production.

The invention provides a gradient crosslinking process of photosensitive resin for photocuring 3D printing, and relates to the technical field of photocuring 3D printing materials. The gradient crosslinking process of the photosensitive resin for photocuring 3D printing comprises the following steps: S1, based on double-initiator system design, adopting molecular dynamics simulation screening, respectively adding a 405nm sensitive type TPO-L initiator and a 365nm sensitive type I TX initiator into an epoxy acrylate prepolymer, and verifying initiation energy barrier matching through quantum chemistry calculation, and generating a pre-initiation gradient resin formula. Through molecular dynamics simulation, initiator combinations are screened, energy barrier matching is verified, the ratio of dual-wavelength sensitive initiators is optimized, and accurate triggering of surface layer and deep layer cross-linking reaction is ensured. And a three-roller grinding and dispersing process is combined with ultrasonic oscillation to eliminate nanoparticle aggregation, so that the mechanical uniformity and light scattering effect of a resin system are improved.

The present disclosure provides a miktoarm polymer having the following structure:where polymer chain 1, 2, 3, 4, A1 and A2 are as defined herein. These miktoarm polymers can produce desirable polymeric materials and being used as a component in photo-curable resins. Further provided herein are methods of producing miktoarm polymers, as well as compositions, resins, devices, and polymeric materials by use of the same. Also provided herein are methods of using miktoarm polymers, resins, and polymeric materials for the fabrication (e.g., via 3D printing) of medical devices, such as orthodontic appliances.

The invention relates to the technical field of decorative materials, in particular to a decorative material with a 3D texture structure and a preparation method and application of the decorative material. The method comprises the following steps: carrying out digital printing on a pretreated substrate to obtain a 2D pattern layer on the surface of the substrate; coating the surface of the 2D pattern layer with a photocuring coating, carrying out preliminary curing, and then carrying out ink-jet printing of a texture developing solution on the surface subjected to preliminary curing to carry out secondary curing, so as to obtain a cured coating; the cured coating comprises a hardened part and an unhardened part; and after an unhardened part in the cured coating is removed through polishing and wire drawing, a surface coating is coated, and the decorative material with the 3D texture structure is obtained. The textures with different widths and depths can be obtained in a manner of combining primary curing of the coating with ultraviolet absorption of the developing solution, and then a microcosmic coarse and visual smooth form is obtained through polishing and wire drawing treatment, so that the obtained 3D texture structure is closer to natural textures.

The invention relates to the technical field of optical protective materials, in particular to an anti-dazzle full-ultraviolet-proof optical protective material and a preparation method thereof.The anti-dazzle full-ultraviolet-proof optical protective material is formed by sequentially compounding a scratch-resistant hardened layer, a PET film layer a, a composite adhesive layer, a PET film layer b, an installation adhesive layer and a PET release film layer from top to bottom; the preparation method comprises the following steps: mixing organic silicon modified polyurethane acrylate, a pigment, a reactive diluent, a flatting agent, a photoinitiator, a solvent and modified nano silicon dioxide to prepare a photocurable scratch-resistant hardening coating liquid; in order to endow the optical material with excellent infrared barrier property and heat insulation property, cesium tungsten bronze is introduced into a composite adhesive layer as a filler, and in order to improve the adhesive power and water resistance of a composite adhesive solution, epoxy resin is taken as a base material, organic silicon modified polyurethane acrylate is introduced as a water-resistant component, acrylic acid is taken as tackifying resin, and a curing agent is taken as a curing agent. And bisphenol A ethoxylate dimethacrylate is used as a diluent.

The embodiment of the invention provides a UV (ultraviolet) thermal dual-curing adhesive and a preparation method thereof. The UV thermal dual-curing adhesive comprises the following components in percentage by mass: 30-55% of a photocuring prepolymer; 5%-25% of an active diluent monomer; 1%-10% of a photoinitiator; 1%-20% of a thermal initiator; 10%-40% of a filler; 0.5%-5% of a coupling agent; 1%-10% of a thixotropic agent; 1%-10% of pigment; 2%-8% of an auxiliary agent; wherein the photocuring prepolymer comprises epoxy resin. According to the UV thermal dual-curing adhesive and the preparation method thereof provided by the embodiment of the invention, the dual-curing adhesive with low shrinkage and low thermal expansion coefficient is obtained by optimizing the structure of the photocuring prepolymer and matching the components, and the prepared adhesive can be rapidly cured under the irradiation of LED 365nm ultraviolet light, or can be thermally cured under the low-temperature condition of 80 DEG C, so that the UV thermal dual-curing adhesive can be widely applied to the field of ultraviolet curing. The product can resist high and low temperature cycle impact of-50 DEG C to 140 DEG C, and has a good application prospect.

The invention discloses a UV-CIPP material for pipeline repair and stress monitoring and a preparation method of the UV-CIPP material, and belongs to the technical field of intelligent materials. The preparation method comprises the following steps: respectively diluting MWCNT slurry according to a certain proportion; soaking the glass fiber in the dipping solution for a period of time, taking out and drying; coating two ends of the dried glass fiber with conductive silver adhesive, and pasting a copper electrode after curing; adding a thermal initiator into the ultraviolet curing resin; respectively preparing test pieces with different resin contents; and sequentially carrying out ultraviolet curing and thermocuring on the prepared test piece. The characteristics and advantages of the ultraviolet curing resin, the glass fiber and the resin material are combined, and the preparation problem of the ultraviolet curing composite material for repairing the intelligent pipeline, which does not influence the mechanical property of the material and can realize excellent monitoring capability, is solved.

The invention provides a preparation method of water-based UV curing conductive ink, and relates to the technical field of polymer conductive material preparation, the preparation method comprises the following steps: respectively preparing modified water-based UV resin, nano-silver and a nano-silver-graphene composite material; and mixing the prepared modified water-based UV resin, nano-silver and a nano-silver-graphene composite material with a photoinitiator, 1, 6-hexanediol diacrylate and an auxiliary agent to obtain the water-based UV curing conductive ink. The preparation method comprises the following steps: firstly, synthesizing an unsaturated epoxy intermediate (EA) by utilizing acrylic acid (AA) and bisphenol A type epoxy resin E-51, then adding the epoxy intermediate EA into an intermediate PUA, and carrying out full end capping on the PUA to prepare light-cured resin; preparing nano-silver and a nano-silver-graphene composite material through a chemical reduction method; and finally, constructing a conductive network in the ink by virtue of a synergistic effect between the nano-silver and the nano-silver-graphene composite material, so as to prepare the water-based UV-cured high-performance conductive ink.

The invention belongs to the technical field of composite prepreg, and relates to UV curing wind power blade repairing resin and a preparation method thereof.The repairing resin comprises a component A and a component B. The component A comprises, by weight, 0-60 parts of glycidyl epoxy resin, 30-80 parts of alicyclic epoxy resin, 0-20 parts of oxetane and 2-30 parts of flexibilizer; the component B is prepared from the following components in parts by weight: 90 to 99 parts of olefin monomer or olefin resin, 0.1 to 6 parts of free radical photoinitiator, 0.1 to 2 parts of thermal cationic initiator and 0.1 to 5 parts of photo cationic initiator. The UV-cured wind power blade repair resin is a hybrid system of an epoxy resin system and acrylate resin, has the advantages of light curing of epoxy resin and acrylate resin, does not need heating or solvent, is controllable in reaction degree, can be quickly formed at low temperature, and has the repair thickness gt; and the material can be applied to repair in winter and other severe environments.

The invention relates to the technical field of photocuring materials, in particular to a cationic epoxy resin photocuring adhesive as well as a preparation method and application thereof. The cationic epoxy resin photocuring adhesive provided by the invention is prepared from the following components in percentage by weight: 25 to 55 percent of alicyclic epoxy resin, 10 to 25 percent of organic silicon modified alicyclic epoxy resin, 10 to 25 percent of oxetane, 5 to 20 percent of abietate dihydric alcohol, 5 to 10 percent of adhesion promoter, 0.3 to 3 percent of sensitizer and 0.1 to 2 percent of photoacid generator. The cationic epoxy resin light-cured adhesive provided by the invention is applied to bonding of electronic materials, has the advantages of high adhesive force and high elongation, particularly has higher adhesive force to copper materials than conventional cationic epoxy adhesives, overcomes the defects of conventional cationic light-cured adhesives, and is excellent in cured product performance, high in aging reliability and wide in application range.

The invention discloses SiZrOC resin capable of realizing photocuring 3D printing as well as a preparation method and application of the SiZrOC resin, and belongs to the technical field of ceramic 3D printing. The preparation method of the SiZrOC resin comprises the following steps: 1, dissolving zirconium oxychloride in a solvent A, adding a chelating agent and triethylamine, and uniformly mixing to obtain a solution A; mixing silane, a solvent B and deionized water, and fully and uniformly mixing to obtain a solution B; step 2, dropwise adding the solution A into the solution B, and reacting for a period of time to obtain SiZrOC sol; step 3, carrying out rotary evaporation on the SiZrOC sol to obtain white turbid high-viscosity resin; and step 4, uniformly dispersing the high-viscosity resin and the organic solvent, then carrying out reduced pressure filtration to obtain clear and transparent faint yellow filtrate, and carrying out rotary evaporation treatment on the filtrate to obtain the faint yellow transparent SiZrOC resin. The ceramic part prepared by the polymer derived ceramic 3D printing technology has ultrahigh mechanical property and high temperature resistance.

The invention relates to the technical field of polyurethane acrylate, and particularly discloses dual-curing polyurethane acrylate resin and a preparation method thereof. Wherein the dual-curing polyurethane acrylate resin is prepared from the following raw materials: polyester polyol, polyether polyol, diisocyanate, hydroxyl acrylate, a chain extender, a photoinitiator, cardanol glycidyl ether, a polymerization inhibitor and modified nanoparticles. Wherein the citric acid and the polyethyleneimine are adopted to carry out synergistic modification on the nano particles, the dispersion stability of the nano particles is improved, so that the mechanical property of the resin is improved, the cardanol glycidyl ether and the photoinitiator generate a synergistic effect, and the resin can be quickly shaped through photocuring promoted by the photoinitiator; the cardanol glycidyl ether participates in the subsequent thermocuring reaction, so that the curing effect is improved, and the adhesive force between the film layer and the base material is enhanced.

The invention belongs to the technical field of high polymer materials, and particularly relates to bio-based light-cured polyurethane acrylate resin as well as a preparation method and application thereof. The preparation method of the bio-based light-cured polyurethane acrylate resin comprises the following steps: (1) mixing a catalyst, a first polymerization inhibitor, first hydroxyl acrylate and itaconic acid, stirring and reacting at 90-120 DEG C for 6-9 hours to obtain a reaction product, then adding epoxidized soybean oil, and stirring at 90-120 DEG C for 3-5 hours to obtain a prepolymer; and (2) cooling the prepolymer obtained in the step (1) to room temperature, dropwise adding second acrylic hydroxyl ester and diisocyanate, and then stirring and reacting at 30-60 DEG C for 1.5-4 hours until an NCO infrared peak value disappears, thereby obtaining the polyurethane acrylate. The resin is high in bio-based content, moderate in viscosity, good in flexibility, high in hardness, strong in adhesive force, high in glossiness, small in smell and good in storage stability, and is suitable for being applied to preparation of UV curing coatings, UV curing printing ink, UV curing adhesives, 3D printing materials and nail polish glue.

The feeding mechanism of the 3D printing device comprises a liquid adding box, a C-opening isolation cover is integrally formed on the inner wall of one side of the liquid adding box, the interior of the liquid adding box is divided into a cavity and a resin groove through the C-opening isolation cover, the resin groove is used for containing photosensitive resin, a bottom plate is fixed in the cavity, and the bottom plate is used for containing the photosensitive resin; a liquid storage box is installed at the top end of the bottom plate, and a multi-layer H-shaped liquid injection structure used for forming a plurality of feeding points at different heights is installed on the inner wall of the liquid adding box. The photosensitive resin liquid simultaneously enters the resin tank from different directions, uniform concentration distribution of the resin liquid in the whole resin tank is guaranteed, the curing effect in the printing process is improved, the resin liquid enters the resin tank in a multi-point supply mode, a light source can more effectively irradiate each feeding point, and the printing efficiency is improved. Therefore, a faster photocuring process is realized, and the phenomena of insufficient illumination and incomplete curing reaction in some areas are avoided.

The invention discloses a sulfydryl silicon resin, a UV light-cured organic silicon optical adhesive as well as a preparation method and application thereof. The optical adhesive comprises sulfydryl silicon resin, vinyl polysiloxane and a photoinitiator, the molar ratio of sulfydryl in the sulfydryl silicon resin to vinyl in the vinyl polysiloxane is (1.2-1.5): 1; the molar ratio of vinyl in the vinyl polysiloxane to the photoinitiator is 1: (0.3-1.8). The optical adhesive disclosed by the invention can be subjected to rapid photocuring based on a click reaction of sulfydryl-vinyl, the preparation method of the optical adhesive does not need a solvent, and compared with conventional OCA, the optical adhesive has a certain filling advantage in the aspect of a full-lamination process, also has relatively high binding power, relatively low stress relaxation rate and excellent creep recovery rate, and can be used for preparing the optical adhesive. Therefore, the optical adhesive is especially suitable for flexible display application scenes represented by folding screens.

The invention relates to the technical field of coatings, and particularly discloses a photocuring anti-fog coating. The photocuring anti-fog coating comprises the following raw materials in parts by weight: 8 parts of a monomer; 30 parts of light-cured resin; 60 parts of a solvent; 0.8 part of a photoinitiator; 0.03 part of an auxiliary agent; the light-cured resin is a comb polymer with a hydrophobic long carbon chain main chain, a hydrophilic functional group branch chain and double bonds. The anti-fog coating can be used for the surfaces of optical products such as car windows and glasses, and has the advantages of lasting anti-fog effect, rapid light curing and the like.

The invention relates to the technical field of metal wire processing, and discloses a high-performance metal wire plastic coating process for aerospace engineering, which comprises the following steps: carrying out base material type selection on a metal wire, and carrying out surface treatment of precise cleaning, etching and depth gradient activation; a Ti-Cr alloy and graphene-copper composite transition layer is deposited through a magnetron sputtering technology, and a multi-layer coating structure is formed through electrostatic spraying of a base coating, a fluidized bed dipping function layer and high velocity oxy-fuel spraying of a nano composite coating in sequence; the molybdenum-gold composite sealing layer is prepared by adopting an electric arc spraying technology, and is subjected to vacuum ultraviolet curing enhancement, high-temperature gradient annealing, gradient sintering and vacuum curing treatment; and heat radiation on the surface of the coating is enhanced through laser-induced micro-nano structure regulation and silicon nitride film sputtering. Through collaborative optimization of base material treatment, coating construction, function strengthening and quality control, the interface bonding strength, the comprehensive performance and the environmental adaptability of the spaceflight metal wire coating are remarkably improved, and the service life of the spaceflight metal wire coating is remarkably prolonged.

The invention provides an ultraviolet curing adhesive. The ultraviolet curing adhesive is prepared from the following raw materials in parts by weight: 30-60 parts of urethane acrylate; 30 to 50 parts by weight of a reactive diluent; 1 part by weight to 5 parts by weight of a photoinitiator; 5-20 parts by weight of a special structure oligomer; 1-6 parts by weight of a coupling agent; 0-3 parts by weight of an auxiliary agent; the oligomer with the special structure is selected from one or more of metal polyester acrylate, carboxyl-containing acrylate oligomer and acrylic phosphate. Compared with the prior art, the ultraviolet curing adhesive provided by the invention adopts components with specific contents, realizes better overall interaction, and is strong in product adhesive strength, good in universality and excellent in ultraviolet aging resistance.

The invention relates to the technical field of protective films, and particularly discloses a composite glass protective paste for a flexible folding screen and a preparation method of the composite glass protective paste. The composite glass protection paste for the flexible folding screen sequentially comprises a functional base film, a first thermosetting polymer film, a UTG ultrathin glass layer, a second thermosetting polymer film and an OCA adhesive layer from top to bottom, the preparation method of the OCA adhesive layer comprises the following steps: carrying out activating treatment on nano silicon dioxide particles to obtain modified particles with cations on the surfaces; carrying out reaction on the modified particles and molten hydroxy acrylic resin under the ultrasonic action, and carrying out extrusion granulation to obtain elastic acrylic master batches; uniformly mixing the elastic acrylic master batch with a cross-linking agent and a photoinitiator to obtain the acrylic OCA; and coating OCA on one surface of the release film, and performing ultraviolet curing to obtain an OCA layer. According to the composite glass protection paste for the flexible folding screen, the bending resistance of the protection paste is improved.

The invention discloses hydrogel for improving photocuring 3D printing precision and application of the hydrogel. The invention discovers that pigments such as thioflavin T, alizarin yellow R, methylene blue and / or purple cabbage and the like are added into ink containing photo-crosslinking hydrogel such as methacrylated gelatin (GelMA) and the like as a photo-curing stabilizer, so that the photo-curing 3D printing precision can be improved. On the basis, the hydrogel ink capable of improving the photocuring 3D printing precision is provided, and the photocrosslinking hydrogel is mixed with the photoinitiator and the photocuring stabilizer in proportion, so that an entity obtained by printing through the hydrogel ink has higher precision. In addition, the hydrogel ink for 3D printing is easy to operate and high in practicability, and construction of repair materials needed in the biomedical field such as tissue engineering is facilitated.

The invention provides a bio-based light-cured heat-conducting and insulating composite material, a preparation method and application, and relates to the technical field of radiation curing, and the bio-based light-cured heat-conducting and insulating composite material comprises a bio-based oligomer, a reactive diluent, a modified heat-conducting filler, a free radical photoinitiator and an organic silicon defoaming agent. The bio-based oligomer is selected as a main component of the photocuring coating, and compared with a coating prepared from petroleum-based acrylic resin in the prior art, the coating has the green and environment-friendly functions, and meanwhile, the harm to the environment caused by exploitation and processing of petrochemical products can be reduced.

The invention relates to alkali-soluble light-cured resin and a preparation method thereof, a light-cured resin composition, a photosensitive dry film and a semiconductor device. The structural formula of the alkali-soluble light-cured resin is shown as a formula (I) or a formula (II), wherein in the formula (I), R1 is selected from one of a single bond, an oxygen atom, a sulfonyl group and an organic group with 1-30 carbon atoms; in the formula (I) and the formula (II), n is a natural number greater than or equal to 0; r2 is selected from organic groups with 1-50 carbon atoms; r3 is selected from an aromatic organic group or an aliphatic organic group; r4 is selected from organic groups containing unsaturated carbon-carbon double bonds; and R5 is selected from carboxyl-containing organic groups. A molecular chain of the alkali-soluble light-cured resin contains a photosensitive group, an imide structure and an alkali-soluble group, on one hand, the thermal mechanical property of the alkali-soluble light-cured resin can be enhanced, and on the other hand, the alkali-soluble light-cured resin can form a uniform and stable resin glue solution in a solvent, so that the comprehensive performance of the alkali-soluble light-cured resin is improved.

According to the photocuring molded dark-color silicon carbide ceramic and the preparation process thereof, a photosensitive resin solution with a high refractive index is prepared, and under the combined action of a structure-directing agent, a macromolecular wetting type dispersing agent, a silane coupling agent, a flatting agent and the like, the wetting effect of resin on silicon carbide powder is improved; the silicon carbide slurry with high fluidity and stability is obtained, the photocuring depth is improved, a silicon carbide green body is printed through the SLA or DLP technology, and the photocuring forming problem of silicon carbide is solved. By optimizing the grain composition of the silicon carbide ceramic and optimizing the carbon source for reactive sintering, the silicon carbide ceramic with high dimensional precision is obtained through degreasing and reactive sintering, and the volume density, mechanical strength and heat-conducting property of the reactive sintering silicon carbide ceramic are effectively improved.

The invention belongs to the technical field of deep eutectic gel wave-absorbing materials, and particularly relates to a preparation method of sodium alginate modified deep eutectic gel with wave-absorbing and strain-sensing functions, which comprises the following steps: mixing sodium alginate with deionized water, mechanically stirring for the first time to form gel A, adding a certain amount of acrylamide, mechanically stirring for the second time to form gel B, and stirring for the second time to form gel B; adding a certain amount of deep eutectic solution, mechanically stirring for the third time, performing ultrasonic vibration, vacuumizing to form gel C, and finally performing ultraviolet curing treatment on the gel C to obtain sodium alginate modified deep eutectic gel; according to the preparation method, complex equipment is not needed, the preparation period is short, the sodium alginate modified deep eutectic gel is added into deep eutectic solutions with different contents, the real part and imaginary part of the dielectric constant of the material are accurately controlled, the characteristic impedance is close to the free space impedance, meanwhile, the ion conduction efficiency is guaranteed, and optimization of wave absorption and sensing is achieved.

The invention discloses an energetic slurry toughening and photocuring 3D printing method, relates to a preparation method of energetic slurry, and aims to solve the problems that an existing energetic material is poor in mechanical property, poor in toughness and easy to crack; the particles are fast to settle in the light-cured resin, the stability is poor, and the printing precision is poor. The invention develops a photocuring high-energy resin for photopolymerization additive manufacturing. The composition contains a high-energy filler, an acrylate adhesive, whiskers and an inert plasticizer. The material has the characteristics of compatibility, printability and mechanical property, and the possibility of printing increasingly complicated high-energy articles is proved through experiments. The preparation method of the light-cured resin comprises the following steps: adding the low polymer bisphenol A epoxy acrylate and the six-functionality polyurethane acrylate; diluting monomers including 1, 6-hexanediol diacrylate and trimethylolpropane triacrylate; uniformly mixing an auxiliary agent, a thickening agent and a dispersing agent, and magnetically stirring for 30 minutes to obtain the light-cured resin. A preparation method of the energetic slurry comprises the following steps: mixing light-cured resin, whiskers, an inert plasticizer, energetic particles, a photoinitiator and a light absorber, and uniformly stirring to obtain the energetic slurry; after the energetic slurry is used for 3D printing, a sample piece is obtained, the yield reaches 95%-100%, the cost is low, preparation is easy, and the method can be applied to the field of energetic slurry 3D printing.

A method includes providing a first bonding surface on a first substrate, the first bonding surface including a thermocurable or photocurable bonding layer. The method includes providing a second bonding surface on a second substrate. The method includes bonding the first substrate to the second substrate by making physical contact between the first bonding surface and a second bonding surface. The method further includes applying thermal energy or light to the bonding layer.

The invention relates to the technical field of surface coating, in particular to a self-adaptive semi-cured interface superposition spraying control method which comprises the following steps: S1, generating spraying path parameters according to the surface curvature of a workpiece and the distance between adjacent stations; s2, workpiece offset data are obtained in real time through a visual positioning system, three-dimensional coordinate compensation data are generated based on an image matching algorithm, and when the offset exceeds a preset threshold value, real-time re-planning of a spraying path is triggered; s3, multiple groups of nozzles are controlled to execute in an alternate spraying mode: after a first layer of material is sprayed at the first station, irradiation is performed for 0.5-2 s by adopting 50-100 mW / cm < 2 > UV intensity, and a semi-cured layer with the light curing rate of 70%-85% and the thickness of 5-20 microns is formed; s4, after the conveying belt moves to a second station, a first layer of material is sprayed on the second station and partially cured, a second layer of material is sprayed on the first station, and the light curing rate is larger than or equal to 95%; s5, the steps S3-S4 are cycled to complete multi-layer spraying; and S6, dynamically adjusting the doping proportion of the nano conductive particles in the spraying material according to the environment humidity.